2-(Diphenylphosphino)-biphenyl
- CAS No.
- 13885-09-1
- Chemical Name:
- 2-(Diphenylphosphino)-biphenyl
- Synonyms
- 2-Biphenylyl(diphenyl)phosphine;2-Diphenylphosphine benzene;2-(DiphenylphosphiNA)-biphenyl;2-(Diphenylphosphino)-biphenyl;biphenyl-2-yldiphenylphosphine;o-Phenylphenyldiphenylphosphane;2-(Diphenylphosphino)biphenyl >2-(Diphenylphosphino)-biphenyl,98%;2-(Diphenylphosphino)-1,1'-biphenyl;1,1'-biphenyl]-2-yldiphenylphosphine
- CBNumber:
- CB01856079
- Molecular Formula:
- C24H19P
- Molecular Weight:
- 338.38
- MDL Number:
- MFCD11559063
- MOL File:
- 13885-09-1.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 80.0 to 86.0 °C |
|---|---|
| Boiling point | 473.2±24.0 °C(Predicted) |
| storage temp. | Inert atmosphere,Room Temperature |
| form | Solid |
| color | White to Almost white |
| Water Solubility | Slightly soluble in water. |
| CAS DataBase Reference | 13885-09-1 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| HS Code | 2931.90.9051 | |||||||||
| NFPA 704 |
|
2-(Diphenylphosphino)-biphenyl price More Price(57)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | D4688 | 2-(Diphenylphosphino)biphenyl >98.0%(GC) | 13885-09-1 | 1g | $35 | 2026-04-30 | Buy |
| TRC | TRC-D492738-50MG | 2-(Diphenylphosphinobiphenyl | 13885-09-1 | 50mg | $84 | 2026-06-03 | Buy |
| TRC | TRC-D492738-10MG | 2-(Diphenylphosphinobiphenyl | 13885-09-1 | 10mg | $65 | 2026-06-03 | Buy |
| TRC | TRC-D492738-100MG | 2-(Diphenylphosphinobiphenyl | 13885-09-1 | 100mg | $103 | 2026-06-03 | Buy |
| Apolloscientific | OR72340 | 2-(Diphenylphosphino)biphenyl ≥95% | 13885-09-1 | 1g | $21 | 2026-06-04 | Buy |
2-(Diphenylphosphino)-biphenyl Chemical Properties,Uses,Production
Uses
2-(Diphenylphosphino)biphenyl as ligand for suzuki reaction.
Uses
2-(Diphenylphosphino)biphenyl is used as an organic chemical synthesis intermediate.
Synthesis
2113-51-1
829-85-6
13885-09-1
General procedure for the synthesis of 2-(diphenylphosphino)-biphenyl from 2-iodobiphenyl and diphenylphosphine: MCM-41-3N-Pd(0) catalyst (21 mg, 0.01 mmol), KOAc (1.5 mmol), and 2-iodobiphenyl (1.0 mmol if solid) were placed in a 20 mL Schlenk tube that had been pre oven-dried. The reaction vessel was evacuated and displaced three times with argon. Subsequently, 2-iodobiphenyl (1.0 mmol, if liquid), diphenylphosphine (1.2 mmol) and DMAc (1 mL) were added via syringe under argon protection. The reaction mixture was stirred at 130°C for 3 hours. After the reaction was completed, the mixture was cooled to room temperature, diluted with CH2Cl2 (20 mL) and filtered.The MCM-41-3N-Pd(0) catalyst was washed with distilled water (2 × 5 mL) and ethanol (2 × 5 mL) for next use. The filtrate was concentrated under vacuum and the residue was purified by fast column chromatography on silica gel to afford the target product 2-(diphenylphosphino)-biphenyl.
References
[1] Organic Letters, 2003, vol. 5, # 13, p. 2315 - 2318
[2] Applied Organometallic Chemistry, 2018, vol. 32, # 8,
[3] Journal of Organometallic Chemistry, 2018, vol. 866, p. 50 - 58
2-(Diphenylphosphino)-biphenyl Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| ShangHai DEMO Chemical Co.,Ltd | 400-021-7337 2355568890 | sales@demochem.com | China | 2569 | 57 |
| Ark Pharm, Inc. | 847-367-3680 | sales@arkpharminc.com | United States | 1669 | 56 |
| Beijing HwrkChemical Technology Co., Ltd | 89508211 18501085097 | sales.bj@hwrkchemical.com | China | 9407 | 55 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| JinYan Chemicals(ShangHai) Co.,Ltd. | 13817811078 | sales@jingyan-chemical.com | China | 9963 | 60 |
| Jia Xing Isenchem Co.,Ltd | 0573-85285100 18627885956 | isenchem@163.com | China | 9389 | 66 |
| Beijing VSciChem Technology Co., Ltd. | 13811761079 | vscichem@163.com | China | 271 | 64 |
View Lastest Price from 2-(Diphenylphosphino)-biphenyl manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-08-07 | 2-(Diphenylphosphino)biphenyl
13885-09-1
|
$1.00 | 1KG | 99% | 20 tons | Shaanxi Dideu Medichem Co. Ltd | |
 |
2026-03-20 | 2-(Diphenylphosphino)-biphenyl
13885-09-1
|
$1.00 | 1kg | 99% | 10 mt | Hebei Chuanghai Biotechnology Co., Ltd | |
 |
2025-12-23 | 2-(Diphenylphosphino)-biphenyl
13885-09-1
|
1KG | 0.98 | 500KG | XINXIANG RUNYU MATERIAL CO., LTD. |
-
- 2-(Diphenylphosphino)biphenyl
13885-09-1
- $1.00
- 99%
- Shaanxi Dideu Medichem Co. Ltd
-
- 2-(Diphenylphosphino)-biphenyl
13885-09-1
- $1.00
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- 2-(Diphenylphosphino)-biphenyl
13885-09-1
- 0.98
- XINXIANG RUNYU MATERIAL CO., LTD.
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