ChemicalBook--->CAS DataBase List--->526-99-8

526-99-8

526-99-8 Structure

526-99-8 Structure
IdentificationMore
[Name]

MUCIC ACID
[CAS]

526-99-8
[Synonyms]

2,3,4,5-TETRAHYDROXYADIPIC ACID
2,3,4,5-TETRAHYDROXYHEXANEDIOIC ACID
D-GALACTARIC ACID
GALACTARIC ACID
GALACTERIC ACID
GALACTOSACCHARIC ACID
GALATARIC ACID
MUCIC ACID
SACCHAROLACTIC ACID
TETRAHYDROXYADIPIC ACID
TETRAHYDROXYHEXANEDIOIC ACID
Galactaric acid, D-
Schleimsaure
Galactaric acid~Tetrahydroxyadipic acid
Mucic acid(galactaric acid)
Mucicacid,99%
Mucicacid,98%
Mucic
(2R,3S,4R,5S)-2,3,4,5-tetrahydroxyhexanedioic acid
(2S,3R,4S,5R)-2,3,4,5-Tetrahydroxyhexane-1,6-dioic acid
[EINECS(EC#)]

208-404-0
[Molecular Formula]

C6H10O8
[MDL Number]

MFCD00004239
[Molecular Weight]

210.14
[MOL File]

526-99-8.mol
Chemical PropertiesBack Directory
[Appearance]

white to light beige fine crystalline powder
[Melting point ]

220-225 °C (dec.)(lit.)
[Boiling point ]

269.65°C (rough estimate)
[density ]

1.5274 (rough estimate)
[refractive index ]

1.5800 (estimate)
[storage temp. ]

Store at RT.
[solubility ]

3.3g/l soluble
[form ]

Solid
[pka]

2.99±0.35(Predicted)
[color ]

White to Off-White
[Water Solubility ]

Soluble in water.
[Merck ]

14,4331
[BRN ]

1728117
[Cosmetics Ingredients Functions]

CHELATING
[InChI]

InChI=1/C6H10O8/c7-1(3(9)5(11)12)2(8)4(10)6(13)14/h1-4,7-10H,(H,11,12)(H,13,14)/t1-,2+,3+,4-
[InChIKey]

DSLZVSRJTYRBFB-DUHBMQHGNA-N
[SMILES]

[C@@H](O)([C@@H](O)C(=O)O)[C@@H](O)[C@H](O)C(=O)O |&1:0,2,7,9,r|
[Uses]

Substitute for tartaric acid, sequestrant for metalions (calcium, iron), retards hardening of concreteintermediate for synthesis of heterocyclic com-pounds (pyrroles).
[CAS DataBase Reference]

526-99-8(CAS DataBase Reference)
[EPA Substance Registry System]

Galactaric acid (526-99-8)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
[Hazard Codes ]

Xi,Xn
[Risk Statements ]

R22:Harmful if swallowed.
R40:Limited evidence of a carcinogenic effect.
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S36/37:Wear suitable protective clothing and gloves .
[WGK Germany ]

2
[RTECS ]

LW5180000
[TSCA ]

Yes
[HS Code ]

29181990
[Storage Class]

11 - Combustible Solids
[Hazardous Substances Data]

526-99-8(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

Pyrrole-->1-Furfurylpyrrole
Hazard InformationBack Directory
[Description]

Mucic acid,C6H10O8 or HOOC-(CHOH)4-COOH, (also known as galactaric or meso - galactaric acid) is an aldaric acid obtained by nitric acid oxidation of galactose or galactose - containing compounds like lactose, dulcite, quercite, and most varieties of gum.
It forms a crystalline powder, which melts at 230°C. It is insoluble in alcohol, and nearly insoluble in cold water. Due to the symmetry in the molecule, it is optically inactive even though it has chiral carbon atoms (i.e., it is a meso compound). When heated with pyridine to 140°C, it is converted into allommic acid. When digested with fuming hydrochloric acid for some time it is converted into a furfural dicarboxylic acid while on heating with barium sulfide it is transformed into athiophene carboxylic acid. The ammonium salt yields on dry distillation carbon dioxide, ammonia, pyrrol and other substances. The acid when fused with caustic alkalis yields oxalic acid. With potassium bisulfate mucic acid forms 3-hydroxy-2-pyrone by dehydration and decarboxylation.
[Chemical Properties]

white to light beige fine crystalline powder
[Definition]

ChEBI: A hexaric acid resulting from formal oxidative ring cleavage of galactose.
[storage]

Store at -20°C
Spectrum DetailBack Directory
[Spectrum Detail]

MUCIC ACID(526-99-8)MS
MUCIC ACID(526-99-8)1HNMR
MUCIC ACID(526-99-8)IR1
MUCIC ACID(526-99-8)IR2
MUCIC ACID(526-99-8)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Mucic acid, 98%(526-99-8)
[Alfa Aesar]

Mucic acid, 98%(526-99-8)
[Sigma Aldrich]

526-99-8(sigmaaldrich)
[TCI AMERICA]

Mucic Acid,>97.0%(T)(526-99-8)
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