| Identification | More | [Name]
2'-Fluoroacetophenone | [CAS]
445-27-2 | [Synonyms]
1-(2-FLUOROPHENYL)ETHANONE
2'-FLUOROACETOPHENONE
2-FLUOROACETOPHENONE
LABOTEST-BB LT01148268
O-FLUOROACETOPHENONE
Ethanone, 1-(2-fluorophenyl)-
Fluoroacetophenone1
Fluoroacetophenonemincolorlessliq
2'-Flouoroacetophenone
2-Acetylfluorobenzene
2-Fluoroacetophenone,97%
2'-Fluoro
2'-Fluoroacetophenone 97% | [EINECS(EC#)]
207-156-0 | [Molecular Formula]
C8H7FO | [MDL Number]
MFCD00000320 | [Molecular Weight]
138.14 | [MOL File]
445-27-2.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless to light yellow or light green | [Melting point ]
26-27C | [Boiling point ]
187-189 °C(lit.)
| [density ]
1.137 g/mL at 20 °C(lit.)
| [refractive index ]
n20/D 1.507(lit.)
| [Fp ]
143 °F
| [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
Soluble in Acetone, Chloroform, Dichloromethane, Ethanol, Ethyl Acetate and Methanol. | [form ]
Liquid | [color ]
Clear colorless to yellow | [Specific Gravity]
1.121 | [BRN ]
2041344 | [InChI]
InChI=1S/C8H7FO/c1-6(10)7-4-2-3-5-8(7)9/h2-5H,1H3 | [InChIKey]
QMATYTFXDIWACW-UHFFFAOYSA-N | [SMILES]
C(=O)(C1=CC=CC=C1F)C | [CAS DataBase Reference]
445-27-2(CAS DataBase Reference) | [NIST Chemistry Reference]
o-Fluoroacetophenone(445-27-2) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319 | [Precautionary statements ]
P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
1993 | [WGK Germany ]
3
| [Hazard Note ]
Irritant | [REACH Registrations]
Active | [HazardClass ]
IRRITANT | [PackingGroup ]
III | [HS Code ]
29147090 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless to light yellow or light green | [Uses]
2'-Fluoroacetophenone is used as starting reagent in the synthesis of ascididemin. It is used to produce 1-(2-piperidin-1-yl-phenyl)-ethanone by reaction with piperidine. | [Synthesis Reference(s)]
Tetrahedron Letters, 31, p. 6179, 1990 DOI: 10.1016/S0040-4039(00)97018-7 | [General Description]
The enantioselective reduction of 2′-fluoroacetophenone has been investigated. | [Synthesis]
There are two methods to synthesize o-fluoroacetophenone, one is the reaction of α-bromoacetophenone with hydrogen fluoride in the presence of pyridine, and the other is the reaction of fluoroacetyl chloride with benzene in the presence of aluminum trichl |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
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| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
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