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Phenyl azide

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Phenyl azide manufacturers

  • PHENYL AZIDE
  • PHENYL AZIDE pictures
  • $1000.00
  • 2026-02-02
  • CAS:622-37-7
  • Purity: 98%HPLC
  • Supply Ability: 2tons
Phenyl azide Basic information
Product Name:Phenyl azide
Synonyms:Azidomethane solution - 0.5M solution intert-butyl methyl ether;Azidobenzene solution ~0.5 M in 2-methyltetrahydrofuran, >=95.0% (HPLC);Azido-benzene;Benzene, triazo-;Azidobenzene solution;Phenyl azide solution;diazobenzeneimide;phenylazoimide
CAS:622-37-7
MF:C6H5N3
MW:119.12
EINECS:210-730-3
Product Categories:Aromatic Azides;Azides;Building Blocks;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks
Mol File:622-37-7.mol
Phenyl azide Structure
Phenyl azide Chemical Properties
Melting point -27.5°C
Boiling point 212.39°C (rough estimate)
density 1.0860
vapor density 73.5 at 22-24 mm
refractive index 1.5589
Fp -12°C
storage temp. -20°C
form liquid
color Pale-yellow oil
BRN 742248
InChIInChI=1S/C6H5N3/c7-9-8-6-4-2-1-3-5-6/h1-5H
InChIKeyCTRLRINCMYICJO-UHFFFAOYSA-N
SMILESC1(N=[N+]=[N-])=CC=CC=C1
Safety Information
Hazard Codes F,Xn
Risk Statements 11-19-48/20/21/22-38
Safety Statements 16
RIDADR UN 2398 3 / PGII
WGK Germany 3
Storage Class3 - Flammable liquids
Hazard ClassificationsAcute Tox. 4 Oral
Eye Dam. 1
Flam. Liq. 2
Skin Irrit. 2
STOT RE 2
MSDS Information
Phenyl azide Usage And Synthesis
UsesPhenylazide in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
Synthesis Reference(s)Journal of the American Chemical Society, 89, p. 5284, 1967 DOI: 10.1021/ja00996a036
Tetrahedron Letters, 27, p. 4749, 1986 DOI: 10.1016/S0040-4039(00)85055-8
General DescriptionAzidobenzene solution can undergo click reaction with alkyne-functionalized oligomers to form O-ester-functionalized o-phenylenes, a group of aromatic foldamers with a good folding tendency in most solvents.
Safety ProfileExplodes when heated.Explosive or violent reactions with Lewis acids [e.g., aluminum chloride (explosive); sulfuric acid (violent)]. When heated to decomposition it emits toxic fumes of NOx.
Tag:Phenyl azide(622-37-7) Related Product Information
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