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methyl 4-cyano-2-methylbenzoate

methyl 4-cyano-2-methylbenzoate Structure
methyl 4-cyano-2-methylbenzoate structure
CAS No.
103261-67-2
Chemical Name:
methyl 4-cyano-2-methylbenzoate
Synonyms
methyl 4-cyano-2-methylbenzoate;methyl 4-cyano-2-methylbenzoate 97%;4-cyano-2-methylBenzoic acid methyl ester;Benzoic acid, 4-cyano-2-methyl-, methyl ester;Methyl4-cyano2-methylbenzoateMethyl4-cyano2-methylbenzoate
CBNumber:
CB02514738
Molecular Formula:
C10H9NO2
Molecular Weight:
175.18
MDL Number:
MFCD18399110
MOL File:
103261-67-2.mol
MSDS File:
SDS
Last updated:2026-08-06 14:26:04
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methyl 4-cyano-2-methylbenzoate Properties

Boiling point 302.7±30.0 °C(Predicted)
Density 1.15±0.1 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
Appearance Off-white to brown Solid

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
HS Code  2926907090

methyl 4-cyano-2-methylbenzoate price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Biosynth DEA26167 Methyl 4-cyano-2-methylbenzoate 103261-67-2 2.5g $354 2026-06-04 Buy
Apolloscientific OR916717 Methyl 4-cyano-2-methylbenzoate 97% 103261-67-2 1g $21 2026-06-04 Buy
Apolloscientific OR916717 Methyl 4-cyano-2-methylbenzoate 97% 103261-67-2 5g $22 2026-06-04 Buy
Apolloscientific OR916717 Methyl 4-cyano-2-methylbenzoate 97% 103261-67-2 25g $89 2026-06-04 Buy
Apolloscientific OR916717 Methyl 4-cyano-2-methylbenzoate 97% 103261-67-2 100g $353 2026-06-04 Buy
Product number Packaging Price Buy
DEA26167 2.5g $354 Buy
OR916717 1g $21 Buy
OR916717 5g $22 Buy
OR916717 25g $89 Buy
OR916717 100g $353 Buy

methyl 4-cyano-2-methylbenzoate Chemical Properties, Uses, Production

Uses

Methyl 4-cyano-2-methylbenzoate is a carboxylate derivative and can be used as an intermediate in organic synthesis.

Synthesis

ZINC CYANIDE

557-21-1

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER

99548-55-7

methyl 4-cyano-2-methylbenzoate

103261-67-2

Example 3.6: Preparation of methyl 4-bromo-2-methylbenzoate; Methyl 4-bromo-2-methylbenzoate (108 g, 471 mmol) was dissolved in N,N-dimethylformamide (4 L) under nitrogen protection followed by the addition of zinc(II) cyanide (88.5 g, 753.6 mmol) and tetrakis(triphenylphosphine)palladium(0) (65 g, 56.60 mmol). The reaction mixture was stirred at 100 °C for 16 hours. After completion of the reaction, the reaction mixture was diluted with toluene for phase separation. The aqueous phase was extracted twice with toluene. All organic phases were combined and washed sequentially with brine and saturated aqueous ammonium hydroxide solution, dried over anhydrous sodium sulfate and concentrated. The crude product was purified by silica gel column chromatography (eluent: ethyl acetate/cyclohexane, 1:5, v/v) to afford methyl 4-cyano-2-methylbenzoate (73 g, 89% yield).1H NMR (400 MHz, CDCl3): δ 7.78 (d, 1H), 7.52 (m, 2H), 3.92 (s, 3H), 2.62 (s, 3H).

References

[1] Patent: WO2010/127926, 2010, A1. Location in patent: Page/Page column 46
[2] Patent: WO2010/127928, 2010, A1. Location in patent: Page/Page column 32
[3] ChemBioChem, 2016, vol. 17, # 8, p. 759 - 767
[4] Patent: US2012/129832, 2012, A1. Location in patent: Page/Page column 11-12
[5] Patent: WO2013/75083, 2013, A1. Location in patent: Paragraph 00467; 00469

methyl 4-cyano-2-methylbenzoate Preparation Products And Raw materials

Raw materials

ZINC CYANIDE 4-Bromo-2-methylbenzoic acid Benzoic acid,4-bromo-2-methyl-,methyl ester

Preparation Products

methyl 4-cyano-2-methylbenzoate Suppliers

Global Suppliers ( 109)
Supplier Tel Email Country ProdList Advantage
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Changzhou Huanling Chemical Co., Ltd. 89803005 18206112582 info@huanlingchem.com China 983 68
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Shanghai Topbiochem Technology Co., Ltd 021-58170097 info@topbiochem.com China 9509 58
Nanjing ShengSai Chemical Co., Ltd. 025-85205967 13951876367 shengsaichem@163.com China 818 58
Suzhou Sino Rare Chemical Co., Ltd. 0512-62857507 sales@sinorarechem.com China 999 58
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Beijing Wuyunyongchang Science and Technology Co., Ltd. 15210642910 moon5.1days@126.com China 202 56
ShangHai AmK Pharmaceutical Technology Co., Ltd. 微信 18019252918 18019252918 sale@amkchem.com China 14982 55
Hangzhou J&H Chemical Co., Ltd. 0571-87396432 sales@jhechem.com China 14905 59
Supplier Advantage
Energy Chemical 61
Changzhou Huanling Chemical Co., Ltd. 68
Shanghai Hanhong Scientific Co.,Ltd. 64
Shanghai Topbiochem Technology Co., Ltd 58
Nanjing ShengSai Chemical Co., Ltd. 58
Suzhou Sino Rare Chemical Co., Ltd. 58
Bide Pharmatech Ltd. 60
Beijing Wuyunyongchang Science and Technology Co., Ltd. 56
ShangHai AmK Pharmaceutical Technology Co., Ltd. 55
Hangzhou J&H Chemical Co., Ltd. 59

View Latest Price from methyl 4-cyano-2-methylbenzoate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
methyl 4-cyano-2-methylbenzoate pictures 2026-08-07 methyl 4-cyano-2-methylbenzoate
103261-67-2
 1KG 98% 1000kgs Shaanxi Dideu New Materials Co. Ltd

methyl 4-cyano-2-methylbenzoate Spectrum

methyl 4-cyano-2-methylbenzoate(103261-67-2)1HNMR

103261-67-2 (methyl 4-cyano-2-methylbenzoate) Related Search:

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methyl 4-cyano-2-methylbenzoate 4-cyano-2-methylBenzoic acid methyl ester Benzoic acid, 4-cyano-2-methyl-, methyl ester Methyl4-cyano2-methylbenzoateMethyl4-cyano2-methylbenzoate methyl 4-cyano-2-methylbenzoate 97% 103261-67-2 03261-67-2