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4,4'-Methylenebis(2,6-di-tert-butylphenol)

4,4'-Methylenebis(2,6-di-tert-butylphenol) Structure
4,4'-Methylenebis(2,6-di-tert-butylphenol) structure
CAS No.
118-82-1
Chemical Name:
4,4'-Methylenebis(2,6-di-tert-butylphenol)
Synonyms
e702;l3mb1;E 702;L 3MB1;lz-mb1;bimoxm;binoxm;etil702;LZ-MB 1;Bis-BHT
CBNumber:
CB0206363
Molecular Formula:
C29H44O2
Molecular Weight:
424.66
MDL Number:
MFCD00008822
MOL File:
118-82-1.mol
MSDS File:
SDS
Last updated:2025-06-13 21:11:40
Product description Number Pack Size Price
4,4′-Methylenebis(2,6-di-tert-butylphenol) for synthesis 8.42857 10g $40.8
4,4′-Methylenebis(2,6-di-tert-butylphenol) for synthesis 8.42857 100g $63.7
4,4'-Methylenebis(2,6-di-tert-butylphenol) >98.0%(GC) M0214 25g $29
4,4'-Methylenebis(2,6-di-tert-butylphenol) >98.0%(GC) M0214 500g $133
4,4''-Methylenebis(2,6-di-tert-butylphenol) M304435 500mg $60
More product size
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4,4'-Methylenebis(2,6-di-tert-butylphenol) Properties

Melting point 155-159 °C(lit.)
Boiling point 289 °C40 mm Hg(lit.)
Density 0.99 g/cm3 (20℃)
vapor pressure 0Pa at 25℃
refractive index 1.4875 (estimate)
Flash point 289°C/40mm
storage temp. Store below +30°C.
solubility <0.0001g/l
form solid
pka 12.03±0.40(Predicted)
color White
Water Solubility 31.9ng/L at 20℃
BRN 1916919
Stability Stable for 2 years from date of purchase as supplied. Solutions are not stable. Solutions must be made fresh and used within 1 working day.
InChIKey MDWVSAYEQPLWMX-UHFFFAOYSA-N
LogP 8.9 at 25℃
Indirect Additives used in Food Contact Substances 4,4'-METHYLENEBIS(2,6-DI-TERT-BUTYLPHENOL)
CAS DataBase Reference 118-82-1(CAS DataBase Reference)
FDA 21 CFR 175.105; 178.2010
FDA UNII 37N5K66648
NIST Chemistry Reference Phenol, 4,4'-methylenebis[2,6-bis(1,1-dimethylethyl)-(118-82-1)
EPA Substance Registry System Phenol, 4,4'-methylenebis[2,6-bis(1,1-dimethylethyl)- (118-82-1)
UNSPSC Code 12352104
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38-38-37-36
Safety Statements  26-36
WGK Germany  1
RTECS  SL9650000
TSCA  Yes
HS Code  29072990
Toxicity LD50 oral in rat: > 24gm/kg
NFPA 704
1
1 0

4,4'-Methylenebis(2,6-di-tert-butylphenol) price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.42857 4,4′-Methylenebis(2,6-di-tert-butylphenol) for synthesis 118-82-1 10g $40.8 2025-07-31 Buy
Sigma-Aldrich 8.42857 4,4′-Methylenebis(2,6-di-tert-butylphenol) for synthesis 118-82-1 100g $63.7 2025-07-31 Buy
TCI Chemical M0214 4,4'-Methylenebis(2,6-di-tert-butylphenol) >98.0%(GC) 118-82-1 25g $29 2025-07-31 Buy
TCI Chemical M0214 4,4'-Methylenebis(2,6-di-tert-butylphenol) >98.0%(GC) 118-82-1 500g $133 2025-07-31 Buy
TRC M304435 4,4''-Methylenebis(2,6-di-tert-butylphenol) 118-82-1 500mg $60 2021-12-16 Buy
Product number Packaging Price Buy
8.42857 10g $40.8 Buy
8.42857 100g $63.7 Buy
M0214 25g $29 Buy
M0214 500g $133 Buy
M304435 500mg $60 Buy

4,4'-Methylenebis(2,6-di-tert-butylphenol) Chemical Properties,Uses,Production

Description

bis-BHT (118-82-1) is a potent antioxidant. Cell permeable.

Chemical Properties

light yellow crystalline

Uses

Antioxidant.

Definition

ChEBI: 4,4'-Methylenebis(2,6-di-tert-butylphenol) is a diarylmethane.

Application

4,4'-Methylenebis(2,6-di-tert-butylphenol), also known as H2-4DBP, could be used as a ligand to react with sets of M(OR)x and MRx. The ligand possesses more flexibility than OBzP or catecholate derivatives, and the para-OH makes it of interest for controlled alcoholysis. This compound has several characteristics, including (i) the ortho position possesses the sterically hindering t-butyl group which will assist in minimizing oligomerization, (ii) the para linkage prevents chelation of the 4DBP ligand to the metal upon coordination, and (iii) may act as a valuable model for complexation behavior of the plastic precursor bisphenol-A [BPA; 4,4' -(propane-2,2-diyl)diphenol] that has become of recent concern[2].

Flammability and Explosibility

Non flammable

References

1) Amorati et al. (2003), Antioxidant activity of 0-bisphenols: the role of intramolecular hydrogen bonding; J. Org. Chem. 68 5198.
[2] T. Boyle, Daniel T Yonemoto, L. Steele. “Synthesis and characterization of 4,4′-methylenebis (2,6-di-tert-butylphenol) derivatives of a series of metal alkoxides and alkyls.” Journal of Coordination Chemistry 65.1(2012): 487–505.

4,4'-Methylenebis(2,6-di-tert-butylphenol) synthesis

88-26-6
118-82-1
Synthesis of 4,4'-Methylenebis(2,6-di-tert-butylphenol) from 3,5-Di-tert-butyl-4-hydroxybenzyl alcohol

4,4'-Methylenebis(2,6-di-tert-butylphenol) Preparation Products And Raw materials

Raw materials

2,6-Di-tert-butylphenol 3,5-DI-TERT-BUTYL-4-HYDROXYBENZYL ETHER 3,5-di-tert-butyl-4-hydroxybenzyl acetate 3,5-Di-tert-butyl-4-hydroxybenzyl alcohol 4,4'-[2,4,6-Trimethyl-1,3-phenylenebis(methylene)]bis[2,6-di(tert-butyl)phenol]
Antioxidant 1330 2,6-Di-tert-butyl-4-(dimethylaminomethyl)phenol Mesitylene Formaldehyde

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Preparation Products

3,5-di-tert-butyl-4-hydroxybenzyl acetate 4,4'-Ethylenebis(2,6-ditert-butylphenol)

4,4'-Methylenebis(2,6-di-tert-butylphenol) Suppliers

Global( 253)Suppliers
Supplier Tel Email Country ProdList Advantage
Qingdao Scienoc Chemical CO Ltd
+86-0532-68076095 +8618661673503 info@scienoc.com China 113 58
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.
+8618950047208 ellena@amitychem.com China 43416 58
Wuhan Kemi-Works Chemical Co., Ltd. 		+86-2785736489 +8618171418573 sales@kemiworks.com China 782 58
Hebei Chuanghai Biotechnology Co., Ltd 		+8615531151365 mina@chuanghaibio.com China 18126 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 20168 58
Hebei Zhuanglai Chemical Trading Co.,Ltd 		+8613343047651 admin@zlchemi.com China 3692 58
Shanghai Tiandui New Material Co., Ltd 		+8615921093949 tianduichemical@shtiandui.com China 60 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21614 55
Zjartschem 		+86-571 87238903 jocelynpan@zjarts.com CHINA 988 58
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29849 58
Supplier Advantage
Qingdao Scienoc Chemical CO Ltd
58
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.
58
Wuhan Kemi-Works Chemical Co., Ltd. 		58
Hebei Chuanghai Biotechnology Co., Ltd 		58
Henan Fengda Chemical Co., Ltd 		58
Hebei Zhuanglai Chemical Trading Co.,Ltd 		58
Shanghai Tiandui New Material Co., Ltd 		58
Henan Tianfu Chemical Co.,Ltd. 		55
Zjartschem 		58
career henan chemical co 		58

View Lastest Price from 4,4'-Methylenebis(2,6-di-tert-butylphenol) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4,4'-Methylenebis(2,6-di-tert-butylphenol) pictures 2025-11-24 4,4'-Methylenebis(2,6-di-tert-butylphenol)
118-82-1
 0.99 RongNa Biotechnology Co.,Ltd
4,4'-Methylenebis(2,6-di-tert-butylphenol) pictures 2025-11-18 4,4'-Methylenebis(2,6-di-tert-butylphenol)
118-82-1
 US $1.10 / g 1g 99.00% 100 Tons Min Dideu Industries Group Limited
4,4'-Methylenebis(2,6-di-tert-butylphenol) pictures 2025-11-04 4,4'-Methylenebis(2,6-di-tert-butylphenol)
118-82-1
 US $0.00 / kg 25kg 98.0% 1800 Tons Shanghai Tiandui New Material Co., Ltd

4,4'-Methylenebis(2,6-di-tert-butylphenol) Spectrum

4,4'-Methylenebis(2,6-di-tert-butylphenol)(118-82-1)MS4,4'-Methylenebis(2,6-di-tert-butylphenol)(118-82-1)1HNMR4,4'-Methylenebis(2,6-di-tert-butylphenol)(118-82-1)13CNMR4,4'-Methylenebis(2,6-di-tert-butylphenol)(118-82-1)IR14,4'-Methylenebis(2,6-di-tert-butylphenol)(118-82-1)IR24,4'-Methylenebis(2,6-di-tert-butylphenol)(118-82-1)ESR

118-82-1(4,4'-Methylenebis(2,6-di-tert-butylphenol))Related Search:

Butyl acetate Antioxidant 1098 3-tert-Butylphenol 4-tert-Butylphenol tert-Butanol
p-Cresol tert-Butyl peroxyacetate Antioxidant 1010 2-sec-Butylphenol 2,4-Di-tert-butylphenol
2,6-Di-tert-butylphenol 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) tert-Butyldimethylsilyl chloride 4-Butylphenol 4,4'-Thiobis(6-tert-butyl-m-cresol)
Antioxidant 1520 Butyl acrylate Butylated Hydroxytoluene

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4,4'-Methylenebis(2,6-di-tert-butylphenol) TIMTEC-BB SBB007948 RARECHEM AQ BD 0024 RALOX(R) 02 S Antioxidant 728 Tetra-tert-butylbisphenol F 2,6-ditert-butyl-4-(3,5-ditert-butyl-4-hydroxy-benzyl)phenol 2,6-ditert-butyl-4-[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]phenol 2,6-ditert-butyl-4-[(3,5-ditert-butyl-4-hydroxy-phenyl)methyl]phenol 4.4'-Methylene bis-(2.6-di-tert-butylphenol) 3g [118-82-1] 4,4zzhlxy-Methylenebis(2,6-di-tert-butylphenol) 4,4-METHYLENEBIS(2,6-DITERTIARYBUTYLPHENOL) 4, 4'-Methylen-bis(2,6-di-tert.-butylphenol) 4,4''-DIHYDROXY-3,3,5,5''-TETRA-TERT-BUTYLDIPHENYLMETHANE 98+% 4,4’-methylenebis(2,6-bis(1,1-dimethylethyl)-pheno 4,4’-methylenebis(2,6-bis(1,1-dimethylethyl)phenol) 4,4’-methylenebis(2,6-di-t-butylphenol) 4,4’-methylenebis(2,6-di-tert-butyl-pheno 4,4’-methylenebis[2,6-bis(1,1-dimethylethyl)-pheno 4,4’-methylenebis[2,6-bis(1,1-dimethylethyl)-Phenol Ethyl 702 ethyl702 Etil 702 etil702 Ionox 220 Ionox 220 Antioxidant ionox220 ionox220antioxidant L 3MB1 l3mb1 LZ-MB 1 lz-mb1 MB 1 (Antioxidant) Methylenebisdibutylphenol RALOX 02 S Bis-BHT JADEWIN AN 702 4,4'-Dihydroxy,3,3'-5,5'-tetra-t-butyldiphenylmethane 4,4'-Dihydroxy-3,5,3',5'-tetra-tert-butyldiphenylmethane 4,4'-Methylenebis(2,6-di-t-butylphenol) Antioxidant E 702 antioxidante702 Bimox M bimoxm Binox M binoxm binox-m bis(4-Hydroxy-3,5-ditertbutyl)phenylmathane Di(4-hydroxy-3,5-di-tert-butylphenyl)methane E 702 e702 mb1(antioxidant) nsc30551 Phenol, 4,4'-methylenebis*2,6-bis(1,1-dimethylethyl)- Phenol, 4,4'-methylenebis*2,6-di-tert-butyl- Phenol, 4,4'-methylenebis[2,6-di-tert-butyl- Antioxidant 702 BIS(3,5-DI-TERT-BUTYL-4-HYDROXYPHENYL)METHANE