| Identification | Back Directory | [Name]
(R)-3-(tert-butyl)-4-(2,6-di
methoxyphenyl)-2,3-dihyd
robenzo[d][1,3]oxaphosph
ole | [CAS]
1338454-03-7 | [Synonyms]
(R)-4-(2,6-Dimethoxyphenyl)-3-(tert-butyl)-2,3-dihydro-1,3-benzoxaphosphole
(R)-3-(tert-butyl)-4-(2,6-di
methoxyphenyl)-2,3-dihyd
robenzo[d][1,3]oxaphosph
ole | [Molecular Formula]
C19H23O3P | [MDL Number]
MFCD31630704 | [MOL File]
1338454-03-7.mol | [Molecular Weight]
330.36 |
| Chemical Properties | Back Directory | [Boiling point ]
422.1±45.0 °C(Predicted) | [storage temp. ]
Inert atmosphere,2-8°C | [form ]
crystal | [color ]
light-yellow | [Optical Rotation]
192.575°(C=0.8629g/100mL, CHCL3, 20°C, 589nm) | [InChI]
InChI=1S/C19H23O3P/c1-19(2,3)23-12-22-16-11-6-8-13(18(16)23)17-14(20-4)9-7-10-15(17)21-5/h6-11H,12H2,1-5H3/t23-/m0/s1 | [InChIKey]
BWPDUHMFZCEKIP-QHCPKHFHSA-N | [SMILES]
O1C2=CC=CC(C3=C(OC)C=CC=C3OC)=C2[P@@](C(C)(C)C)C1 |
| Questions And Answer | Back Directory | [Reaction]
- Ligand/palladium catalyst for asymmetric Suzuki-Miyaura cross-coupling reactions.
- Ligand/nickel catalyst for asymmetric intramolecular reductive cyclization
- Ligand/rhodium catalyst for asymmetric hydroboration
|
| Hazard Information | Back Directory | [Uses]
(R)-BIDIME is a P-chiral monophosphorus ligand used for the transition metal-catalyzed asymmetric Suzuki-Miyaura and hydroboration reactions. | [reaction suitability]
reagent type: ligand |
|
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
LaaJoo
|
| Tel: |
021-60702684 18516024827 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList20079/0_EN.htm |
| Company Name: |
3A Chemicals
|
| Tel: |
400-668-9898 |
| Website: |
www.3achem.com |
|