| Identification | Back Directory | [Name]
Bis(diphenylphosphinophenyl)ether palladium (II) dichloride | [CAS]
205319-06-8 | [Synonyms]
Pd-117
bis(diphenylphosphinophenyl)etherpalladium(II)...
Dichloro[bis(diphenylphosphinophenyl)ether]palladium(II)
Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II)
cis-[Bis[2-(diphenylphosphino)phenyl] ether]dichloropalladium
Bis(diphenylphosphinophenyl)ether palladium (II) dichloride
Dichloro[bis(diphenylphosphinophenyl)ether]palladium(II), Pd 14.8% | [Molecular Formula]
C36H28Cl2OP2Pd | [MDL Number]
MFCD09953446 | [MOL File]
205319-06-8.mol | [Molecular Weight]
717.9 |
| Chemical Properties | Back Directory | [Appearance]
light yellow powder | [Melting point ]
243-250°C | [storage temp. ]
2-8°C | [form ]
Powder | [color ]
yellow | [Water Solubility ]
Insoluble in water. | [InChIKey]
VYOUBMJFTDMKRR-UHFFFAOYSA-L | [SMILES]
P(C1C=CC=CC=1)(C1=CC=CC=C1)C1=CC=CC=C1OC1C=CC=CC=1P(C1C=CC=CC=1)C1C=CC=CC=1.[Pd](Cl)Cl |
| Hazard Information | Back Directory | [Chemical Properties]
light yellow powder | [Uses]
Dichloro[bis(diphenylphosphinophenyl)ether]palladium(II) is used as a catalyst for cross-coupling reaction of 2-brom-1,3-dienes to prepare high stereoselectivity of conjugated Z,E dienes. |
| Questions And Answer | Back Directory | [Reaction]
- Stereoretentive palladium-catalyzed Kumada-Corriu couplings of alkenyl halides at room temperature.
- Highly selective reactions of unbiased alkenyl halides: Negishi-Plus couplings.
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