| Identification | More | [Name]
Sulphur Black 1 | [CAS]
1326-82-5 | [Synonyms]
2,4-Dinitro-phenol sulfurised
c.i. 53185
Sulphur Black 1
Phenol, 2,4-dinitro-, sulfurized
Sulfur Black 1, Unsolubilized
SulfurblackBR
Sulfur black 1 (C.I. 53185)
SURLFBLACK
Black BR/B
C.I. Sulfur Black 1
Sulphur Black B
Asathio Black D-BS
Atul Sulphur Black GXE
Duasyn Thiocarbon CMR
Kayaku Sulphur Black B
Nissen Black B
Rifa Sulphur Black BR
Sulphur Black B521
Sulphur Black BN
Sulphur Black BRN. | [EINECS(EC#)]
215-444-2 | [Molecular Formula]
C6H4N2O5 | [MDL Number]
MFCD01770808 | [Molecular Weight]
184.11 | [MOL File]
1326-82-5.mol |
| Hazard Information | Back Directory | [Chemical Properties]
Black powder. Insoluble in water and ethanol. Dissolves in sodium sulfide solution to a dark green color; in hydrochloric acid to a greenish black precipitate; in sodium hydroxide solution to a blue color. Dissolves slightly in concentrated sulfuric acid when cold, but darkens to a greenish blue precipitate upon heating. Continued heating turns the precipitate dark blue, and dilution yields a greenish blue precipitate. The dyed material exhibits a yellowish olive color in an alkaline sodium hydrosulfite solution, which returns to its original color upon oxidation. It completely fades in sodium hypochlorite solution. | [Uses]
Sulphur Black 1 is a commonly used dye for dyeing cotton, linen, viscose fibers and their fabrics black. It has good dyeing rate and levelness. It is also used for dyeing vinylon/cotton blended fabrics and vinylon. It can also be blended with sulfur vat black (CLG) to achieve a jet black color. | [Definition]
ChEBI: 2,4-dinitrophenol is a dinitrophenol having the nitro groups at the 2- and 4-positions. It has a role as an oxidative phosphorylation inhibitor, a bacterial xenobiotic metabolite, an antiseptic drug, an allergen and a geroprotector. It is a conjugate acid of a 2,4-dinitrophenol(1-). | [Preparation]
2,4-Dinitrophenol?or its Sodium salt (by 1-Chloro-2,4-dinitrobenzene alkaline hydrolysis) and Sodium polysulfide heating, in 110 ~ 120 ℃ reflux heating 48 to 72 hours, or in 130 ~ 140 ℃ under pressure to short time heating, then dilution melt, adding acid or air oxidation make dye completely precipitated out. In the molten material to the intermediate Sodium polysulfide proportion must be appropriate, such ability in reaction end solution almost no dye residual. According to dye the preparation process of the use conditions, has determined the empirical formula is C24H16N6O8S7 orC24H16N6O8S8 | [Properties and Applications]
green black and blue black. Black uniform powder. Insoluble in water and Etanol. In the Sodium sulfide solution solubility is good, for green black; Add Sodium hydroxide and Sodium sulfide solution of colour and lustre is blue; Add hydrochloric acid Sodium sulfide solution to have green black precipitation; In the cold part of concentrated sulfuric acid solution, after heating for deep green light blue, further heating into dark blue; In 25% of fuming sulfuric acid for black blue, dilution after green black precipitation. Dyeing content in alkaline insurance powder solution for yellow olive, after oxidation can restore the original colour and lustre; In Sodium hypochlorite solution all fade, join concentrated sulfuric acid no effect. Mainly used for cotton, vinylon/cotton blended fabric dyeing, and can also be used to hemp, viscose fiber dyeing.
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Standard
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Acid Resistance
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Alkali Resistance
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Light Fastness
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Fulling
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Persperation Fastness
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Soaping
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Moderate
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Severe
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|
ISO
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4-5
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4-5
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6-7
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4-5
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5
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5
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4-5
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AATCC
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5
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5
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6-7
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4
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|
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4-5
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|
|
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