| Identification | Back Directory | [Name]
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER | [CAS]
12257-42-0 | [Synonyms]
4-norbornadiene)dirhodium(I)
Dichloro(norbornadiene)dirhodium
Bis[chloro(norbornadiene)rhodium]
Chloronorbornadiene rhodium dimer
NORBORNADIENE RHODIUM(1) CHLORIDE
BIS(NORBORNADIENE-MU-CHLORORHODIUM)
Dichlorobis(norbornadiene)dirhodium
Chloronorbornadiene rhodium(Ⅰ) dimer
CHLORONORBORNADIENE RHODIUM(I) DIMER
Norbornadiene rhodium chloride dimer
CHLORO(NORBORNADIENE)RHODATE (I) DIMER
Bis((mu-chloro)(norbornadiene)rhodium)
Bis(chloro(eta4-norbornadiene)rhodium)
Chloronorbornadienerhodium(I)dimer,99%
NORBORNADIENE RHODIUM(I) CHLORIDE DIMER
Di-Mu-chlorobis(norbornadiene)dirhodiuM
BICYCLO(2.2.1)HEPTA-2,5-DIENE-RHODIUM(I)
CHLORO(2,5-NORBORNADIENE)RHODIUM(I) DIMER
Bis(mu-chloro)bis(norbornadiene)dirhodium
Bis(mu-chloro)bis[(norbornadiene)rhodium]
DI-M-CHLOROBIS(NORBORNADIENE) DIRHODIUM(I)
Di-μ-chlorobis(norbornadiene) dirhodiuM(I)
DI-MU-CHLOROBIS(NORBORNADIENE) DIRHODIUM(I)
2,5-NORBORNADIENE-RHODIUM(I) CHLORIDE DIMER
di-ae-chlorobis(norbornadiene) dirhodium(i)
Chloro(norbornadiene)rhodium(I), dimer, 99.9%
Chloronorbornadiene rhodiuM(I) diMer, 99% 100MG
Di-mu-chlorobis(eta4-norbornadiene)dirhodium(I)
RHODIUM(I) CHLORIDE 2,5-NORBORNADIENE COMPLEX DIMER
Bicyclo[2.2.1]hepta-2,5-diene-rhodium chloride dimer
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER
Di-μ-chlorobis(norbornadiene)dirhodium(I), Rh 44% min
Chloronorbornadiene rhodiuM(I) diMer,98% [Rh(NBD)Cl]2
Di-^m-chlorobis(norbornadiene)dirhodium(I), Rh 44% min
Di-mu-chlorobis(norbornadiene)dirhodium(I), Rh 44% min
BICYCLO[2.2.1]HEPTA-2,5-DIENE-RHODIUM(I) CHLORIDE DIMER
Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer 96%
bis[(2,3,5,6-η)-bicyclo[2.2.1]hepta-2,5-diene]di-μ-chlorodirhodium
bis[(2,3,5,6-eta)-bicyclo[2.2.1]hepta-2,5-diene]di-mu-chlorodirhodium
Bis(norbornadiene-mu-chlororhodium)
Chloronorbornadiene Rhodium(I) Dimer
2,5-Norbornadiene-rhodium(I) chloride dimer, Chloro(2,5-norbornadiene)rhodium(I) dimer, Rhodium(I) chloride 2,5-Norbornadiene complex dimer | [EINECS(EC#)]
235-510-4 | [Molecular Formula]
C14H16Cl2Rh2 8* | [MDL Number]
MFCD00198060 | [MOL File]
12257-42-0.mol | [Molecular Weight]
460.99 |
| Chemical Properties | Back Directory | [Appearance]
mustard yellow crystals | [Melting point ]
239-241°C (dec.) | [storage temp. ]
2-8°C
| [solubility ]
sol chloroform and benzene; insol ether and light petroleum | [form ]
Powder | [color ]
yellow to orange | [Water Solubility ]
Slightly soluble in acetone, chloroform, methanol and insoluble in water. | [Exposure limits]
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 | [InChI]
InChI=1/2C7H8.2ClH.2Rh/c2*1-2-7-4-3-6(1)5-7;;;;/h2*1-4,6-7H,5H2;2*1H;;/q;;;;2*+1/p-2/t2*6-,7+;;;; | [InChIKey]
RXDWVIOULPVOEO-SEGRDSFWNA-L | [SMILES]
[C@@]12([H])[CH][CH][C@]([CH][CH]1)([H])C2.[C@@]12([H])[CH][CH][C@@]([H])([CH][CH]1)C2.Cl[Rh].Cl[Rh] |&1:0,4,9,13,r,^1:2,3,5,6,11,12,15,16| |
| Hazard Information | Back Directory | [Chemical Properties]
mustard yellow crystals | [Uses]
Di-μ-chlorobis(norbornadiene)dirhodium(I) is used as catalysts in olefin hydroformylation, olefin hydrogenation and olefin isomerization | [Preparation]
Bis(bicyclo[2.2.1]hepta-2,5- diene)dichlorodirhodium is prepared by reacting rhodium(III) Chloride and bicyclo[2.2.1]hepta-2,5-diene in aq ethanol, when shaken for 2 days, give a yellow deposit.
| [reaction suitability]
core: rhodium
reagent type: catalyst | [Purification Methods]
It recrystallises from hot CHCl3/pet ether as fine crystals soluble in CHCl3 and *C6H6 but is almost insoluble in Et2O or pet ether. [Abel et al. J Chem Soc 3178 1959.] |
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