| Identification | More | [Name]
2,6-Diisopropylaniline | [CAS]
24544-04-5 | [Synonyms]
2,6-DIISOPROPYLANILINE
DIPA
2,6-bis(1-methylethyl)-benzenamin
2,6-bis(1-methylethyl)-Benzenamine
2,6-diisopropyl-anilin
2,6-diisopropylphenylamine
Aniline, 2,6-diisopropyl-
Diisopropylaniline,90%
2,6-DIISOPROPYLANILINE, TECH., 90%
Amitraz E.C.
2,6-Diisopropylaniline, 90+%
2,6-Bis(1-methylethyl)aniline
2,6-Di(propan-2-yl)aniline
2,6-Diisopropylbenzenamine | [EINECS(EC#)]
246-305-4 | [Molecular Formula]
C12H19N | [MDL Number]
MFCD00008887 | [Molecular Weight]
177.29 | [MOL File]
24544-04-5.mol |
| Chemical Properties | Back Directory | [Appearance]
Clear liquid | [Melting point ]
-45 °C (lit.) | [Boiling point ]
257 °C (lit.) | [density ]
0.94 g/mL at 25 °C(lit.)
| [vapor pressure ]
<0.01 mm Hg ( 20 °C)
| [refractive index ]
n20/D 1.532(lit.)
| [Fp ]
255 °F
| [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
<0.2g/l | [form ]
Liquid | [pka]
4.25±0.10(Predicted) | [color ]
Clear | [Water Solubility ]
<0.20 g/L | [Usage]
2,6-Diisopropylaniline is used as intermediate for the manufacture of carbodiimides stabilizers, RIM-PUR, synthetic resins, pesticides, antioxidants, pharmaceuticals and other products. WWW Link | [BRN ]
2208763 | [InChI]
1S/C12H19N/c1-8(2)10-6-5-7-11(9(3)4)12(10)13/h5-9H,13H2,1-4H3 | [InChIKey]
WKBALTUBRZPIPZ-UHFFFAOYSA-N | [SMILES]
CC(C)c1cccc(C(C)C)c1N | [LogP]
3.18 at 20℃ | [CAS DataBase Reference]
24544-04-5(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzenamine, 2,6-bis(1-methylethyl)-(24544-04-5) | [EPA Substance Registry System]
24544-04-5(EPA Substance) |
| Questions And Answer | Back Directory | [Description]
2,6-Diisopropylaniline is an organic compound with the formula H2NC6H3(CHMe2)2 (Me = CH3). It is a colorless liquid although, like many anilines, samples can appear yellow or brown.
|
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H319-H412 | [Precautionary statements ]
P273-P305+P351+P338 | [Hazard Codes ]
Xi | [Risk Statements ]
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
2
| [RTECS ]
BX4025000
| [TSCA ]
Yes | [REACH Registrations]
Active | [HS Code ]
29214980 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Aquatic Chronic 3
Eye Irrit. 2 |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Isoproturon-->2-Isopropylaniline | [Preparation Products]
3,5-diisopropylphenol-->4,4'-Methylenebis(2,6-diisopropylaniline)-->1,3-diisopropyl-2-isothiocyanato-5-phenoxybenzene-->(2,6-Diisopropyl-4-Phenoxy)Phenylthiourea-->Diafenthiuron-->4-Phenoxy-2,6-Diisopropyl Aniline-->4-Bromo-2,6-bis(1-methylethyl)benzenamine-->2,6-Diisopropylphenyl isocyanate-->N-Cyclohexyl-2,6-bis(1-methylethyl)-Benzenamine-->2,4-Diisopropylbenzene-1,3-diaMine-->2-(2,6-diisopropylphenyl)-1H-benzo[5,10]anthra[2,1,9-def]isoquinoline-1,3(2H)-dione |
| Hazard Information | Back Directory | [Chemical Properties]
Clear liquid | [Uses]
2,6-Diisopropylaniline is used as intermediate for the manufacture of carbodiimides stabilizers, RIM-PUR, synthetic resins, pesticides, antioxidants, pharmaceuticals and other products.
2,6-Diisopropylaniline may be used in the preparation of multitopic Schiff-base ligand precursors.It may be used in the preparation of NSN-donor proligand, 4,5-bis(2,6-diisopropylanilino)-2,7-di-tert-butyl-9,9-dimethylthioxanthene. It may be used to prepare N-heterocyclic carbene complexes for α-arylation of acyclic ketones, amination of haloarenes, and aqueous Suzuki coupling.
2,6-Diisopropylaniline may be used in the preparation of organocatalyst based on naphthalene diimides (NDIs).
| [Reactions]
2,6-Diisopropylaniline is an amine. It undergoes condensation with triacetylmethane in toluene in the presence of p-toluenesulfonic acid provides 3-[1-(2,6-diisopropylphenylamino)ethylidene]pentane-2,4-dione.
2,6-Diisopropylaniline is an aromatic amine. It reacts with bis(trimethylsilylmethyl)yttrium complexes supported by bulky amidopyridinate (Ap) and amidinate (Amd) ligands to afford yttrium alkyl anilido species. This reaction involves the elimination of TMS (Trimethylsilane). | [General Description]
2,6-Diisopropylaniline is an aromatic amine. It reacts with bis(trimethylsilylmethyl)yttrium complexes supported by bulky amidopyridinate (Ap) and amidinate (Amd) ligands to afford yttrium alkyl anilido species. This reaction involves the elimination of TMS (Trimethylsilane). | [Purification Methods]
This method for purifying 2,6-Diisopropylaniline comprises bringing 2,6-diisopropylaniline into contact with an alkyl- or arylsulfonic acid to produce the alkyl- or arylsulfonic acid salt of the 2,6-diisopropylaniline, recrystallizing the sulfonic acid salt in an organic solvent, and subsequently treating the obtained crystals with an alkali. |
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