| Identification | More | [Name]
N,N-Dimethylbenzamide | [CAS]
611-74-5 | [Synonyms]
LABOTEST-BB LT00793055
N,N-DIMETHYLBENZAMIDE
Dimethylbenzamide
Dimethylbenzmide
n,n-dimethyl-benzamid
N,N-Dimethylbenzamide98%
Benzamide, N,N-dimethyl-(6CI,8CI,9CI) | [EINECS(EC#)]
210-279-2 | [Molecular Formula]
C9H11NO | [MDL Number]
MFCD00008320 | [Molecular Weight]
149.19 | [MOL File]
611-74-5.mol |
| Chemical Properties | Back Directory | [Appearance]
white to slightly yellow cryst. low melting solid | [Melting point ]
43-45 °C (lit.) | [Boiling point ]
132-133 °C/15 mmHg (lit.) | [density ]
1.0753 (rough estimate) | [refractive index ]
1.5279 (estimate) | [Fp ]
>230 °F
| [storage temp. ]
Keep in dark place,Sealed in dry,2-8°C | [form ]
powder to lump to clear liquid | [pka]
-1.14±0.70(Predicted) | [color ]
White or Colorless to Light yellow | [Water Solubility ]
Soluble in water. | [BRN ]
774955 | [InChI]
1S/C9H11NO/c1-10(2)9(11)8-6-4-3-5-7-8/h3-7H,1-2H3 | [InChIKey]
IMNDHOCGZLYMRO-UHFFFAOYSA-N | [SMILES]
CN(C)C(=O)c1ccccc1 | [CAS DataBase Reference]
611-74-5(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzamide, N,N-dimethyl-(611-74-5) | [EPA Substance Registry System]
611-74-5(EPA Substance) |
| Questions And Answer | Back Directory | [Preparation]
Using Cu2O as a catalyst, o-phenanthroline as a ligand, and oxygen as an oxidant, phenylacetonitrile, N,N-dimethylformamide (DMF), and iodobenzene as reactants, a one-pot process can be used to simultaneously carry out amidation and cyanation reactions to generate the target products N,N-dimethylbenzamide and benzonitrile, with yields of 85% and 75%, respectively. |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H302-H315-H319-H335 | [Precautionary statements ]
P261-P264-P270-P301+P312-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [RTECS ]
CV4500000
| [TSCA ]
Yes | [REACH Registrations]
Active | [HS Code ]
29242990 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
white to slightly yellow cryst. low melting solid | [Uses]
Reagent for deoxygenation of secondary alcohols. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 36, p. 2721, 1971 DOI: 10.1021/jo00817a036
Journal of the American Chemical Society, 77, p. 1114, 1955 DOI: 10.1021/ja01610a010
Synthetic Communications, 12, p. 989, 1982 DOI: 10.1080/00397918208061938 | [General Description]
N,N-Dimethylbenzamide is a hydrotropic agent and its ability to solubilize drugs with low aqueous solubility has been investigated. It reacts with PhLnI complexes (Ln-Eu, Sm, Yb) to yield benzophenone in good yields. Deuterium exchange labelling experimets on N,N-dimethylbenzamide using [IrH2(Me2CO)2(PPh3)2]BF4 as catalyst and deuterium gas as the source of isotope has been conducted. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
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https://www.jkchemical.com |
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Alfa Aesar
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400-6106006 |
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http://chemicals.thermofisher.cn |
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Energy Chemical
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400-0056266 |
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www.energy-chemical.com |
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China Langchem Inc.
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0086-21-58956006 |
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www.chemicalbook.com/ShowSupplierProductsList19141/0_EN.htm |
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Aemon Chemical
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0086-755-86198205 |
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www.aemonchem.com |
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Maya High Purity Chemicals
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+86 (573) 82222445 (0)18006601000 452520369 |
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www.chemicalbook.com/ShowSupplierProductsList15221/0_EN.htm |
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