| Identification | More | [Name]
TITANIUM(III) FLUORIDE | [CAS]
13470-08-1 | [Synonyms]
TITANIUM FLUORIDE
TITANIUM(III) FLUORIDE
TITANIUM(IV) FLUORIDE
TITANIUM TETRAFLUORIDE
TITANIUM TRIFLUORIDE
TiF3
Titanium fluoride (TiF3)
titaniumfluoride(tif3)
Titanium(III)fluoride,min.98%
Titanium(III)fluoride99%
Titanium(III) fluoride, min. 98%
Titanium(III) trifluoride
TSCS(13470-08-1) | [EINECS(EC#)]
236-732-4 | [Molecular Formula]
F3Ti | [MDL Number]
MFCD00042544 | [Molecular Weight]
104.86 | [MOL File]
13470-08-1.mol |
| Chemical Properties | Back Directory | [Appearance]
Red to brown crystalline powder | [Melting point ]
1200 °C | [Boiling point ]
1400 °C | [density ]
3.4 g/mL at 25 °C(lit.)
| [solubility ]
insoluble in H2O, dilute acid solutions, alkaline solutions | [form ]
Crystalline Powder | [color ]
Red to brown | [Specific Gravity]
3.4 | [Water Solubility ]
Sparingly soluble. It hydrolyses in water. | [Crystal Structure]
VF3 type | [Sensitive ]
Air & Moisture Sensitive | [crystal system]
Three sides | [Space group]
R3c | [Lattice constant]
| a/nm | b/nm | c/nm | α/o | β/o | γ/o | V/nm3 | | 0.543 | 0.543 | 1.364 | 90 | 90 | 120 | 0.3488 |
| [Exposure limits]
ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3 | [InChI]
1S/3FH.Ti/h3*1H;/q;;;+3/p-3 | [InChIKey]
NLPMQGKZYAYAFE-UHFFFAOYSA-K | [SMILES]
F[Ti](F)F | [CAS DataBase Reference]
13470-08-1(CAS DataBase Reference) | [EPA Substance Registry System]
Titanium fluoride (TiF3) (13470-08-1) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS05 | [Signal word ]
Danger | [Hazard statements ]
H314 | [Precautionary statements ]
P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | [Hazard Codes ]
C | [Risk Statements ]
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R34:Causes burns.
R32:Contact with acids liberates very toxic gas.
R14:Reacts violently with water. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3260 8/PG 2
| [WGK Germany ]
3
| [F ]
10 | [Hazard Note ]
Corrosive | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
28261990 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Eye Dam. 1
Skin Corr. 1B |
| Hazard Information | Back Directory | [Chemical Properties]
Red to brown crystalline powder | [Uses]
It is used as a laboratory chemicals & for manufacture of chemicals. | [Production Methods]
Titanium metal is hydrogenated at 600-700°C. It is then placed in a small nickel boat and inserted into the horizontal nickel tube (closed at one end). The hydride is fluorinated with gaseous HF. The open end of the tube has a cooling jacket and is sealed with picein to a copper cover. Two copper tubes are silver-soldered into the cover and serve as an inlet and outlet for the hydrogen; the inlet tube also contains a concentric silver tube for introducing HF. The output gases pass through an empty polyethylene bottle, a bubble counter filled with paraffin oil and a polyethylene trap to freeze excess HF gas. The closed end of the reaction tube is placed in a tubular furnace. The temperature is measured externally. After thoroughly flushing the apparatus with Hs, fluorination followed with a 1 4 mixture of H2 and HF for four to five hours. The HF flow is first started at a temperature above 200°C. The water temperature in the cooling jacket should be higher than 20°C to prevent condensation of the HF. After completion of the fluorination, the product is left to cool in a stream of hydrogen. The yield is 90%. | [reaction suitability]
core: titanium
reagent type: catalyst |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Spectrum Chemical Manufacturing Corp.
|
| Telephone: |
021-021-021-67601398-809-809-809 15221380277 |
| Website: |
www.spectrumchemical.com/oa_html/index.jsp?minisite=10020&respid=22372&language=us |
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
|