ChemicalBook--->CAS DataBase List--->131-22-6

131-22-6

131-22-6 Structure

131-22-6 Structure
IdentificationMore
[Name]

4-PHENYLAZO-1-NAPHTHYLAMINE
[CAS]

131-22-6
[Synonyms]

4-BENZENE-AZO-ALPHA-NAPTHYLAMINE
4-PHENYLAZO-1-NAPHTHYLAMINE
ALPHA-NAPHTHYL RED
A-NAPHTHYL RED
AURORA KA-7777
BENZENEAZO-1-NAPHTHYLAMINE
CI NO 11350
NAPHTHYL RED
SOLVENT YELLOW 4
1-Amino-4-phenylazonaphthalene
1-Naphthalenamine, 4-(phenylazo)-
1-Naphthylamine, 4-(phenylazo)-
4-(phenylazo)-1-naphthalenamin
4-[(E)-Phenyldiazenyl]-1-naphthalenamine
4-Benzeneazo-1-naphthylamine
4-Benzene-azo-alpha-naphthylamine
BNA
C.I. Solvent Yellow 4
c.i.solventyellow4
C.I.SolventYellow4(11350)-Naphthylred
[EINECS(EC#)]

205-018-4
[Molecular Formula]

C16H13N3
[MDL Number]

MFCD00004025
[Molecular Weight]

247.29
[MOL File]

131-22-6.mol
Chemical PropertiesBack Directory
[Melting point ]

124°C
[Boiling point ]

380.33°C (rough estimate)
[density ]

1.1633 (rough estimate)
[refractive index ]

1.6470 (estimate)
[solubility ]

Solubility Virtually insoluble in water; slightly soluble in ethanol; soluble in acetone, benzene,ethyl acetate, toluene, xylene
[Colour Index ]

11350
[form ]

crystals
[pka]

2.70(at 25℃)
[color ]

Dark red
[PH Range]

Red (3.7) to yellow (5.0)
[λmax]

439nm
[Major Application]

Display device, semiconductor, sensors, photosensitive materials, recording materials, fooding materials, imaging materials, inks, engraving coatings, lubricants, hair dyes, food storage, dental materials
[CAS DataBase Reference]

131-22-6(CAS DataBase Reference)
[EPA Substance Registry System]

1-Naphthalenamine, 4-(phenylazo)- (131-22-6)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[RTECS ]

QJ0360000
[TSCA ]

TSCA listed
[HS Code ]

2927.00.5000
[Toxicity]

mma-sat 500 mg/plate AEMIDF 42,641,81
Raw materials And Preparation ProductsBack Directory
[Raw materials]

1-Naphthylamine-->methyl benzenediazoate-->4-(phenylazo)-1-naphthol-->benzenediazonium-->Phenyl azide-->Diethyl ether-->Water-->Sulfuric acid-->Hydroxylamine-->Aniline-->Ethanol-->Nitrobenzene-->Ammonia-->Aniline-->1-Naphthylamine
[Preparation Products]

pentamethylphenol-->1,4-Diaminonaphthalene-->AZOCARMINE G
Hazard InformationBack Directory
[Uses]

4-PHENYLAZO-1-NAPHTHYLAMINE is used as acid-base indicator. pH 4.0 (red) to 5.0 (orange).
[Preparation]

aniline diazotization, and Naphthalen-1-amine coupling.
[Safety Profile]

Mutation data reported. When heated to decomposition it emits toxic vapors of NOx.
[Properties and Applications]

brilliant red light yellow to brilliant yellow orange (mineral oil). Red acicular crystal, melting point 123 ℃. Soluble in alcohol and benzene. In concentrated sulfuric acid for magenta; After dilution for red light brown, precipitation, At 2% hot hydrochloric acid solution for magenta solution, there are residues. Dye alcohol solution to join concentrated sodium hydroxide solution for yellow brown. Used for oil, paraffin wax, paint color.
Standard Light Fastness Heat-resistant(℃) Water Sodium Carbonate(5%) Hydrochloric acid(5%)
Melting point Stable
ISO Well 109 75 Insoluble No change Poor
[Purification Methods]

Crystallise the dye from cyclohexane or aqueous EtOH. [Brode et al. J Am Chem Soc 74 4641 1952, Beilstein 16 H 361, 16 III 406, 16 IV 546.]
Spectrum DetailBack Directory
[Spectrum Detail]

4-PHENYLAZO-1-NAPHTHYLAMINE(131-22-6)MS
4-PHENYLAZO-1-NAPHTHYLAMINE(131-22-6)IR1
4-PHENYLAZO-1-NAPHTHYLAMINE(131-22-6)IR2
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

131-22-6(sigmaaldrich)
[TCI AMERICA]

4-Phenylazo-1-naphthylamine,>95.0%(T)(131-22-6)
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