| Identification | More | [Name]
Methyl glycolate | [CAS]
96-35-5 | [Synonyms]
GLYCOLIC ACID METHYL ESTER
HYDROXYACETIC ACID METHYL ESTER
METHYL 2-HYDROXYACETATE
METHYL GLYCOLATE
METHYL HYDROXYACETATE
MG
Aceticacid,hydroxy-,methylester
hydroxy-aceticacimethylester
Methyl ester of hydroxyacetic acid
Methylglycolate,98%
2-hydroxyethanoate
2-Hydroxyacetic acid methyl ester
Glycolic acid methyl
Hydroxyacetic acid methyl | [EINECS(EC#)]
202-502-7 | [Molecular Formula]
C3H6O3 | [MDL Number]
MFCD00004667 | [Molecular Weight]
90.08 | [MOL File]
96-35-5.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colourless liquid | [Melting point ]
149-151 °C
| [Boiling point ]
149-151 °C(lit.)
| [density ]
1.167 g/mL at 25 °C(lit.)
| [vapor density ]
3.12 (vs air)
| [vapor pressure ]
17 mm Hg ( 52 °C)
| [refractive index ]
n20/D 1.417(lit.)
| [Fp ]
153 °F
| [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
Chloroform, Methanol | [form ]
Liquid | [pka]
13.00±0.10(Predicted) | [color ]
Clear colorless | [Water Solubility ]
Miscible with water. | [Detection Methods]
GC,NMR | [BRN ]
1699571 | [InChIKey]
GSJFXBNYJCXDGI-UHFFFAOYSA-N | [CAS DataBase Reference]
96-35-5(CAS DataBase Reference) | [NIST Chemistry Reference]
Acetic acid, hydroxy-, methyl ester(96-35-5) | [EPA Substance Registry System]
96-35-5(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H227 | [Precautionary statements ]
P210e-P280a-P370+P378a-P501a-P210-P280-P403+P235-P501 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [TSCA ]
Yes | [HS Code ]
29181990 |
| Hazard Information | Back Directory | [Chemical Properties]
Clear colorless liquid | [Uses]
Methyl glycolate is a chemical reagent used in the synthesis of taxol and rapamycin. It is used in leather tanning and textile dyeing. It acts as a flavoring agent, preservative in food processing, in water treatment industries and as chemical intermediates. Further, it is used in emulsion polymers, ink and paint additive to improve flow properties and impart gloss. It plays an important role in producing triisopropylsilanyloxy-acetic acid methyl ester using imidazole as reagent. | [Reactions]
Methyl glycolate possesses chemical properties similar to both alcohols and esters, and can undergo carbonylation, hydrolysis, and oxidation reactions.
| [General Description]
Synthesis of methyl glycolate from the carbonylation of HCHO using heteropoly acids (HPAs) as catalysts, followed by esterification with methanol was reported. Size-selective vibrational spectroscopy of methyl glycolate clusters was reported. | [Synthesis]
Methyl glycolate was synthesized in a single step by reaction of CA with sodium hydroxide and methanol in an autoclave reactor. The highest MG yield of 81.4% was obtained under suitable conditions of 8:1:1 methanol: sodium hydroxide: CA (molar ratio), after 5 h at 150 °C, in a laboratory autoclave reactor. |
|
| Company Name: |
Shanghai Bank Pharma Limited Gold
|
| Telephone: |
2221346380 17701603001 |
| Website: |
www.chemicalbook.com/showsupplierproductslist20106/0_en.htm |
| Company Name: |
Liu Fang Yi Gold
|
| Telephone: |
19956514532 |
| Website: |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Jia Xing Isenchem Co.,Ltd
|
| Telephone: |
0573-85285100 18627885956 |
| Website: |
https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm |
|