| Identification | More | [Name]
BIS(DICYCLOHEXYLPHOSPHINO)METHANE | [CAS]
137349-65-6 | [Synonyms]
BIS(DICYCLOHEXYLPHOSPHINO)METHANE
METHYLENEBIS(DICYCLOHEXYLPHOSPHINE)
1,2-Bis(dicyclohexylphosphino)methane
Bis(dicyclohexylphosphino)methane,min.97%
Bis(dicyclohexylphosphino)methane, 97+%
Bis(dicyclohexylphosphino)methane, min. 97% | [Molecular Formula]
C25H46P2 | [MDL Number]
MFCD00143763 | [Molecular Weight]
408.58 | [MOL File]
137349-65-6.mol |
| Chemical Properties | Back Directory | [Melting point ]
95-102 °C (lit.) | [Boiling point ]
511.2±20.0 °C(Predicted) | [form ]
crystal | [color ]
white | [Sensitive ]
Air Sensitive | [BRN ]
5340912 | [InChI]
1S/C25H46P2/c1-5-13-22(14-6-1)26(23-15-7-2-8-16-23)21-27(24-17-9-3-10-18-24)25-19-11-4-12-20-25/h22-25H,1-21H2 | [InChIKey]
OWFLJHJHQKHZJR-UHFFFAOYSA-N | [SMILES]
C1CCC(CC1)P(CP(C2CCCCC2)C3CCCCC3)C4CCCCC4 | [CAS DataBase Reference]
137349-65-6(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
UN1325 | [WGK Germany ]
3
| [F ]
10-23 | [HazardClass ]
4.1 | [PackingGroup ]
II | [HS Code ]
2931900090 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
Catalyst for:
- Ru/phosphine catalyzed anti-Markovnikov addition reactions
- Regioselective Suzuki coupling reactions
- Ru/phosphine catalyzed homogeneous hydrogenation reactons
- Mediated cross-coupling reactions
| [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
|
| Company Name: |
J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
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Alfa Aesar
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400-6106006 |
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http://chemicals.thermofisher.cn |
| Company Name: |
T&W GROUP
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021-61551611 13296011611 |
| Website: |
www.trustwe.com/ |
| Company Name: |
Sigma-Aldrich
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021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
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