ChemicalBook--->CAS DataBase List--->921-01-7

921-01-7

921-01-7 Structure

921-01-7 Structure
IdentificationMore
[Name]

D-Cysteine
[CAS]

921-01-7
[Synonyms]

BETA-MERCAPTOALANINE
D-CYS-OH
D-CYSTEINE
H-D-CYS-OH
RARECHEM AB PP 1441
(S)-2-AMINO-3-MERCAPTOPROPIONIC ACID
D-cysteine free base crystalline
D-Cysteinefreebase
(2S)-2-amino-3-sulfanyl-propanoic acid
D-Cysteine (9CI)
H-D-Cys-OH (D-Cysteine)
(S)-2-Amino-3-mercaptopropanoic acid
[EINECS(EC#)]

213-062-0
[Molecular Formula]

C3H7NO2S
[MDL Number]

MFCD00066461
[Molecular Weight]

121.16
[MOL File]

921-01-7.mol
Chemical PropertiesBack Directory
[Appearance]

White crystalline powder
[Melting point ]

~230 °C (dec.)
[Boiling point ]

293.9±35.0 °C(Predicted)
[density ]

1.334±0.06 g/cm3(Predicted)
[storage temp. ]

−20°C
[solubility ]

Aqueous Acid (Slightly), Water (Slightly)
[form ]

Crystalline Powder
[pka]

2.07±0.10(Predicted)
[color ]

White
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[Optical Rotation]

[α]20/D 7.6±1.0°, c = 5% in 5 M HCl
[Water Solubility ]

Soluble in water (partly).
[Sensitive ]

Air Sensitive
[BRN ]

1721407
[Major Application]

peptide synthesis
[InChI]

1S/C3H7NO2S/c4-2(1-7)3(5)6/h2,7H,1,4H2,(H,5,6)/t2-/m1/s1
[InChIKey]

XUJNEKJLAYXESH-UWTATZPHSA-N
[SMILES]

N[C@H](CS)C(O)=O
[LogP]

0.230 (est)
[CAS DataBase Reference]

921-01-7(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302
[Precautionary statements ]

P264-P270-P301+P312a-P330-P501a
[Hazard Codes ]

Xi,Xn
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[F ]

10-23
[HS Code ]

29309090
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Oral
Hazard InformationBack Directory
[Chemical Properties]

White crystalline powder
[Uses]

D-Cysteine has been used in the functionalization of QDs for applications in photocatalysis.
It can also be used in the synthesis of:
  • cysteine-based chiral carbon dots (CDs)
  • D-luciferin and aminoluciferin analogs

[Definition]

ChEBI: An optically active form of cysteine having D-configuration.
[reaction suitability]

reaction type: solution phase peptide synthesis
[Purification Methods]

Purify it by recrystallisation from H2O (free from metal ions) and dry it in a vacuum. It is soluble in H2O, EtOH, Me2CO, EtOAc, AcOH, *C6H6 and CS2. Acidic solutions can be stored under N2 for a few days without deterioration. [For synthesis and spectra see Greenstein & Winitz Chemistry of the Amino Acids (J. Wiley) Vol 3 p1879 1961, Beilstein 4 III 1618, 4 IV 3144.]
Spectrum DetailBack Directory
[Spectrum Detail]

D-Cysteine(921-01-7)1HNMR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

921-01-7(sigmaaldrich)
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