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86-48-6

86-48-6 Structure

86-48-6 Structure
IdentificationMore
[Name]

1-Hydroxy-2-naphthoic acid
[CAS]

86-48-6
[Synonyms]

1-HYDROXY-2-NAPHTHOIC ACID
1-HYDROXY-NAPHTHALENE-2-CARBONIC ACID
1-NAPHTHOL-2-CARBOXYLIC ACID
ALPHA-HYDROXYNAPHTHOIC ACID
LABOTEST-BB LT00452757
RARECHEM AL BE 0359
1-hydroxy-2-naphthalenecarboxylicaci
1-hydroxy-2-Naphthalenecarboxylicacid
2-Naphthalenecarboxylic acid, 1-hydroxy-
1-hydroxy-β-naphthoic acid
hydroxy-2-naphthoic acid
1-HYDROXYNAPHTHALENE-2-CARBOXYLIC ACID (1-HYDROXY-2-NAPHTHOIC ACID)
1-Hydroxy-2-naphthoic acid, 98+%
2-Carboxy-1-naphthol
Hydroxynaphthalene-2-carboxylic acid
Naphthol-2-carboxylic acid
[EINECS(EC#)]

201-674-0
[Molecular Formula]

C11H8O3
[MDL Number]

MFCD00003960
[Molecular Weight]

188.18
[MOL File]

86-48-6.mol
Chemical PropertiesBack Directory
[Appearance]

beige to brown-grey powder
[Melting point ]

195-200 °C (dec.) (lit.)
[Boiling point ]

283.17°C (rough estimate)
[density ]

1.2100 (rough estimate)
[refractive index ]

1.6310 (estimate)
[Fp ]

150 °C
[storage temp. ]

Sealed in dry,Room Temperature
[solubility ]

alcohol: freely soluble
[form ]

Powder or Crystals
[pka]

3.02±0.30(Predicted)
[color ]

White to slightly pink to tan or
[Water Solubility ]

SOLUBLE IN HOT WATER
[Merck ]

14,4834
[BRN ]

974438
[InChI]

1S/C11H8O3/c12-10-8-4-2-1-3-7(8)5-6-9(10)11(13)14/h1-6,12H,(H,13,14)
[InChIKey]

SJJCQDRGABAVBB-UHFFFAOYSA-N
[SMILES]

OC(=O)c1ccc2ccccc2c1O
[LogP]

3.196 (est)
[CAS DataBase Reference]

86-48-6(CAS DataBase Reference)
[EPA Substance Registry System]

86-48-6(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[TSCA ]

Yes
[HS Code ]

29182910
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Carbon dioxide-->Water-->1-Naphthol-->Sodium formate-->1-Naphthalenol, sodium salt-->Magnesium methyl carbonate-->Potassium bicarbonate
[Preparation Products]

2-hydroxymethyl-1-naphthol-->1-Hydroxy-2-naphthaldehyde-->4-Hydroxy-1-naphthoic acid-->2-Nitroso-1-naphthol-->Naphthochrome green-->4-[Bis[4-hydroxy-3-(sodiooxycarbonyl)-1-naphthalenyl]methylene]-1,4-dihydro-1-oxonaphthalene-2-carboxylic acid sodium salt-->1,7-dihydroxynaphthalene-2-carboxylic Acid
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1-Naphthol-2-carboxylic acid(86-48-6).msds
Hazard InformationBack Directory
[Chemical Properties]

beige to brown-grey powder
[Uses]

Metabolite from phenanthrene degradation.
[Definition]

ChEBI: 1-hydroxy-2-naphthoic acid is a naphthoic acid with the carboxy group at position 2 and carrying a hydroxy substituent at the 1-position. It is a xenobiotic metabolite produced by the biodegradation of phenanthrene by microorganisms. It has a role as a bacterial xenobiotic metabolite and a fungal xenobiotic metabolite. It is a naphthoic acid, a member of naphthols and a hydroxy monocarboxylic acid. It is functionally related to a 2-naphthoic acid. It is a conjugate acid of a 1-hydroxy-2-naphthoate.
[Preparation]

Treatment of the dried sodium salt of 1-naphthol with carbon dioxide at 135℃ under pressure gives an 80 % yield of product.
[General Description]

1-Hydroxy-2-naphthoic acid is produced by the transformation of phenanthrene by NCIB 9816 clones.
[Purification Methods]

Successively crystallise the acid from EtOH/water, diethyl ether and acetonitrile, with filtration through a column of charcoal and Celite. [Tong & Glesmann J Am Chem Soc 79 583 1957, Beilstein 10 H 331, 10 IV 1194.]
Spectrum DetailBack Directory
[Spectrum Detail]

1-Hydroxy-2-naphthoic acid(86-48-6)MS
1-Hydroxy-2-naphthoic acid(86-48-6)1HNMR
1-Hydroxy-2-naphthoic acid(86-48-6)13CNMR
1-Hydroxy-2-naphthoic acid(86-48-6)IR1
1-Hydroxy-2-naphthoic acid(86-48-6)IR2
1-Hydroxy-2-naphthoic acid(86-48-6)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1-Hydroxy-2-naphthoic acid, 99%(86-48-6)
[Alfa Aesar]

1-Hydroxy-2-naphthoic acid, 98+%(86-48-6)
[Sigma Aldrich]

86-48-6(sigmaaldrich)
[TCI AMERICA]

1-Hydroxy-2-naphthoic Acid,>98.0%(T)(86-48-6)
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