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683-85-2

683-85-2 Structure

683-85-2 Structure
IdentificationMore
[Name]

DIMETHYLPHOSPHORAMIDOUS DICHLORIDE
[CAS]

683-85-2
[Synonyms]

DICHLORO(DIMETHYLAMINO)PHOSPHINE
DIMETHYLAMINODICHLOROPHOSPHINE
(DIMETHYLAMINO)PHOSPHONOUS DICHLORIDE
DIMETHYLAMINOPHOSPHOROUS DICHLORIDE
DIMETHYLAMINOPHOSPHORUS DICHLORIDE
DIMETHYLPHOSPHORAMIDOUS DICHLORIDE
(CH3)2NPCl2
Dichlor(dimethylamino)phosphan
dimethylamidodichlorophosphite
dimethyl-amidophosphorousacid-dichloride
Dimethylaminodichlorphosphan
Dimethylaminodichlorphosphine
N,N-Dimethylamidodichlorophosphite
Dimethylaminodichlorophosphine,98%
N,N-Dimethylamide phosphorous aciddichloride
[Molecular Formula]

C2H6Cl2NP
[MDL Number]

MFCD00013613
[Molecular Weight]

145.96
[MOL File]

683-85-2.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless to light yellow liquid
[Boiling point ]

150 °C (lit.)
[density ]

1.271 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.505(lit.)
[Fp ]

−10 °F
[storage temp. ]

Refrigerator (+4°C) + Flammables area
[form ]

Liquid
[pka]

-1.98±0.70(Predicted)
[color ]

Colorless to light yellow
[Water Solubility ]

Reacts with water.
[Sensitive ]

Moisture Sensitive
[InChI]

InChI=1S/C2H6Cl2NP/c1-5(2)6(3)4/h1-2H3
[InChIKey]

XPWWDZRSNFSLRQ-UHFFFAOYSA-N
[SMILES]

P(N(C)C)(Cl)Cl
[CAS DataBase Reference]

683-85-2(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Corrosion (GHS05)
GHS02,GHS05
[Signal word ]

Danger
[Hazard statements ]

H225-H314
[Precautionary statements ]

P210-P233-P240-P280-P303+P361+P353-P305+P351+P338
[Hazard Codes ]

F,C
[Risk Statements ]

R11:Highly Flammable.
R14:Reacts violently with water.
R34:Causes burns.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 2924 3/PG 2
[WGK Germany ]

3
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29310099
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
Hazard InformationBack Directory
[Chemical Properties]

Colorless to light yellow liquid
[Uses]

Dimethylphosphoramidous dichloride (N,N-dimethylamidodichlorophosphite) may be used in the synthesis of the following:
  • N,N-dimethylamidotetrachlorophosphorane
  • O-propylchloroformimino-N,N-dimethylamidochlorophosphate
  • 1,3-bisarylsulphonyl-1,3,2,4-diazadiphosphetidines
[Uses]

Dimethylphosphoramidous dichloride (N,N-dimethylamidodichlorophosphite) may be used in the synthesis of the following N,N-dimethylamidotetrachlorophosphorane, O-propylchloroformimino-N,N-dimethylamidochlorophosphate, bisarylsulphonyldiazadiphosphetidines.
[General Description]

Dimethylphosphoramidous dichloride (dimethylaminodichlorophosphine) is a phosphorus chloride derivative. It exists in two stable isomers, a gauche-conformer with C1 symmetry and anti-conformer with Cs symmetry. Its synthesis has been reported. Molecular conformation has been investigated through correlation between the 35Cl NQR frequencies and charge on the chlorine atoms. Its vibrational spectra has been studied. Its reaction with SO2 has been investigated. It participates in the synthesis of [(dimethylamino)phosphoryl] bis(difluoromethylene)phosphonate.
Spectrum DetailBack Directory
[Spectrum Detail]

DIMETHYLPHOSPHORAMIDOUS DICHLORIDE(683-85-2)Raman
DIMETHYLPHOSPHORAMIDOUS DICHLORIDE(683-85-2)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Dimethylphosphoramidous dichloride(683-85-2)
[Alfa Aesar]

Dichloro(dimethylamino)phosphine, 98%(683-85-2)
[Sigma Aldrich]

683-85-2(sigmaaldrich)
[TCI AMERICA]

Dichloro(dimethylamino)phosphine,>98.0%(GC)(683-85-2)
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