ChemicalBook--->CAS DataBase List--->21050-13-5

21050-13-5

21050-13-5 Structure

21050-13-5 Structure
IdentificationMore
[Name]

Bis(triphenylphosphine)iminium chloride
[CAS]

21050-13-5
[Synonyms]

BIS(TRIPHENYLPHOSPHINE)IMINIUM CHLORIDE
BIS(TRIPHENYLPHOSPHINE)IMINIUMHLORIDE
BIS(TRIPHENYLPHOSPHORANYLIDENE)AMMONIUM CHLORIDE
HEXAPHENYLDIPHOSPHAZENIUM CHLORIDE
PHOSPHORUS(1+), TRIPHENYL(P,P,P-TRIPHENYLPHOSPHINEIMIDATO-KN)-, CHLORIDE, (T-4)-
PPNCI
Bis(triphenylphosphine)iminium chloride~PPNCl
triphenyl(P,P,P-triphenylphosphine imidato)phosphorus(1+) chloride
Bis(Triphenylphosphoranylidene)AmmoniumChloride97%
Bis(triphenylphosphine)iminiumchloride,97%
ppncl
bis(triphenylphosphoranylidene)ammonium
Bis-(triphenylphosphino)-iminium chloride
Bis(triphenylphosphine)iminium chloride, Hexaphenyldiphosphazenium chloride, PPNCl
[EINECS(EC#)]

244-170-6
[Molecular Formula]

C36H34Cl2N2P2
[MDL Number]

MFCD00151523
[Molecular Weight]

627.52
[MOL File]

21050-13-5.mol
Chemical PropertiesBack Directory
[Melting point ]

270-272 °C(lit.)
[storage temp. ]

2-8°C
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Powder
[color ]

white
[Water Solubility ]

Moderately soluble in water.
[BRN ]

4097979
[InChI]

InChI=1S/C36H30ClNP2/c37-40(34-25-13-4-14-26-34,35-27-15-5-16-28-35,36-29-17-6-18-30-36)38-39(31-19-7-1-8-20-31,32-21-9-2-10-22-32)33-23-11-3-12-24-33/h1-30H
[InChIKey]

QMTYWEYUVVWPQL-UHFFFAOYSA-N
[SMILES]

P(Cl)(C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)N=P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1
[CAS DataBase Reference]

21050-13-5(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi,Xn
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R20:Harmful by inhalation.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S38:In case of insufficient ventilation, wear suitable respiratory equipment .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S22:Do not breathe dust .
[WGK Germany ]

3
[F ]

10
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Inhalation
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

Co-catalyst used with a chiral Cobalt-salen complex for the asymmetric addition of carbon dioxide to propylene oxide. Also used in the preparation of 5-Hydroxy-clethodim Sulfoxide.
[Uses]

suzuki reaction
[General Description]

Visit our Sensor Applications portal to learn more.
Spectrum DetailBack Directory
[Spectrum Detail]

Bis(triphenylphosphine)iminium chloride(21050-13-5)1HNMR
Bis(triphenylphosphine)iminium chloride(21050-13-5)IR1
Bis(triphenylphosphine)iminium chloride(21050-13-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Bis(triphenylphosphoranylidene)ammonium chloride, 97%(21050-13-5)
[Sigma Aldrich]

21050-13-5(sigmaaldrich)
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