ChemicalBook--->CAS DataBase List--->2142-69-0

2142-69-0

2142-69-0 Structure

2142-69-0 Structure
IdentificationMore
[Name]

2'-Bromoacetophenone
[CAS]

2142-69-0
[Synonyms]

1-(2-BROMOMPHENYL)ETHANONE
1-(2-BROMOPHENYL)ETHANONE
1-ACETYL-2-BROMOBENZENE
2'-BROMOACETOPHENONE
2-BROMOACETOPHENONE
AKOS BBS-00004325
ETHANONE, 1-(2-BROMOPHENYL)-
O-BROMOACETOPHENONE
O-BROMOPHENYL METHYL KETONE
Acetophenone, o-bromo-
o-bromoacetophnones
2'-Bromoacetophenone 1-(2-Bromophenyl)ethanone o-Bromoacetophenone
2-Bromoacetophenone,~97%
2'-BromoActophenone
2'-Bromoacetophenone
1-Acetyl-2-bromobenzene,o-Bromoacetophenone
1-(2-Bromophenyl)ethan-1-one
1-Bromo-2-acetylbenzene
2-Acetyl-1-bromobenzene
Methyl (2-bromophenyl) ketone
[EINECS(EC#)]

218-398-1
[Molecular Formula]

C8H7BrO
[MDL Number]

MFCD00000067
[Molecular Weight]

199.04
[MOL File]

2142-69-0.mol
Chemical PropertiesBack Directory
[Appearance]

Clear pale yellow to orange liquid
[Melting point ]

°C
[Boiling point ]

116-117 °C (12 mmHg)
[density ]

1.476 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.568(lit.)
[Fp ]

>230 °F
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

Liquid
[color ]

Clear pale yellow to orange
[Specific Gravity]

1.476
[Water Solubility ]

PRACTICALLY INSOLUBLE
[BRN ]

1931534
[InChI]

InChI=1S/C8H7BrO/c1-6(10)7-4-2-3-5-8(7)9/h2-5H,1H3
[InChIKey]

PIMNFNXBTGPCIL-UHFFFAOYSA-N
[SMILES]

C(=O)(C1=CC=CC=C1Br)C
[CAS DataBase Reference]

2142-69-0(CAS DataBase Reference)
[NIST Chemistry Reference]

Ethanone, 1-(2-bromophenyl)-(2142-69-0)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P280g-P305+P351+P338-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

UN 2645 (PHENACYL BROMIDE)
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HazardClass ]

6.1 (PHENACYL BROMIDE)
[PackingGroup ]

II (PHENACYL BROMIDE)
[HS Code ]

29147090
[Storage Class]

10 - Combustible liquids
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1-(2-Bromophenyl)ethanone(2142-69-0).msds
Hazard InformationBack Directory
[Chemical Properties]

Clear pale yellow to orange liquid
[Uses]

2-bromoacetophenone is employed in the selective derivatization of cytosine moieties for the determination of global DNA methylation by reversed phase high performance liquid chromatography with spectrofluorimetric detection.
[General Description]

2′-Bromoacetophenone (2-Bromoacetophenone) undergoes enantioselective addition reaction with phenylacetylene catalyzed by chiral camphorsulfonamide. It reacts with aliphatic primary amines in the presence of palladium catalyst to afford 3-methyleneisoindolin-1-ones.
[Synthesis]

Phenacyl bromide is an organic intermediate that can be obtained from acetophenone after direct bromination.

Spectrum DetailBack Directory
[Spectrum Detail]

2'-Bromoacetophenone(2142-69-0)MS
2'-Bromoacetophenone(2142-69-0)1HNMR
2'-Bromoacetophenone(2142-69-0)13CNMR
2'-Bromoacetophenone(2142-69-0)IR1
2'-Bromoacetophenone(2142-69-0)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2'-Bromoacetophenone, 98+%(2142-69-0)
[Alfa Aesar]

2'-Bromoacetophenone, 99%(2142-69-0)
[Sigma Aldrich]

2142-69-0(sigmaaldrich)
[TCI AMERICA]

2'-Bromoacetophenone,>98.0%(GC)(2142-69-0)
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