| Identification | More | [Name]
Methyl vinyl sulfone | [CAS]
3680-02-2 | [Synonyms]
METHYL VINYL SULFONE
METHYL VINYL SULPHONE
VINYL METHYL SULFONE
(methylsulfonyl)-ethen
1-(Methylsulfonyl)ethylene
Sulfone, methyl vinyl
sulfone,methylvinyl
URI 718
(methylsulphonyl)ethylene
Methylvinylsulfone,98%,stab.with200ppm4-t-butylphenol
Methyl vinyl sulfone, stabilized, 98%
Ethene, (methylsulfonyl)-
METHYL VINYL SULFONE , STABILIZED WITH 200PPM 4-T-BUTYLPHENOL
METHYL VINYL SULFONE, 98%, STABILIZED
Ethenyl methyl sulfone
Methyl ethenyl sulfone
Methyl vinyl sulfone, 98%, stab. with 200ppm 4-tert-butylphenol | [EINECS(EC#)]
222-958-0 | [Molecular Formula]
C3H6O2S | [MDL Number]
MFCD00007567 | [Molecular Weight]
106.14 | [MOL File]
3680-02-2.mol |
| Chemical Properties | Back Directory | [Appearance]
light yellow liquid | [Boiling point ]
115-117 °C19 mm Hg(lit.) | [density ]
1.212 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.463(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
0-6°C | [form ]
Liquid | [color ]
Clear colorless to slightly yellow | [Specific Gravity]
1.212 | [Stability:]
Stable. Incompatible with strong oxidizing agents. Irritant. | [BRN ]
878198 | [InChI]
InChI=1S/C3H6O2S/c1-3-6(2,4)5/h3H,1H2,2H3 | [InChIKey]
WUIJTQZXUURFQU-UHFFFAOYSA-N | [SMILES]
C=CS(C)(=O)=O | [CAS DataBase Reference]
3680-02-2(CAS DataBase Reference) | [NIST Chemistry Reference]
Ethene, (methylsulfonyl)-(3680-02-2) | [EPA Substance Registry System]
3680-02-2(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
T+,T,Xi | [Risk Statements ]
R22:Harmful if swallowed.
R27:Very Toxic in contact with skin.
R41:Risk of serious damage to eyes. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2810 6.1/PG 1
| [WGK Germany ]
3
| [RTECS ]
WR6825000
| [HazardClass ]
6.1 | [PackingGroup ]
II | [HS Code ]
29309099 |
| Hazard Information | Back Directory | [General Description]
Clear pale yellow liquid. | [Reactivity Profile]
METHYL VINYL SULFONE(3680-02-2) is incompatible with oxidizing agents . Can react exothermically with reducing agents to release hydrogen gas or hydrogen sulfide. In the presence of various catalysts (such as acids) or initiatiators, can undergo exothermic polymerization reactions. | [Air & Water Reactions]
Water soluble. | [Fire Hazard]
This chemical is probably combustible. | [Chemical Properties]
light yellow liquid | [Uses]
Methyl vinyl sulfone has been used:
- as derivatization reagent in an improved method for detection of pseudouridine in nucleoside mixtures by capillary HPLC-mass spectrometry
- in preparation of methylsulfonylethyl cellulose via Michael addition to cotton fabric
- in Heck vinylation of aryl halides
| [Purification Methods]
Pass the sulfone through a column of alumina, then de-gas, distil it in a vacuum line and store it at -190o until required. [Beilstein 1 III 1866.] |
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