| Identification | Back Directory | [Name]
(R)-4-(anthracen-9-yl)-3-(t
ert-butyl)-2,3-dihydrobenz
o[d][1,3]oxaphosphole | [CAS]
1456816-37-7 | [Synonyms]
(R)-4-(anthracen-9-yl)-3-(t
ert-butyl)-2,3-dihydrobenz
o[d][1,3]oxaphosphole | [Molecular Formula]
C25H23O3P | [MDL Number]
MFCD31630705 | [MOL File]
1456816-37-7.mol | [Molecular Weight]
370.42 |
| Chemical Properties | Back Directory | [Boiling point ]
525.7±50.0 °C(Predicted) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
crystal | [color ]
light yellow | [Sensitive ]
air sensitive, store cold | [InChI]
1S/C25H23OP/c1-25(2,3)27-16-26-22-14-8-13-21(24(22)27)23-19-11-6-4-9-17(19)15-18-10-5-7-12-20(18)23/h4-15H,16H2,1-3H3 | [InChIKey]
HKAWVLHXUZNLPP-UHFFFAOYSA-N | [SMILES]
P1(COc2c1c(ccc2)c3c4c(cc5c3cccc5)cccc4)C(C)(C)C |
| Questions And Answer | Back Directory | [Reaction]
- Ligand/palladium catalyst for general Miyaura borylation reactions.
- Ligand/palladium catalyst for general and sterically demanding Suzuki-Miyaura cross-coupling reactions.
- Ligand/palladium catalyst for aryl-alkyl Suzuki-Miyaura cross-coupling reactions.
- Ligand/nickel catalyst for intramolecular reductive cyclization.
- Ligand/palladium catalyst for Dearomative cyclization.
|
| Hazard Information | Back Directory | [Uses]
(R)-AntPhos is a P-chiral monophosphorus ligand used for the asymmetric Suzuki-Miyaura and Miyaura borylation reactions. This ligand is uniquely effective for sterically hindered cross-coupling reactions. | [reaction suitability]
reagent type: ligand |
|
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Energy Chemical
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