ChemicalBook--->CAS DataBase List--->14221-02-4

14221-02-4

14221-02-4 Structure

14221-02-4 Structure
IdentificationMore
[Name]

Tetrakis(triphenylphosphine)platinum
[CAS]

14221-02-4
[Synonyms]

PLATINUM-TETRAKIS(TRIPHENYLPHOSPHINE)
TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM
TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM(0)
Platinum(0)tetrakis(triphenylphosphine)
Tetrakis(triphenylphosphine)platinum(0),98%
( beta-4)-platinu
Tetrakis-(triphenylphosphino)-platinum
Tetrakis(triphenylphosphine)platinum(0), Pt 15.2% min
Platinum, tetrakis(triphenylphosphine)-, (T-4)-
[EINECS(EC#)]

238-087-4
[Molecular Formula]

C72H60P4Pt
[MDL Number]

MFCD00010014
[Molecular Weight]

1244.22
[MOL File]

14221-02-4.mol
Chemical PropertiesBack Directory
[Appearance]

yellow powder
[Melting point ]

122 °C
[storage temp. ]

0-6°C
[solubility ]

Soluble in benzene
[form ]

Liquid
[color ]

Clear
[Water Solubility ]

INSOLUBLE
[Sensitive ]

Air Sensitive
[InChI]

1S/4C18H15P.Pt/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;
[InChIKey]

SYKXNRFLNZUGAJ-UHFFFAOYSA-N
[SMILES]

[Pt].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12
[CAS DataBase Reference]

14221-02-4(CAS DataBase Reference)
[Storage Precautions]

Air sensitive;Light sensitive;Store under argon gas
[EPA Substance Registry System]

14221-02-4(EPA Substance)
Safety DataBack Directory
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[F ]

8-10-23
[TSCA ]

Yes
[HS Code ]

29310099
[Storage Class]

11 - Combustible Solids
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Tetrakis(triphenylphosphine)platinum(14221-02-4).msds
Hazard InformationBack Directory
[Chemical Properties]

yellow powder
[Uses]

Tetrakis(triphenylphosphine)platinum(0), Pt is widely used in hydrosilation and oxidation. In Catalysts, Metal & Specialty Catalysts, Products & Industries.
[reaction suitability]

core: platinum
reagent type: catalyst
[Purification Methods]

It forms yellow crystals on adding hexane to a cold saturated solution in *C6H6. It is soluble in *C6H6 and CHCl3 but insoluble in EtOH and hexane. A less pure product is obtained if it is crystallised by adding hexane to a CHCl3 solution. It is stable in air for several hours and completely stable under N2. [Malatesta & Cariello J Am Chem Soc 2323 1958, Beilstein 16 IV 955.]
Spectrum DetailBack Directory
[Spectrum Detail]

Tetrakis(triphenylphosphine)platinum(14221-02-4)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Tetrakis(triphenylphosphine)platinum(0), 98%(14221-02-4)
[Alfa Aesar]

Tetrakis(triphenylphosphine)platinum(0), Pt 15.2% min(14221-02-4)
[Sigma Aldrich]

14221-02-4(sigmaaldrich)
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