ChemicalBook--->CAS DataBase List--->696-59-3

696-59-3

696-59-3 Structure

696-59-3 Structure
IdentificationMore
[Name]

2,5-Dimethoxytetrahydrofuran
[CAS]

696-59-3
[Synonyms]

2,5-DIMETHOXYTETRAHYDROFURAN
DIMETHOXYTETRAHYDROFURAN
DMTHF
FURAN, TETRAHYDRO-2,5-DIMETHOXY
TETRAHYDRO-2,5-DIMETHOXYFURAN
2,5-Dimethoxytetrahydrofuran,c&t
2,5-dimethoxytetrahydrofuran,mixtureofcis-andtransisomers
cis,trans-2,5-Dimethoxytetrahydrofuran
dimethoxytetrahydrofuran(tetrahydro-2,5-demethoxy-furan)
Protectol DMT
tetrahydro-2,5-dimethoxy-fura
2,5-Dimethoxytetrahydrofuran, mixture of cis and trans
2,5-DIMETHOXY-TETRAHYDROFURAN (CIS+TRANS )
2,5-DIMETHOXYTETRAHYDROFURAN, 98%, MIXTU RE OF ISOMERS
2,5-Dimethoxy Tetrahydrofulan
2,5-Dimethoxytetrahydrofuran (cis-and trans-mixture)
2,5-Dimethoxytetrahydrofuran, 99%, mixtureof cis-and trans isomers
2,3,4,5-Tetrahydro-2,5-dimethoxyfuran
[EINECS(EC#)]

211-797-1
[Molecular Formula]

C6H12O3
[MDL Number]

MFCD00005359
[Molecular Weight]

132.16
[MOL File]

696-59-3.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless to light yellow liqui
[Melting point ]

-45 °C
[Boiling point ]

145-147 °C(lit.)
[density ]

1.023 g/mL at 20 °C(lit.)
[vapor pressure ]

5 hPa (20 °C)
[refractive index ]

n20/D 1.418
[Fp ]

95 °F
[storage temp. ]

Flammables area
[solubility ]

300g/l
[form ]

Liquid
[color ]

Clear colorless to slightly yellow
[PH]

5 (300g/l, H2O, 20℃)
[explosive limit]

2.0-12.3%(V)
[Water Solubility ]

350 g/L (20 ºC)
[Sensitive ]

Air & Light Sensitive
[BRN ]

104261
[InChI]

1S/C6H12O3/c1-7-5-3-4-6(8-2)9-5/h5-6H,3-4H2,1-2H3
[InChIKey]

GFISDBXSWQMOND-UHFFFAOYSA-N
[SMILES]

COC1CCC(OC)O1
[LogP]

0.34 at 20℃
[CAS DataBase Reference]

696-59-3(CAS DataBase Reference)
[NIST Chemistry Reference]

Furan, tetrahydro-2,5-dimethoxy-(696-59-3)
[EPA Substance Registry System]

696-59-3(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Skull and Crossbones (GHS06)
GHS02,GHS06
[Signal word ]

Danger
[Hazard statements ]

H226-H315-H331
[Precautionary statements ]

P210-P233-P240-P241-P303+P361+P353-P304+P340+P311
[Hazard Codes ]

Xi,Xn
[Risk Statements ]

R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
R36:Irritating to the eyes.
R20/21:Harmful by inhalation and in contact with skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S16:Keep away from sources of ignition-No smoking .
[RIDADR ]

UN 1993 3/PG 3
[WGK Germany ]

1
[Autoignition Temperature]

>205 °C
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

29321900
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 3 Inhalation
Flam. Liq. 3
Skin Irrit. 2
[Toxicity]

LD50 orally in Rabbit: 2040 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium hydroxide-->Methanol-->Diethyl ether-->Tetrahydrofuran-->Toluene-->Potassium carbonate-->Sodium carbonate-->Bromine-->Magnesium sulfate-->Benzene-->Hydrogen-->Carbon dioxide-->Nickel-->Furan-->Potassium Acetate-->Raney nickel-->2,5-Dihydro-2,5-dimethoxyfuran-->Potassium carbonate (13C)
[Preparation Products]

3-(2-Formyl-1H-pyrrol-1-yl)benzonitrile-->5-Methyl-2-pyrrol-1-yl-thiophene-3-carboxylic acid-->1-Methyl-5-(1H-pyrrol-1-yl)-1H-pyrazole-4-carboxylic acid-->Tropyl a ormulphenylacetate-->Ethyl 1-methyl-5-(1H-pyrrol-1-yl)-1H-pyrazole-4-carboxylate-->8-isopropyl-8-azabicyclo[3.2.1]oct-3-yl endo-(±)-formylphenylacetate-->2-Amino-5-ethyl-thiophene-3-carboxylic acid methyl ester-->N-Isopropylnortropinyl a hydroxymethyl)phenylacetate-->Naphthalene-2,3-dicarboxaldehyde-->3-(1H-Pyrrol-1-yl)thiophene-2-carboxylic acid-->4-(1H-Pyrrol-1-yl)benzoic acid
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2,5-Dimethoxytetrahydrofuran(696-59-3).msds
Hazard InformationBack Directory
[Chemical Properties]

Colorless to light yellow liqui
[Uses]

2,5-Dimethoxytetrahydrofuran is a tetrahydrofuran derivative that finds application in proteomics research and in organic synthesis. It is also used as an intermediate for atropine sulfate, which is an anticholinergic drug. Further, it acts as a precursor of butanediol. In addition to this, it is used as a photographic hardener and as disinfectant in formulations.
[Synthesis]

2,5-Dimethoxytetrahydrofuran is prepared by catalytic hydrogenation of 2,5-dialkoxy-2,5-dihydrofurans.
[Solubility in water]

Practically insoluble in H2O; soluble in MeOH, Et2O, THF.
[Precautions]

Flammable liquids must be stored in a cool, ventilated place. Noxious by inhalation, ingestion, or by contact with skin. Use in a fume hood.
Spectrum DetailBack Directory
[Spectrum Detail]

2,5-Dimethoxytetrahydrofuran(696-59-3)MS
2,5-Dimethoxytetrahydrofuran(696-59-3)1HNMR
2,5-Dimethoxytetrahydrofuran(696-59-3)IR1
2,5-Dimethoxytetrahydrofuran(696-59-3)IR2
2,5-Dimethoxytetrahydrofuran(696-59-3)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2,5-Dimethoxytetrahydrofuran, mixture of cis-and trans isomers, 99%(696-59-3)
[Alfa Aesar]

2,5-Dimethoxytetrahydrofuran, cis + trans, 98%(696-59-3)
[Sigma Aldrich]

696-59-3(sigmaaldrich)
[TCI AMERICA]

2,5-Dimethoxytetrahydrofuran  (cis-and trans-mixture),>98.0%(GC)(696-59-3)
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