| Identification | More | [Name]
2-Amino-9,9-dimethylfluorene | [CAS]
108714-73-4 | [Synonyms]
9H-Fluoren-2-amine,9,9-dimethyl-
Fluoren-2-amine,9,9-dimethyl-
2-AMINO-9,9-DIMETHYLFLUORENE
9,9-Dimethyl-9H-fluoren-2-amine | [EINECS(EC#)]
805-747-3 | [Molecular Formula]
C15H15N | [MDL Number]
MFCD09953790 | [Molecular Weight]
209.29 | [MOL File]
108714-73-4.mol |
| Chemical Properties | Back Directory | [Melting point ]
166.0 to 170.0 °C | [Boiling point ]
374.2±21.0 °C(Predicted) | [density ]
1.107 | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [form ]
Powder | [pka]
4.35±0.40(Predicted) | [color ]
Off-white | [InChI]
InChI=1S/C15H15N/c1-15(2)13-6-4-3-5-11(13)12-8-7-10(16)9-14(12)15/h3-9H,16H2,1-2H3 | [InChIKey]
GUTJITRKAMCHSD-UHFFFAOYSA-N | [SMILES]
C1(C)(C)C2=C(C=CC=C2)C2=C1C=C(N)C=C2 | [CAS DataBase Reference]
108714-73-4(CAS DataBase Reference) |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Acetic acid-->Nitric acid-->n-Butyllithium-->Iodomethane-->ZINC-->Potassium Acetate-->Fluorene-->Acetamide, N-(9,9-dimethyl-9H-fluoren-2-yl)--->9,9-Dimethylfluorene-->2-Bromo-9,9-dimethylfluorene-->9,9-Dimethyl-2-nitrofluorene | [Preparation Products]
N-(4-bromophenyl)-N-(9,9-dimethyl-9H-fluoren-2-yl)-9,9-dimethyl-9H-fluoren-2-amine-->N-(4-biphenyl)-(9,9-dimethylfluoren-2--yl)Amine-->2-BroMo-5,7-dihydro-7,7-diMethyl-5-phenyl-indeno[2,1-b]carbazole-->5,7-Dihydro-7,7-dimethyl-indeno[2,1-b]carbazole-->Bis-(9,9-diMethyl-9H-fluoren-2-yl)-aMine |
| Hazard Information | Back Directory | [Chemical Properties]
White solid | [Synthesis]
General procedure for the synthesis of 9,9-dimethyl-9H-fluoren-2-amine from 2-nitro-9,9-dimethylfluorene: 23.9 g (100.0 mmol) of 2-nitro-9,9-dimethylfluorene and 0.5 g of 10% Pd/activated carbon catalyst were suspended in 500 mL of ethanol, and the reaction was stirred for 24 h under hydrogen atmosphere. Upon completion of the reaction, the catalyst was removed by filtration and the filtrate was concentrated under reduced pressure and purified by column chromatography to afford 16.9 g of the light yellow solid product 9,9-dimethyl-9H-fluoren-2-amine in 81% yield. The structure of the product was confirmed by high resolution mass spectrometry (HR-MS) (calculated value: [M+H]+ 209.1204, measured value: [M+H]+ 209.1194). | [References]
[1] Journal of Materials Chemistry B, 2013, vol. 1, # 40, p. 5450 - 5455
[2] Patent: US8865322, 2014, B2. Location in patent: Page/Page column 26; 37; 38
[3] Patent: CN105418515, 2016, A. Location in patent: Paragraph 0012; 0040 |
|
|