| Identification | More | [Name]
2-CHLOROTHIOANISOLE | [CAS]
17733-22-1 | [Synonyms]
1-CHLORO-2-(METHYLTHIO)BENZENE
2-CHLOROPHENYL METHYL SULFIDE
2-CHLOROTHIOANISOLE
2-Chloro-alpha-toluenethiol
1-Chloro-2-(methylthio)benzene, 2-Chlorophenyl methyl sulphide
2-Chloro-1-(methylthio)benzene
2-CHLOROTHIOSANISOLE
2-Chlorobenzyl mercaptan, 97+%
Benzene, 1-chloro-2-(methylthio)-
2-CHLORO THIOANISOLE 99%
(2-chlorophenyl)(methyl)sulfane
1-(Methylthio)-2-chlorobenzene
1-Methylthio-2-chlorobenzene
Methyl (2-chlorophenyl) sulfide
Methyl [2-chlorophenyl] sulfide
Methyl 2-chlorophenyl sulfide
2-Chlorobenzyl thioalcohol | [Molecular Formula]
C7H7ClS | [MDL Number]
MFCD00040124 | [Molecular Weight]
158.65 | [MOL File]
17733-22-1.mol |
| Chemical Properties | Back Directory | [Boiling point ]
239-240 °C (lit.) | [density ]
1,22 g/cm3 | [refractive index ]
n20/D 1.608(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Sealed in dry,Room Temperature | [Appearance]
Colorless to light yellow Liquid | [Sensitive ]
Stench | [InChI]
1S/C7H7ClS/c1-9-7-5-3-2-4-6(7)8/h2-5H,1H3 | [InChIKey]
IHLDFHCSSCVPQW-UHFFFAOYSA-N | [SMILES]
CSc1ccccc1Cl | [CAS DataBase Reference]
17733-22-1(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
UN 3334 | [WGK Germany ]
3
| [Hazard Note ]
Irritant/Stench | [HazardClass ]
STENCH | [HS Code ]
2909309090 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
2-Chlorothioanisole may be used to synthesize 2-chlorophenyl methyl sulfone. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 48, p. 3114, 1983 DOI: 10.1021/jo00166a040 | [General Description]
2-Chlorothioanisole can be prepared from the reaction between N,N-dimethylformamide, 1,2-dichlorobenzene, finely ground KOH and methyl mercaptan. Benzene dipole moment value analysis of 2-chlorothioanisole indicates that it exists predominantly in trans- form. 1H NMR spectrum of 2-chlorothioanisole has been studied in acetone-d6 solution. |
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