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ChemicalBook >> CAS DataBase List >>TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE

TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE

TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE Structure
TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE structure
CAS No.
949922-62-7
Chemical Name:
TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE
Synonyms
2-c]pyridine-5(4H)-carboxylate;N-Boc-2-bromo-4,5,6,7-tetrahydrothieno[3,2-c]pyridine;2-Bromo-5-Boc-4,5,6,7-tetrahydrothieno[3,2-c]pyridine;tert-Butyl 2-bromo-6,7-dihydrothieno[3,2-c]pyridine-5(4H);tert-butyl 2-broMo-4H,5H,6H,7H-thieno[3,2-c]pyridine-5-carboxylate;TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE;tert-butyl 2-bromo-6,7-dihydro-4H-thieno[3,2-c]pyridine-5-carboxylate;2-Bromo-6,7-dihydro-4H-thieno[3,2-c]pyridine-5-carboxylic acid tert-butyl ester;2-bromo-6,7-dihydrothieno[3,2-c]pyridine-5(4H)-carboxylic acid tert-butyl ester;Thieno[3,2-c]pyridine-5(4H)-carboxylic acid, 2-bromo-6,7-dihydro-, 1,1-dimethylethyl ester
CBNumber:
CB01502347
Molecular Formula:
C12H16BrNO2S
Molecular Weight:
318.23
MDL Number:
MFCD09878703
MOL File:
949922-62-7.mol
Last updated:2026-05-27 17:19:08
Product description Number Pack Size Price
TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)-CARBOXYLATE 95% SC1751 1G $189
TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)-CARBOXYLATE 95% SC1751 5G $566
TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)-CARBOXYLATE 95% SC1751 10G $849
tert-Butyl 2-Bromo-6,7-dihydrothieno[3,2-c]pyridine-5(4H)-carboxylate 069998 1.00g $415
tert-Butyl 2-Bromo-6,7-dihydrothieno[3,2-c]pyridine-5(4H)-carboxylate 069998 5.00g $1176
More product size
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TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE Properties

Boiling point 382.8±42.0 °C(Predicted)
Density 1.445±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pka -1.62±0.20(Predicted)
Appearance White to off-white Solid

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H332-H335
Precautionary statements  P261-P280-P305+P351+P338

TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE price More Price(32)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
AstaTech SC1751 TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)-CARBOXYLATE 95% 949922-62-7 1G $189 2026-04-30 Buy
AstaTech SC1751 TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)-CARBOXYLATE 95% 949922-62-7 5G $566 2026-04-30 Buy
AstaTech SC1751 TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)-CARBOXYLATE 95% 949922-62-7 10G $849 2026-04-30 Buy
Matrix Scientific 069998 tert-Butyl 2-Bromo-6,7-dihydrothieno[3,2-c]pyridine-5(4H)-carboxylate 949922-62-7 1.00g $415 2026-05-18 Buy
Matrix Scientific 069998 tert-Butyl 2-Bromo-6,7-dihydrothieno[3,2-c]pyridine-5(4H)-carboxylate 949922-62-7 5.00g $1176 2026-05-18 Buy
Product number Packaging Price Buy
SC1751 1G $189 Buy
SC1751 5G $566 Buy
SC1751 10G $849 Buy
069998 1.00g $415 Buy
069998 5.00g $1176 Buy

TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE Chemical Properties,Uses,Production

Synthesis

tert-butyl 6,7-dihydrothieno[3,2-c]pyridine-5(4H)-carboxylate

230301-73-2

TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE

949922-62-7

Tert-butyl 6,7-dihydrothieno[3,2-c]pyridine-5(4H)-carboxylate (5.0 g, 20.89 mmol) was used as starting material and dissolved in acetonitrile (25 mL). To this solution was added N-bromosuccinimide (4.09 g, 22.98 mmol) at room temperature and the reaction mixture was stirred overnight. Upon completion of the reaction, the reaction was quenched by the addition of water (50 mL) and subsequently extracted with ethyl acetate (50 mL × 2). The organic phases were combined and washed sequentially with water (50 mL × 2) and saturated brine (40 mL), then dried over anhydrous sodium sulfate. The solvent was removed by concentration under reduced pressure, and the crude product obtained was purified by column chromatography (eluent: petroleum ether/ethyl acetate, v/v = 20/1) to give the final white solid product tert-butyl 2-bromo-6,7-dihydrothieno[3,2-c]pyridine-5(4H)-carboxylate (6.21 g, 93% yield).

References

[1] Patent: CN104497008, 2016, B. Location in patent: Paragraph 0190; 0195; 0196
[2] European Journal of Medicinal Chemistry, 2018, vol. 145, p. 389 - 403

TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE Preparation Products And Raw materials

Raw materials

tert-butyl 6,7-dihydrothieno[3,2-c]pyridine-5(4H)-carboxylate Acetonitrile N-Bromosuccinimide

Preparation Products

TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE Suppliers

Global( 96)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd. 		+8613336195806 sales@capot.com China 29640 60
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 33024 60
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29815 58
Accela ChemBio Inc. 		+1-858-6993322 info@accelachem.com United States 21193 58
Alchem Pharmtech,Inc. 		8485655694 sales@alchempharmtech.com United States 63687 58
AFINE CHEMICALS LIMITED 		+86-0571-85134551 sales@afinechem.com China 15073 58
Dayang Chem (Hangzhou) Co.,Ltd. 		+86-0571-88938639 +8617705817739 info@dycnchem.com China 52705 58
changzhou huayang technology co., ltd 		+8615250961469 2571773637@qq.com China 9653 58
Labnetwork lnc. 		+86-27-50766799 +8618062016861 contact@labnetwork.com China 19987 58
Suzhou Victorypharm Co.,Ltd. 		+86-13916956214 sales@victory-pharm.com China 1299 58
Supplier Advantage
Capot Chemical Co.,Ltd. 		60
ATK CHEMICAL COMPANY LIMITED 		60
career henan chemical co 		58
Accela ChemBio Inc. 		58
Alchem Pharmtech,Inc. 		58
AFINE CHEMICALS LIMITED 		58
Dayang Chem (Hangzhou) Co.,Ltd. 		58
changzhou huayang technology co., ltd 		58
Labnetwork lnc. 		58
Suzhou Victorypharm Co.,Ltd. 		58

View Lastest Price from TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE pictures 2019-07-06 TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE
949922-62-7
 $2.00 1KG 99% Career Henan Chemical Co

TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE Spectrum

TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE(949922-62-7)1HNMR

949922-62-7(TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE)Related Search:

Dibenzothiophene 2-BROMO-4,5,6,7-TETRAHYDROTHIENO[3,2-C]PYRIDINE [2-(5-BROMO-THIOPHEN-2-YL)-ETHYL]-CARBAMIC ACID TERT-BUTYL ESTER TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE
TERT-BUTYL 2-BROMO-6,7-DIHYDROTHIENO[3,2-C]PYRIDINE-5(4H)CARBOXYLATE 2-Bromo-5-Boc-4,5,6,7-tetrahydrothieno[3,2-c]pyridine 2-c]pyridine-5(4H)-carboxylate tert-butyl 2-broMo-4H,5H,6H,7H-thieno[3,2-c]pyridine-5-carboxylate tert-Butyl 2-bromo-6,7-dihydrothieno[3,2-c]pyridine-5(4H) 2-Bromo-6,7-dihydro-4H-thieno[3,2-c]pyridine-5-carboxylic acid tert-butyl ester Thieno[3,2-c]pyridine-5(4H)-carboxylic acid, 2-bromo-6,7-dihydro-, 1,1-dimethylethyl ester 2-bromo-6,7-dihydrothieno[3,2-c]pyridine-5(4H)-carboxylic acid tert-butyl ester N-Boc-2-bromo-4,5,6,7-tetrahydrothieno[3,2-c]pyridine tert-butyl 2-bromo-6,7-dihydro-4H-thieno[3,2-c]pyridine-5-carboxylate 949922-62-7 Heterocycle-Pyridine series CHIRAL CHEMICALS