| Identification | Back Directory | [Name]
Dichloro(p-cymene)ruthenium(II) dimer | [CAS]
52462-29-0 | [Synonyms]
CyMene Ru dichloride diMer
Dichloro(p-cyMene)rutheniuM(II
Dichloro(p-cymene)ruthenium dimer
Bis(p-cymene) tetrachloro ruthenium
Dichloro(p-cymene)ruthenium(Ⅱ) dimer
Tetrachlorobis-(4-cymene)-diruthenium
DICHLORO(P-CYMENE)RUTHENIUM(II) DIMER
P-cyMenerutheniuM chloridediMertwotwo
P-CYMENE RUTHENIUM (II) CHLORIDE DIMER
P-CYMENERUTHENIUM(II) DICHLORIDE DIMER
DichlorobispcymenechlororutheniumIImin
Dichloro(p-cymene)ruthenium(II)dimer,98%
Dichlorobis(p-cymene)ruthenium(II) dimer
Dichloro(p-cymene)ruthenium(II) dimer 97%
Dichloro(p-cymene)ruthenium(II) dimmer,98%
bis(p-cymene)diruthenium(ii) tetrachloride
DI-MU-CHLOROBIS[(P-CYMENE)CHLORO-RUTHENIUM]
Di-?chlorobis[(p-cymene)chlororuthenium(II)]
Di-mu-chloro-bis[chloro(p-cymene)ruthenium[]
Dichloro(p-cyMene)rutheniuM(Ⅱ) diMer, 33% Ru
Dichloro(p-cyMene)rutheniuM(II) diMer
Di-m-chlorobis[(p-cymene)chlororuthenium(II)]
Di-mu-chloro-bis[chloro(p-cymene)ruthenium[Ⅱ]
DI-MU-CHLOROBIS[(P-CYMENE)CHLORORUTHENIUM(II)]
Di-u-chlorobis[(p-cymene)chloro Ruthenium(II)]
(p-Cymene)ruthenium(II) chloride dimer Benzene
1-methyl-4-(1-methylethyl)-, ruthenium complex
Di-μ-chlorobis(p-cymene)chlororuthenium(II),98%
DI-MU-CHLORO-BIS[CHLORO(P-CYMENE)RUTHENIUM(II)]
DI-MY-CHLORO-BIS[(P-CYMENE)CHLORORUTHENIUM(II)]
Di-micron-chlorobis(p-cymene)chlororuthenium(II)
Di-á-chlorobis(p-cyMene)chlororutheniuM(II), 98%
Di-chlorobis(p-cyMene)chlororutheniuM(II), 98% 1GR
Dichloro(p-cymene)ruthenium(II) dimer ,98% [33% Ru]
Di-mu-chlorobis[(p-cymene)chlororuthenium(II)],min.98%
DI--CHLOROBIS[(P-CYMENE)CHLORORUTHENIUM(II)] (33% RU)
Benzene, 1-methyl-4-(1-methylethyl)-, ruthenium complex
Di-mu-chlorobis (p-cymene)chlororuthenium (II) , min. 98%
Di-μ-chlorobis[(p-cyMene)chlororutheniuM(II)],[Ru(p-cyMene)Cl2]2
Dichloro(p-cyMene)rutheniuM(Ⅱ) diMer, 33% Ru, Product of UMicore
Di-μ-chlorobis[(p-cyMene)chlororutheniuM(II)],98% [Ru(p-cyMene)Cl2]2
p-Cymeneruthenium(II) Dichloride Dimer
Di-mu-chloro-bis[chloro(p-cymene)ruthenium(II)]
RutheniuM, di-M-chlorodichlorobis[(1,2,3,4,5,6-h)-1-Methyl-4-(1-Methylethyl)benzene]di-
Bis(p-cymene)diruthenium(II) tetrachloride~Di-mu-chlorobis[(p-cymene)chlororuthenium(II)]
RutheniuM, di-.Mu.-chlorodichlorobis[(1,2,3,4,5,6-.eta.)-1-Methyl-4-(1-Methylethyl)benzene]di- | [EINECS(EC#)]
435-530-5 | [Molecular Formula]
C20H28Cl4Ru2 | [MDL Number]
MFCD00064793 | [MOL File]
52462-29-0.mol | [Molecular Weight]
612.39 |
| Questions And Answer | Back Directory | [Synthesis]
Dissolving the compound in water led to the spontaneous formation of the bridged structure XXI. The structure is Dichloro(p-cymene)ruthenium(II) dimer. ¹H NMR (CDCl₃): 7.27 (s, 2H, NHC), 7.05 (s, 1H, NHS), 5.86 (m, 2H, cymene), 5.57 (d, 2H), 5.51 (d, 1H, cymene), 5.24 (d, 2H, cymene), 4.51 (bs, 2H and CH₂), 4.11 (bs, 1H and CH₂), 3.50 (s, 6H, Me), 2.82 (m, 1H, iPr), 2.63 (m, 3H, CH₂), 2.02 (m, 1H and CH₂), 1.86 (s, Me), 1.26 (d, 12H, iPr). The synthetic route is shown in Figure 1.
 Figure: Synthetic route of Dichloro(p-cymene)ruthenium(II) dimer |
| Chemical Properties | Back Directory | [Appearance]
red-orange to red-brown crystals or powder | [Melting point ]
247.0-250.0 °C (dec.)(lit.)
| [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
Chloroform (Sparingly), Ethyl Acetate (Sparingly) | [form ]
Powder | [color ]
brown | [Water Solubility ]
insoluble | [Stability:]
Light Sensitive | [InChI]
InChI=1S/2C10H14.4ClH.2Ru/c2*1-8(2)10-6-4-9(3)5-7-10;;;;;;/h2*4-8H,1-3H3;4*1H;;/q;;;;;;2*+2/p-4 | [InChIKey]
HDIYUTHATPCURB-UHFFFAOYSA-L | [SMILES]
C1(C(C)C)C=CC(C)=CC=1.C1(C(C)C)=CC=C(C)C=C1.[Ru](Cl)Cl.[Ru](Cl)Cl |
| Hazard Information | Back Directory | [Chemical Properties]
red-orange to red-brown crystals or powder | [Uses]
Hydrosilylation Catalysts
Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Cyclometalated ruthenium complexes with arylimines and nitrogen-containing heterocycles via C-H bond activation | [General Description]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information. | [reaction suitability]
reagent type: catalyst |
|
| Company Name: |
J & K SCIENTIFIC LTD.
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| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
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| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Jia Xing Isenchem Co.,Ltd
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| Telephone: |
0573-85285100 18627885956 |
| Website: |
https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm |
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