Ameisensäure-phenylmethylester

Benzyl formate Struktur
104-57-4
CAS-Nr.
104-57-4
Bezeichnung:
Ameisensäure-phenylmethylester
Englisch Name:
Benzyl formate
Synonyma:
Benzyl alcohol, formate;FEMA 2145;jiasuanbianzhi;BENZYL METHANOATE;NSC 8049;Benzylformiat;BENZYL FORMATE;N-BENZYL FORMATE;BenzylFormate>Benzyl methanoater
CBNumber:
CB7737035
Summenformel:
C8H8O2
Molgewicht:
136.15
MOL-Datei:
104-57-4.mol

Ameisensäure-phenylmethylester Eigenschaften

Schmelzpunkt:
3.6℃
Siedepunkt:
203 °C(lit.)
Dichte
1.088 g/mL at 25 °C(lit.)
Dampfdruck
1.69hPa at 20℃
FEMA 
2145 | BENZYL FORMATE
Brechungsindex
n20/D 1.511(lit.)
Flammpunkt:
180 °F
storage temp. 
Inert atmosphere,Room Temperature
Aggregatzustand
clear liquid
Farbe
Colorless liquid
Wichte
1.091 (20/4℃)
Geruch (Odor)
powerful fruity, spicy odor
Geruchsart
floral
Biologische Quelle
synthetic
Wasserlöslichkeit
Insoluble in water, soluble in organic solvents, oils.
Merck 
14,1134
JECFA Number
841
BRN 
2041319
Henry's Law Constant
2.0×100 mol/(m3Pa) at 25℃, Brockbank (2013)
Major Application
flavors and fragrances
Kosmetik-Inhaltsstoffe Funktionen
PERFUMING
InChI
1S/C8H8O2/c9-7-10-6-8-4-2-1-3-5-8/h1-5,7H,6H2
InChIKey
UYWQUFXKFGHYNT-UHFFFAOYSA-N
SMILES
O=COCC1=CC=CC=C1
LogP
1.79 at 21.9℃
CAS Datenbank
104-57-4(CAS DataBase Reference)
NIST chemische Informationen
Formic acid, phenylmethyl ester(104-57-4)
EPA chemische Informationen
Formic acid, phenylmethyl ester (104-57-4)

Sicherheit

Kennzeichnung gefährlicher Xn
R-Sätze: 21/22
S-Sätze: 36-36/37-23
RIDADR  NA 1993 / PGIII
WGK Germany  1
RTECS-Nr. LQ5400000
TSCA  TSCA listed
HS Code  29151300
Speicherklasse 10 - Combustible liquids
Hazard Classifications Acute Tox. 4 Dermal
Acute Tox. 4 Oral
Toxizität LD50 orl-rat: 1400 mg/kg FCTXAV 11,1019,73

Ameisensäure-phenylmethylester Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R21/22:Gesundheitsschädlich bei Berührung mit der Haut und beim Verschlucken.

S-Sätze Betriebsanweisung:

S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.

Chemische Eigenschaften

Benzyl formate has an intense, pleasant, floral-fruity odor and sweet taste reminiscent of apricot and pineapple.

Occurrence

Reported found in the oil of Rosa rugosa, sour cherry, American cranberry, ligonberry, coffee, black tea, Agaricus mushroom, Ocimum basilicum, Bourbon vanilla and crowberry (Empetrum nigrum Coll.).

Verwenden

Solvent for cellulose esters; in perfumery.
It has a very sweet taste, more fruity than floral, spicy Banana-type. It is used quite frequently in perfume compositions, for floral bases such as Jasmin, Gardenia, NeroIi, Hyacinth, Carnation, and Fougeres and used in flavour compositions for imitation: Apricot, Banana, Cherry, Chocolate, Honey, Liquor, Nut, Peach, Plum, Prune, Pineapple, etc. Concentrations are usually about 12-15 ppm in the finished product. In chewing gum, the concentration may be as high as 35 ppm.

synthetische

By heating a mixture of formic/acetic anhydride and benzyl alcohol to 50°C; by passing a mixture of formic acid and excess benzyl alcohol over a catalyst (ThO2 or TiO2) at high temperature.

Hazard

May be narcotic in high concentration.

Sicherheitsprofil

Moderately toxic by ingestion andskin contact. Mutation data reported. Probably narcotic inhigh concentrations. When heated todecomposition it emits acrid, irritating fumes.

Ameisensäure-phenylmethylester Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Ameisensäure-phenylmethylester Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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104-57-4(Ameisensäure-phenylmethylester)Verwandte Suche:


  • Benzyl alcohol, formate
  • benzylalcohol,formate
  • Benzylester kyseliny mravenci
  • benzylesterkyselinymravenci
  • Benzylformiat
  • Formicacid,phenylmethylester
  • formicacidphenylmethylester
  • Natural Benzyl formate
  • jiasuanbianzhi
  • BENZYL FORMATE
  • BENZYL METHANOATE
  • Benzyl methanoater
  • FORMIC ACID BENZYL ESTER
  • FORMIC ACID:BENZYL ESTER
  • N-BENZYL FORMATE
  • BENZYL FORMATE 95+% FCC
  • FORMIC ACID BENZYL ESTER 95+%
  • Formic acid benzyl
  • phenylmethyl formate
  • phenylmethyl methanoate
  • NSC 8049
  • BenzylFormate>
  • Benzyl formate USP/EP/BP
  • Benzyl formate(kosher)
  • FEMA 2145
  • 104-57-4
  • 140-57-4
  • HCO2CH2C6H5
  • HCOOCH2C6H5
  • ESTER
  • Industrial/Fine Chemicals
  • A-B
  • Alphabetical Listings
  • Flavors and Fragrances
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