| Identification | More | [Name]
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) | [CAS]
14871-41-1 | [Synonyms]
BIS(TRIPHENYLPHOSPHINE)IRIDIUMCARBONYL CHLORIDE
BIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) CARBONYL CHLORIDE
CARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) CHLORIDE
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
CHLOROCARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM (I)
IRIDIUM(I)BIS(TRIPHENYLPHOSPHINE)CARBONYL CHLORIDE
VASKA'S COMPLEX
carbonylchlorobis(triphenylphosphine)-iridiu
carbonylchlorobis(triphenylphosphine)iridium
CARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I ) CHLORIDE, 99.99%
Chlorocarbonylbis(triphenylphosphine)iridium(I),99%VASKA'SCOMPLEX
vaska's catalyst
Bis-(triphenylphosphino)-iridium carbonyl chloride
Chlorocarbonylbis(triphenylphosphine)iridium(I), Iridium(I)bis(triphenylphosphine)carbonyl chloride | [EINECS(EC#)]
238-941-6 | [Molecular Formula]
C37H30ClIrOP2 | [MDL Number]
MFCD00009590 | [Molecular Weight]
780.25 | [MOL File]
14871-41-1.mol |
| Chemical Properties | Back Directory | [Appearance]
GREEN FINE CRYSTALLINE POWDER | [Melting point ]
215°C | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
Soluble in chloroform, toluene. Slightly soluble in acetone, alcohol | [form ]
crystal | [color ]
lemon yellow | [λmax]
385nm(lit.) | [InChI]
InChI=1S/2C18H15P.CO.ClH.Ir/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h2*1-15H;;1H;/q;;;;+1/p-1 | [InChIKey]
KMVALWICXMGTQO-UHFFFAOYSA-M | [SMILES]
P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.Cl[Ir].[O+]#[C-] | [CAS DataBase Reference]
14871-41-1(CAS DataBase Reference) | [EPA Substance Registry System]
Iridium, carbonylchlorobis(triphenylphosphine)- (14871-41-1) |
| Hazard Information | Back Directory | [Chemical Properties]
GREEN FINE CRYSTALLINE POWDER | [Uses]
Carbonylchlorobis(triphenylphosphine)iridium(I) is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs. | [Application]
Carbonylchlorobis(triphenylphosphine)iridium(I) can be used as a catalyst precursor for homogeneous hydrogenation, decarbonylation of acyl halides, hydrosilylation of olefins, and hydroboration. | [Preparation]
In a round-bottomed flask a mixture containing 3.52 g (10 mmol) of IrCl3.3H2O, 13.1 g (50 mmol) of PPh3, 4 mL of aniline, and 150 mL of DMF is heated under nitrogen at reflux for 12 h. After filtering the resulting redbrown solution hot, 300 mL of warm methanol is added rapidly and the mixture stirred. Upon cooling in an ice bath, yellow crystals of Carbonylchlorobis(triphenylphosphine)iridium(I) are collected on a filter and washed with 250 mL of methanol and then with 25 mL of diethyl ether (87-90%). |
| Questions And Answer | Back Directory | [Reaction]
- Catalyst for the intramolecular carbonylative [2+2+1] cycloaddition of allenynes.
- Catalyst for the selective hydrogenation of myrcene.
- Catalyst for silylation of ortho-functionalized aryl halides with hydrosilanes.
- Catalyst for synthesis of aldenamines from carboxamides by silane-reduction/dehydration under mild conditions.
- Hydrogen atom transfer catalyst for radical cyclizations.
- Complex for photocatalytic alkane dehydrogenation.
- Catalyst for chemoselective reductive nucleophilic addition to N-methoxyamides.
- Catalyst for chemoselective reductive alkynylation of tertiary amides.
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