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1807740-34-6

1807740-34-6 Structure

1807740-34-6 Structure
IdentificationBack Directory
[Name]

(S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole
[CAS]

1807740-34-6
[Synonyms]

(S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole
[Molecular Formula]

C25H23O3P
[MDL Number]

MFCD31630706
[MOL File]

1807740-34-6.mol
[Molecular Weight]

370.42
Chemical PropertiesBack Directory
[Boiling point ]

525.7±50.0 °C(Predicted)
[storage temp. ]

Inert atmosphere,2-8°C
[form ]

crystal
[color ]

light yellow
[Sensitive ]

air sensitive, store cold
[InChI]

InChI=1S/C25H23OP/c1-25(2,3)27-16-26-22-14-8-13-21(24(22)27)23-19-11-6-4-9-17(19)15-18-10-5-7-12-20(18)23/h4-15H,16H2,1-3H3/t27-/m1/s1
[InChIKey]

HKAWVLHXUZNLPP-HHHXNRCGSA-N
[SMILES]

O1C2=CC=CC(C3C4=CC=CC=C4C=C4C=3C=CC=C4)=C2[P@](C(C)(C)C)C1
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302
[Precautionary statements ]

P501-P270-P264-P301+P312+P330
[WGK Germany ]

WGK 3
[HS Code ]

2931499090
[Storage Class]

11 - Combustible Solids
Questions and Answers (Q&A)Back Directory
[Reactions]

1. Ligand/palladium catalyst for general Miyaura borylation reactions.
2. Ligand/palladium catalyst for general and sterically demanding Suzuki-Miyaura cross-coupling reactions.
3. Ligand/palladium catalyst for aryl-alkyl Suzuki-Miyaura cross-coupling reactions.
4. Ligand/nickel catalyst for intramolecular reductive cyclization’
5. Ligand/palladium catalyst for Dearomative cyclization’ Reactions of 1807740-34-6
Hazard InformationBack Directory
[Uses]

(S)-AntPhos is a P-chiral monophosphorus ligand used for the asymmetric Suzuki-Miyaura and Miyaura borylation reactions. This ligand is uniquely effective for sterically hindered cross-coupling reactions.
[reaction suitability]

reagent type: ligand
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