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1806-29-7

1806-29-7 Structure

1806-29-7 Structure
IdentificationMore
[Name]

2,2'-Biphenol
[CAS]

1806-29-7
[Synonyms]

2,2'-BIPHENOL
2,2'-BIPHENYLDIOL
2,2'-DIHYDROXYBIPHENYL
2,2'-DIHYDROXYDIPHENYL
2,2'-DIPHENOL
BIPHENYL-2,2'-DIOL
O,O'-BIPHENOL
O,O'-DIHYDROXYBIPHENYL
O,O'-DIPHENOL
[1,1’-biphenyl]-2,2’-diol
2,2'-Dihydroxy-1,1'-biphenyl
Biphenyl, 2,2'-dihydroxy
o-Dihydroxydiphenyl
o,o-Biphenol~Biphenyl-2,2-diol~o,o-Diphenol
O,O'-Diphenole
2,2’-Biphenol (2,2’-Dihydroxybiphenyl)
2,2'-dihydroxybipphenol
ORTHOORTHOBIPHENOL
2,2''-BIPHENOL 99%
2,2μ-Biphenol, 2,2μ-Biphenyldiol, 2,2μ-Diphenol
[EINECS(EC#)]

217-303-0
[Molecular Formula]

C12H10O2
[MDL Number]

MFCD00002210
[Molecular Weight]

186.21
[MOL File]

1806-29-7.mol
Chemical PropertiesBack Directory
[Appearance]

Beige to greyish-beige powder
[Melting point ]

108-110 °C
[Boiling point ]

315 °C(lit.)
[density ]

0.83
[refractive index ]

1.6086 (estimate)
[Fp ]

154 °C
[storage temp. ]

Store below +30°C.
[form ]

Powder
[pka]

7.32±0.10(Predicted)
[color ]

Beige to grayish-beige
[Water Solubility ]

insoluble
[BRN ]

1638363
[InChI]

1S/C12H10O2/c13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14/h1-8,13-14H
[InChIKey]

IMHDGJOMLMDPJN-UHFFFAOYSA-N
[SMILES]

Oc1ccccc1-c2ccccc2O
[CAS DataBase Reference]

1806-29-7(CAS DataBase Reference)
[NIST Chemistry Reference]

[1,1'-Biphenyl]-2,2'-diol(1806-29-7)
[EPA Substance Registry System]

1806-29-7(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Exclamation Mark (GHS07)Skull and Crossbones (GHS06)
GHS05,GHS07,GHS06
[Signal word ]

Danger
[Hazard statements ]

H301-H319-H315-H318-H335-H302
[Precautionary statements ]

P261-P280-P305+P351+P338-P264-P270-P301+P312+P330-P302+P352+P332+P313+P362+P364-P305+P351+P338+P310-P501-P280i-P301+P310a-P321-P405-P501a
[Hazard Codes ]

Xi,Xn
[Risk Statements ]

R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
R36:Irritating to the eyes.
R22:Harmful if swallowed.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S39:Wear eye/face protection .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[WGK Germany ]

2
[RTECS ]

DV4200000
[F ]

8-9-23
[Autoignition Temperature]

324 °C
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29029090
[Storage Class]

11 - Combustible Solids
[Toxicity]

oms-hmn:lym 5 mmol/L CNREA8 45,2471,85
Hazard InformationBack Directory
[Chemical Properties]

Beige to greyish-beige powder
[Uses]

2,2'-Dihydroxybiphenyl, is an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff.
[Definition]

ChEBI: A member of the class of hydroxybiphenyls carrying hydroxy groups at positions 2 and 2'.
[Production Methods]

2,2'-Dihydroxybiphenyl is obtained by alkaline fusion of biphenylene oxide at ca. 300 ℃ (sometimes catalyzed by fluorene or carbazole) or by debutylation of 3,3',5,5'-tetra-tert-butyl-2,2'-dihydroxybiphenyl, which itself is produced by the oxidative coupling of 2,4-di-tert-butylphenol. 2,2'-Dihydroxy-5,5'-dimethylbiphenyl can be synthesized accordingly.
[Safety Profile]

Poison by intraperitoneal andintravenous routes. Human mutation data reported. Whenheated to decomposition it emits acrid smoke andirritating fumes.
[Purification Methods]

Crystallise the biphenyl repeatedly from toluene, then sublime it at 60o/10-4mm. [Beilstein 6 IV 6645.]
Spectrum DetailBack Directory
[Spectrum Detail]

2,2'-Biphenol(1806-29-7)MS
2,2'-Biphenol(1806-29-7)1HNMR
2,2'-Biphenol(1806-29-7)13CNMR
2,2'-Biphenol(1806-29-7)IR1
2,2'-Biphenol(1806-29-7)IR2
2,2'-Biphenol(1806-29-7)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2,2'-Biphenol, 99%(1806-29-7)
[Alfa Aesar]

2,2'-Dihydroxybiphenyl, 99%(1806-29-7)
[Sigma Aldrich]

1806-29-7(sigmaaldrich)
[TCI AMERICA]

2,2'-Biphenol,>98.0%(GC)(1806-29-7)
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