| Identification | More | [Name]
Tris(triphenylphosphine)ruthenium(II) chloride | [CAS]
15529-49-4 | [Synonyms]
DICHLOROTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENATE (II)
DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
DICHLOROTRIS(TRIPHENYLPHOSPHINO)RUTHENIUM (II)
RUTHENIUM DICHLOROTRIS(TRIPHENYLPHOSPHINE)
RUTHENIUM(II)-TRIS(TRIPHENYLPHOSPHINE) DICHLORIDE
TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(2) DICHLORIDE
TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) CHLORIDE
TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) DICHLORIDE
dichlorotris(triphenylphosphine)ruthenium
Dichlorotris(triphenylphosphine)ruthenium(II),99%
dichlorotris(triphenylphosphine)ruthenium(ii), premion
DICHLOROTRIS(TRIPHENYLPHOSPHINO)RUTHENIUM(II) (10% RU)
TRIS(TRIPHENYLPHOSPHINE) RUTHENIUM II
Dichlorotris(triphenylphosphine)ruthenium(II), Premion(R), 99.95% (metals basis), Ru 10.2% min
Dichlorotris(triphenylphosphine)ruthenium(II) Dissociates in solution
Dichlorotris(triphenylphosphine)ruthenium(II), Premion, 99.95% (metals basis), Ru 10.2% min
Ruthenium chloride triphenyl phosphine
Dichlorotris(triphenylphosphine)ruthenium(II), Ruthenium(II)-tris(triphenylphosphine) dichloride | [EINECS(EC#)]
239-569-7 | [Molecular Formula]
C54H45Cl2P3Ru | [MDL Number]
MFCD00013077 | [Molecular Weight]
958.83 | [MOL File]
15529-49-4.mol |
| Chemical Properties | Back Directory | [Appearance]
black crystals | [Melting point ]
159 °C | [storage temp. ]
Refrigerator | [solubility ]
Very slightly soluble (with dissociation) in acetone, alcohol, chloroform, ethyl acetate, and toluene | [form ]
Solution | [color ]
Clear | [Water Solubility ]
insoluble | [Hydrolytic Sensitivity]
8: reacts rapidly with moisture, water, protic solvents | [Sensitive ]
Air & Moisture Sensitive | [BRN ]
4935939 | [InChI]
InChI=1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2 | [InChIKey]
QUVLSIIMVTXAPD-UHFFFAOYSA-M | [SMILES]
P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Ru](Cl)Cl | [CAS DataBase Reference]
15529-49-4(CAS DataBase Reference) | [Storage Precautions]
Air sensitive;Store under inert gas;Moisture sensitive |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R20/21:Harmful by inhalation and in contact with skin . | [Safety Statements ]
S36/37:Wear suitable protective clothing and gloves .
S22:Do not breathe dust . | [RIDADR ]
2811 | [WGK Germany ]
3
| [TSCA ]
No | [HS Code ]
28439000 | [Storage Class]
11 - Combustible Solids |
| Hazard Information | Back Directory | [Chemical Properties]
black crystals | [Uses]
Dichlorotris(triphenylphosphine)ruthenium(II) serves as a precatalyst for the hydrogenation of alkenes, nitro compounds, ketones, carboxylic acids, synthesis of furans from allenyl sulfides and C-H Activation Catalyst in a Ruthenium/Lewis Acid System | [Uses]
suzuki reaction | [Preparation]
Tris(triphenylphosphine)ruthenium(II) chloride can be prepared by refluxing hydrated Ruthenium(III) Chloride and Triphenylphosphine in ethanol according to the procedure of Wilkinson. | [General Description]
Tris(triphenylphosphine)ruthenium(II) chloride can be used in the hydrogenation of nitro groups, imines, and ketones, and the selective oxidation of alcohols. | [reaction suitability]
core: ruthenium
reagent type: catalyst
reaction type: C-H Activation |
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