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2-(Diphenylphosphino)-biphenyl

CAS No.
13885-09-1
Chemical Name:
2-(Diphenylphosphino)-biphenyl
Synonyms
2-Diphenylphosphine benzene;2-(DiphenylphosphiNA)-biphenyl;2-(Diphenylphosphino)-biphenyl;biphenyl-2-yldiphenylphosphine;o-Phenylphenyldiphenylphosphane;2-Biphenylyl(diphenyl)phosphine;2-(Diphenylphosphino)biphenyl >2-(Diphenylphosphino)-biphenyl,98%;2-(Diphenylphosphino)-1,1'-biphenyl;1,1'-biphenyl]-2-yldiphenylphosphine
CBNumber:
CB01856079
Molecular Formula:
C24H19P
Molecular Weight:
338.38
MDL Number:
MFCD11559063
MOL File:
13885-09-1.mol
Last updated:2025-07-24 18:13:45
Product description Number Pack Size Price
2-(Diphenylphosphino)biphenyl >98.0%(GC) D4688 1g $35
2-(Diphenylphosphinobiphenyl D492738 100mg $75
2-(Diphenylphosphino)-biphenyl FD140367 2g $70
2-(Diphenylphosphino)biphenyl J97841 25g $120
2-(Diphenylphosphino)biphenyl CS-W003792 25g $99
More product size

2-(Diphenylphosphino)-biphenyl Properties

Melting point 80.0 to 86.0 °C
Boiling point 473.2±24.0 °C(Predicted)
storage temp. Inert atmosphere,Room Temperature
form Solid
color White to Almost white
Water Solubility Slightly soluble in water.
CAS DataBase Reference 13885-09-1

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
HS Code  2931.90.9051
NFPA 704
1
2 0

2-(Diphenylphosphino)-biphenyl price More Price(34)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical D4688 2-(Diphenylphosphino)biphenyl >98.0%(GC) 13885-09-1 1g $35 2025-07-31 Buy
TRC D492738 2-(Diphenylphosphinobiphenyl 13885-09-1 100mg $75 2021-12-16 Buy
Biosynth Carbosynth FD140367 2-(Diphenylphosphino)-biphenyl 13885-09-1 2g $70 2021-12-16 Buy
AK Scientific J97841 2-(Diphenylphosphino)biphenyl 13885-09-1 25g $120 2021-12-16 Buy
ChemScene CS-W003792 2-(Diphenylphosphino)biphenyl 13885-09-1 25g $99 2021-12-16 Buy
Product number Packaging Price Buy
D4688 1g $35 Buy
D492738 100mg $75 Buy
FD140367 2g $70 Buy
J97841 25g $120 Buy
CS-W003792 25g $99 Buy

2-(Diphenylphosphino)-biphenyl Chemical Properties,Uses,Production

Uses

2-(Diphenylphosphino)biphenyl as ligand for suzuki reaction.

Uses

2-(Diphenylphosphino)biphenyl is used as an organic chemical synthesis intermediate.

Synthesis

2-Iodobiphenyl

2113-51-1

Diphenylphosphine

829-85-6

2-(Diphenylphosphino)-biphenyl

13885-09-1

General procedure for the synthesis of 2-(diphenylphosphino)-biphenyl from 2-iodobiphenyl and diphenylphosphine: MCM-41-3N-Pd(0) catalyst (21 mg, 0.01 mmol), KOAc (1.5 mmol), and 2-iodobiphenyl (1.0 mmol if solid) were placed in a 20 mL Schlenk tube that had been pre oven-dried. The reaction vessel was evacuated and displaced three times with argon. Subsequently, 2-iodobiphenyl (1.0 mmol, if liquid), diphenylphosphine (1.2 mmol) and DMAc (1 mL) were added via syringe under argon protection. The reaction mixture was stirred at 130°C for 3 hours. After the reaction was completed, the mixture was cooled to room temperature, diluted with CH2Cl2 (20 mL) and filtered.The MCM-41-3N-Pd(0) catalyst was washed with distilled water (2 × 5 mL) and ethanol (2 × 5 mL) for next use. The filtrate was concentrated under vacuum and the residue was purified by fast column chromatography on silica gel to afford the target product 2-(diphenylphosphino)-biphenyl.

References

[1] Organic Letters, 2003, vol. 5, # 13, p. 2315 - 2318
[2] Applied Organometallic Chemistry, 2018, vol. 32, # 8,
[3] Journal of Organometallic Chemistry, 2018, vol. 866, p. 50 - 58

2052-07-5
1079-66-9
13885-09-1
Synthesis of 2-(Diphenylphosphino)-biphenyl from 2-Bromobiphenyl and Chlorodiphenylphosphine
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View Lastest Price from 2-(Diphenylphosphino)-biphenyl manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-(Diphenylphosphino)-biphenyl pictures 2026-01-30 2-(Diphenylphosphino)-biphenyl
13885-09-1
US $1.00 / kg 1kg 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
2-(Diphenylphosphino)-biphenyl pictures 2025-12-23 2-(Diphenylphosphino)-biphenyl
13885-09-1
US $0.00-0.00 / KG 1KG 0.98 500KG XINXIANG RUNYU MATERIAL CO., LTD.
2-(Diphenylphosphino)biphenyl   pictures 2025-12-12 2-(Diphenylphosphino)biphenyl
13885-09-1
US $1.00-0.00 / KG 1KG 99% 20 tons Shaanxi Dideu Medichem Co. Ltd

2-(Diphenylphosphino)-biphenyl Spectrum

2-(Diphenylphosphino)-biphenyl 2-(DiphenylphosphiNA)-biphenyl o-Phenylphenyldiphenylphosphane biphenyl-2-yldiphenylphosphine 2-(Diphenylphosphino)-biphenyl,98% [1,1'-Biphenyl]-2-yldiphenylphosphine 2-Biphenylyl(diphenyl)phosphine 2-(Diphenylphosphino)biphenyl > Phosphine, [1,1'-biphenyl]-2-yldiphenyl- 2-(Diphenylphosphino)-1,1'-biphenyl 1,1'-biphenyl]-2-yldiphenylphosphine 2-Diphenylphosphine benzene 13885-09-1 Achiral Phosphine Aryl Phosphine