ChemicalBook--->CAS DataBase List--->118-46-7

118-46-7

118-46-7 Structure

118-46-7 Structure
IdentificationMore
[Name]

1-Amino-7-naphthol
[CAS]

118-46-7
[Synonyms]

1-AMINO-7-HYDROXYNAPHTHALENE
1-AMINO-7-NAPHTHOL
7-HYDROXY-1-NAPHTHYLAMINE
8-AMINO-2-NAPHTHOL
8-AMINO-2-NAPHTOL
CYANOL
SALOR-INT L157775-1EA
8-amino-2-naphthaleno
8-amino-2-Naphthalenol
8-amino-2-naphtho
8-Amino-2-napthol
AMINO-2-NAPHTHOL, 8-
8-Amino-2-naphtol 98%
1-AMINO-7-NAPHTHOLTECH.GRADE
8-Amino-2-hydroxynaphthalene
8-Amino-2-naphthelenol
8-Aminonaphthalen-2-ol
8-Aminonaphthalene-2-ol
[EINECS(EC#)]

204-252-4
[Molecular Formula]

C10H9NO
[MDL Number]

MFCD00004031
[Molecular Weight]

159.18
[MOL File]

118-46-7.mol
Chemical PropertiesBack Directory
[Appearance]

grey to grey-brown granular powder
[Melting point ]

206-210 °C(lit.)
[Boiling point ]

284.68°C (rough estimate)
[density ]

1.1202 (rough estimate)
[refractive index ]

1.6070 (estimate)
[storage temp. ]

2-8°C, stored under nitrogen
[solubility ]

soluble in Methanol
[form ]

Powder or Crystals
[pka]

pK1: 4.20(+1) (25°C)
[color ]

Gray to brown
[Water Solubility ]

slightly soluble
[Sensitive ]

Light Sensitive
[InChI]

InChI=1S/C10H9NO/c11-10-3-1-2-7-4-5-8(12)6-9(7)10/h1-6,12H,11H2
[InChIKey]

KVHHMYZBFBSVDI-UHFFFAOYSA-N
[SMILES]

C1=C2C(C=CC=C2N)=CC=C1O
[CAS DataBase Reference]

118-46-7(CAS DataBase Reference)
[EPA Substance Registry System]

2-Naphthalenol, 8-amino- (118-46-7)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P280a-P304+P340-P405-P501a-P261-P305+P351+P338-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

2
[RTECS ]

QL3331000
[TSCA ]

Yes
[HS Code ]

29222990
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

1-Naphthylamine-7-sulfonic acid-->2-Naphthalenol, 8-nitro--->N-cyclohexyl-2-imino-1-isopropyl-10-methyl-5-oxo-1,5-dihydro-2H-dipyrido[1,2-a:2,3-d]pyrimidine-3-carboxamide
[Preparation Products]

1-Acetamido-7-hydroxynaphthalene-->6-Bromo-8-fluoro-2-naphthol-->8-amino-5,7-dichloronaphthalen-2-ol
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1-Amino-7-naphthol(118-46-7).msds
Hazard InformationBack Directory
[Chemical Properties]

grey to grey-brown granular powder
[Uses]

Sulfonation gives 1-amino-7-hydroxynaphthalene-4-sulfonic acid. The N-acetyl derivative is an important coupling component for after-chrome and metal-complex dyes, e.g., C.I. Mordant Black 38 and C.I. Acid Black 60.
[Production Methods]

The sodium salt of 1-aminonaphthalene-7-sulfonic acid is added to 80 % potassium hydroxide at 210℃, and the reaction is completed by heating for 6 h at 230℃. After dilution and careful acidification with hydrochloric acid, the acid solution is screened to remove impurities and neutralized to precipitate 159 in 80 % yield (mp 207℃).
Spectrum DetailBack Directory
[Spectrum Detail]

1-Amino-7-naphthol(118-46-7)MS
1-Amino-7-naphthol(118-46-7)1HNMR
1-Amino-7-naphthol(118-46-7)13CNMR
1-Amino-7-naphthol(118-46-7)IR1
1-Amino-7-naphthol(118-46-7)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

8-Amino-2-naphthol, 98%(118-46-7)
[Alfa Aesar]

8-Amino-2-naphthol, 98%(118-46-7)
[Sigma Aldrich]

118-46-7(sigmaaldrich)
[TCI AMERICA]

8-Amino-2-naphthol,>95.0%(T)(118-46-7)
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