ChemicalBook--->CAS DataBase List--->146960-90-9

146960-90-9

146960-90-9 Structure

146960-90-9 Structure
IdentificationBack Directory
[Name]

1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
[CAS]

146960-90-9
[Synonyms]

1,1'-Bis(dicyclohexylphosphino
1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
1,1'-Bis(dicyclohexylphosphiNA)ferrocene
1,1'-Bis(dicyclohexylphosphino)ferrocene,98%
1,1'-Bis(dicyclohexylphosphino)ferrocene,Min.98%
1,1'-Bis(dicyclohexylphosphino)ferrocene, min. 98%
[EINECS(EC#)]

1533716-785-6
[Molecular Formula]

2C17H26P.Fe
[MDL Number]

MFCD09038820
[MOL File]

146960-90-9.mol
[Molecular Weight]

578.578
Chemical PropertiesBack Directory
[Melting point ]

134-136°C
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Powder
[color ]

orange
[InChI]

InChI=1S/2C17H22P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*15-16H,1-6,9-12H2;/q2*-1;+2
[InChIKey]

OYQDKNYBVNMMJN-UHFFFAOYSA-N
[SMILES]

P(C1CCCCC1)(C1CCCCC1)[C-]12C3=C4C5=C1[Fe+2]16782345C2C1=C6[C-]7(P(C1CCCCC1)C1CCCCC1)C8=2
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

22-24-26-36/37
[WGK Germany ]

3
[TSCA ]

No
[HS Code ]

2931499090
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Chemical Properties]

1,1'-Bis(dicyclohexylphosphino)ferrocene is stable under recommended storage conditions, it reacts with strong oxidizing agents.
[Uses]

1,1'-Bis(dicyclohexylphosphino)ferrocene is an orange to brown powder, it can be used as an organophosphine ligand.
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
Questions And AnswerBack Directory
[Reaction]

  1. Ligand for palladium-catalyzed synthesis of oxindoles by amide ɑ-arylation.
  2. Ligand for palladium-catalyzed alkoxycarbonylation of aryl chlorides.
  3. Ligand for ruthenium-catalyzed alcohol-allene C-C coupling reaction via hydrohydroxyalkylation of 1,1-disubstituted allenes employing alcohols.
  4. Ligand for nickel-catalyzed cross-coupling reaction of arylboronic acids with aryl carbonates.
  5. Ligand for palladium-catalyzed regiodivergent hydroesterification of aryl olefins with phenyl formate to form linear structured phenyl arylpropanoates.
  6. Ligand for palladium-catalyzed direct borylation of benzyl alcohol and its analogues in the absence of bases.
Reactions of 146960-90-9
Spectrum DetailBack Directory
[Spectrum Detail]

1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE(146960-90-9)1HNMR
1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE(146960-90-9)31PNMR
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