ChemicalBook--->CAS DataBase List--->513-78-0

513-78-0

513-78-0 Structure

513-78-0 Structure
IdentificationMore
[Name]

CADMIUM CARBONATE
[CAS]

513-78-0
[Synonyms]

CADMIUM CARBONATE
cadmiumcarbonate(cdco3)
cadmiummonocarbonate
carbonicacid,cadmium(2+)salt(1:1)
carbonicacid,cadmiumsalt
Carbonicacid,cadmiumsalt(1:1)
caswellno134a
chemcarb(cdco3)
epapesticidechemicalcode012901
kalcit
mikrokalcit
otavite
supermikrokalcit
CADMIUM CARBONATE, 99.995%
CADMIUM CARBONATE, 99.999%
CADMIUM CARBONATE, POWDER, CA. 1 MICRON, 98%
CADMIUM CARBONATE EXTRA PURE
CADMIUM CARBONATE, 99.99% (METALS BASIS)
CADMIUM CARBONATE, PURATRONIC, 99.998% (METALS BASIS)
CADMIUM CARBONATE 97%
[EINECS(EC#)]

208-168-9
[Molecular Formula]

CCdO3
[MDL Number]

MFCD00010918
[Molecular Weight]

172.42
[MOL File]

513-78-0.mol
Chemical PropertiesBack Directory
[Appearance]

Milky white powder
[Melting point ]

500 °C (lit.)
[density ]

4.258 g/mL at 25 °C(lit.)
[solubility ]

H2O: insoluble(lit.)
[form ]

powder
[color ]

White to off-white
[Specific Gravity]

4.258
[Odor]

Odorless
[Stability:]

Stable. Incompatible with strong acids.
[Water Solubility ]

Very slightly soluble in water. Soluble in dilute acids, concentrated solutions of ammonium salts.
[Merck ]

14,1616
[Solubility Product Constant (Ksp)]

pKsp: 12
[Exposure limits]

ACGIH: TWA 0.01 mg/m3; TWA 0.002 mg/m3
NIOSH: IDLH 9 mg/m3
[InChI]

1S/CH2O3.Cd/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2
[InChIKey]

GKDXQAKPHKQZSC-UHFFFAOYSA-L
[SMILES]

[Cd++].[O-]C([O-])=O
[CAS DataBase Reference]

513-78-0(CAS DataBase Reference)
[EPA Substance Registry System]

513-78-0(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn,N
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R45:May cause cancer.
[Safety Statements ]

S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S53:Avoid exposure-obtain special instruction before use .
[RIDADR ]

UN 3077 9/PG 3
[WGK Germany ]

3
[RTECS ]

FF9320000
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

28369917
[Storage Class]

6.1B - Non-combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
[Hazard Classifications]

Acute Tox. 2 Inhalation
Acute Tox. 4 Dermal
Acute Tox. 4 Oral
Aquatic Acute 1
Aquatic Chronic 1
Carc. 1B
Muta. 1B
Repr. 2
STOT RE 1
[Safety Profile]

Confirmed human carcinogen. Poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of cadmium.
[Hazardous Substances Data]

513-78-0(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ammonium hydroxide-->Cadmium chloride
[Preparation Products]

Pigment yellow 37 (C.I. 77199)-->dicadmium selenide sulphide
Hazard InformationBack Directory
[Chemical Properties]

White powdery solid; density 4.258 g/cm3; decomposes on heating below 500°C; insoluble in water and liquid ammonia; soluble in acid (with reaction).
[Physical properties]

White powdery solid; density 4.258 g/cm3; decomposes on heating below 500°C; insoluble in water and liquid ammonia; soluble in acid (with reaction).
[Uses]

Cadmium carbonate is the raw material for the production of pigments for ceramic and frits and for production of cadmium salt. Used as reagents. It is used for intermediates of manufacturing polyester, glass pigment flux, organic catalysts, plastic plasticizer, stabilizer.
[Uses]

Cadmium carbonate occurs in nature as the mineral otavite. The commer_x0002_cial applications of this compound are limited. It is used as a catalyst in organic synthesis and as a starting material to prepare other cadmium salts.
[reaction suitability]

reagent type: catalyst
core: cadmium
Questions And AnswerBack Directory
[Preparation]

Cadmium carbonate is precipitated by adding excess ammonium carbonate to a solution of cadmium chloride:
CdCl2 + (NH4)2CO3 → CdCO3 + 2NH4Cl
The precipitate is filtered and dried at 100°C. If an alkali metal carbonate is used instead of ammonium carbonate, a hydrated basic carbonate is obtained which upon heating with ammonium chloride at 150°C in the absence of air produces anhydrous carbonate.
Cadmium carbonate also may be obtained by slow absorption of cadmium oxide with carbon dioxide.
Spectrum DetailBack Directory
[Spectrum Detail]

CADMIUM CARBONATE(513-78-0)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Cadmium carbonate, 99.999%(513-78-0)
[Alfa Aesar]

Cadmium carbonate, Puratronic, 99.998% (metals basis)(513-78-0)
[Sigma Aldrich]

513-78-0(sigmaaldrich)
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