methyl 3-(2-bromophenyl)propanoate
- CAS No.
- 66191-86-4
- Chemical Name:
- methyl 3-(2-bromophenyl)propanoate
- Synonyms
- O-broMophenolMethyl propionate;Methyl 3-(2-bromophenyl)propionate;methyl 3-(2-bromophenyl)propanoate;Methyl3-(2-bromophenyl)propionate,98%;Methyl 3-(2-Bromophenyl)propionate >3-(2-bromophenyl)propanoic acid methyl ester;3-(2-Bromophenyl)propionic Acid Methyl Ester;Benzenepropanoic acid, 2-bromo-, methyl ester
- CBNumber:
- CB01563913
- Molecular Formula:
- C10H11BrO2
- Molecular Weight:
- 243.1
- MDL Number:
- MFCD09953149
- MOL File:
- 66191-86-4.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| Methyl 3-(2-Bromophenyl)propionate >98.0%(GC) | M2587 | 1g | $33 |
| Methyl 3-(2-Bromophenyl)propionate >98.0%(GC) | M2587 | 5g | $130 |
| Methyl 3-(2-Bromophenyl)propionate >98% | OR350280 | 5g | $21 |
| Methyl 3-(2-Bromophenyl)propionate >98% | OR350280 | 25g | $49 |
| Methyl 3-(2-bromophenyl)propionate 98% | AS8050 | 1g | $27 |
| More product size | |||
| Boiling point | 87℃/0.02Torr |
|---|---|
| Density | 1.389±0.06 g/cm3(Predicted) |
| refractive index | 1.5380 to 1.5420 |
| storage temp. | Sealed in dry,Room Temperature |
| form | Liquid |
| color | Colorless to pale yellow |
| CAS DataBase Reference | 66191-86-4 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| HS Code | 2916399090 | |||||||||
| NFPA 704 |
|
methyl 3-(2-bromophenyl)propanoate price More Price(33)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | M2587 | Methyl 3-(2-Bromophenyl)propionate >98.0%(GC) | 66191-86-4 | 1g | $33 | 2026-04-30 | Buy |
| TCI Chemical | M2587 | Methyl 3-(2-Bromophenyl)propionate >98.0%(GC) | 66191-86-4 | 5g | $130 | 2026-04-30 | Buy |
| Apolloscientific | OR350280 | Methyl 3-(2-Bromophenyl)propionate >98% | 66191-86-4 | 5g | $21 | 2026-06-04 | Buy |
| Apolloscientific | OR350280 | Methyl 3-(2-Bromophenyl)propionate >98% | 66191-86-4 | 25g | $49 | 2026-06-04 | Buy |
| Activate Scientific | AS8050 | Methyl 3-(2-bromophenyl)propionate 98% | 66191-86-4 | 1g | $27 | 2026-06-04 | Buy |
methyl 3-(2-bromophenyl)propanoate Chemical Properties,Uses,Production
Synthesis
67-56-1
15115-58-9
66191-86-4
To a stirred solution of 3-(2-bromophenyl)propionic acid (7.7 g, 33.6 mmol) in methanol (60 mL) at room temperature was added thionyl chloride (0.9 mL, 12 mmol) dropwise. The reaction mixture was heated to reflux for 1 hour. Subsequently, additional thionyl chloride (0.9 mL each, total 24 mmol) was added in two additions under reflux conditions, the second addition following the complete reaction of the first. After continuing the reflux reaction for 2 h, the volatile components were removed by distillation under reduced pressure (70 °C, 0.8 kPa). The light yellow oily residue obtained was dissolved in dichloromethane (60 mL) and washed with saturated aqueous sodium bicarbonate (60 mL). The organic layer was dried over anhydrous sodium sulfate, filtered, and concentrated under reduced pressure to afford methyl o-bromophenylpropionate (7.8 g, 96% yield) as a yellow oily liquid. The proton NMR spectral data of the product were in agreement with those reported in the literature [10].
References
[1] Angewandte Chemie - International Edition, 2016, vol. 55, # 51, p. 15797 - 15801
[2] Angew. Chem., 2016, vol. 128, p. 16029 - 16033,5
[3] Beilstein Journal of Organic Chemistry, 2015, vol. 11, p. 884 - 892
[4] Journal of Heterocyclic Chemistry, 2018, vol. 55, # 3, p. 670 - 684
[5] Tetrahedron, 2013, vol. 69, # 36, p. 7618 - 7626
methyl 3-(2-bromophenyl)propanoate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29640 | 60 |
| HaBo Hong Kong Co., Limited. | +86-25-18512596065 | info@habotech.com | CHINA | 933 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29792 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9636 | 58 |
| Neostar United (Changzhou) Industrial Co., Ltd. | +86-0519-85551759 +8613506123987 | marketing1@neostarunited.com | China | 8828 | 58 |
| SIMAGCHEM CORP | +86-5922680277 +86-13806087780 | sale@simagchem.com | China | 17346 | 58 |
| Win-Win chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 14304 | 58 |
| Aston Chemical | 13000000000 | sales@astonchem.com | United States | 1634 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52705 | 58 |
View Lastest Price from methyl 3-(2-bromophenyl)propanoate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2020-01-09 | methyl 3-(2-bromophenyl)propanoate
66191-86-4
|
$1.00 | 1ASSAYS | 85.0-99.8% | 20tons | Career Henan Chemical Co |
-
- methyl 3-(2-bromophenyl)propanoate
66191-86-4
- $1.00
- 85.0-99.8%
- Career Henan Chemical Co
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