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ChemicalBook >> CAS DataBase List >>(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride

(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride

(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride Structure
(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride structure
CAS No.
135620-04-1
Chemical Name:
(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride
Synonyms
(S,S)-JACOBSEN CATALYST;(S,S)-JACOBSEN'S CATALYST;(S,S)-Jacbosen;(S,S)-JACOBSEN;(S,S)-Jacobsencat.;JACOBSEN'S CATALYST;-1,2-cyclohexanediamine]manganese(III);(S,S)-(+)-Jacobsen manganese (III) catalyst;(S,S)-JACOBSEN'S CATALYST MANGANESE(III) CHLORIDE COMPLEX;(+)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO- HEXANEDIAMINO-MN CL
CBNumber:
CB0286099
Molecular Formula:
C36H52ClMnN2O2
Molecular Weight:
635.2
MDL Number:
MFCD02101663
MOL File:
135620-04-1.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-09-12 18:48:05
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(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride Properties

Melting point 330-332 °C(lit.)
storage temp. Inert atmosphere,Room Temperature
form Powder
color brown
InChIKey VGAJDQCIDNCJQC-JINVCYSXSA-K
SMILES CC(C)(C)c1cc2C=[N@@H]3[C@H]4CCCC[C@@H]4[N@H]5=Cc6cc(cc(c6O[Mn]35(Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C
CAS DataBase Reference 135620-04-1
FDA UNII RIM5C05I0Z
UNSPSC Code 12352101
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38-20/21/22
Safety Statements  26-36-36/37/39
WGK Germany  3
F  9
HS Code  29310099
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride price More Price(31)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 404454 (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 135620-04-1 1g $62.9 2026-04-30 Buy
Sigma-Aldrich 404454 (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 135620-04-1 5g $206 2026-04-30 Buy
Strem Chemicals 25-0301 (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III) chloride, 98% (S,S)-Jacobsen Cat. 98% 135620-04-1 1g $50 2026-04-30 Buy
Strem Chemicals 25-0301 (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III) chloride, 98% (S,S)-Jacobsen Cat. 98% 135620-04-1 5g $192 2026-04-30 Buy
Biosynth FB29346 (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 135620-04-1 0.01kg $322.13 2026-06-04 Buy
Product number Packaging Price Buy
404454 1g $62.9 Buy
404454 5g $206 Buy
25-0301 1g $50 Buy
25-0301 5g $192 Buy
FB29346 0.01kg $322.13 Buy

(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride Chemical Properties,Uses,Production

Reaction

  1. Catalyst for the conversion of olefins to chiral epoxides in high enantiomeric excess.
  2. Pharmaceutically important, single enantiomer amino alcohols are efficiently produced from the corresponding chiral epoxide by acid or base-catalyzed epoxide ring-opening reactions.
  3. Asymmetric Kinetic resolution of secondary alcohols in water.
  4. Enantioselective Reformatsky reaction with ketones.
Reactions of 135620-04-1

Chemical Properties

dark brown powder

Uses

Reactant involved in:

  • Studies of intercalative binding with ct-DNA and radical scavenging antioxidant activity
  • Immobilization on phenoxy-modified zirconium poly(styrenephenylvinylphosphonate)
  • Synthesis of derivatvies for studies of conformational models of enantioselective reactions

Catalyst involved in:
  • Asymmetric epoxidation of olefins
  • Immobilization on ionic liquid modified mesoporous silica for oxidative kinetic resolution of racemic secondary alcohols
  • Immobilization on diamine modified zirconium olig-styrenyl phosphonate hydrogen phosphate for epoxidation of styrene
', 'Salen (Mn)-catalyzed asymmetric epoxidation of unfunctionalized olefins. High enantioselectivities and yields are obtained for a variety of substrates, especially cis-alkenes. A few applications include the synthesis of the taxol side chain and cis-1-amino-2-indanol. Jacobsenμs catalyst has also been used in the asymmetric α-hydroxylation of silyl enol ethers. Catalyst for the enantioselective epoxidation of a variety of olefins.

(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride Preparation Products And Raw materials

Raw materials

Preparation Products

(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride Suppliers

Global( 108)Suppliers
Supplier Tel Email Country ProdList Advantage
Chengdu Forest Science and Technology Development Co., Ltd. 18030648795 18030648795 sales@cdforestchem.com China 1998 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Jia Xing Isenchem Co.,Ltd 0573-85285100 18627885956 isenchem@163.com China 9389 66
Innochem(Beijing) Technology Co.,Ltd. 010-56541685 13070143590 sales@innochem.cn China 172 57
Tianjin Derchemist Science & Technology Co., Ltd. 22-58627059 13920586291 zdcomcon@126.com China 4094 50
Thermo Fisher Scientific 800-810-5118 cnchemical@thermofisher.com China 17752 75
Shanghai T&W Pharmaceutical Co., Ltd. +86 21 61551611 China 9874 58
Shanghai Incat Chemtech Co.,Ltd. 021-57603038 13601791340;13818007232 307593986@qq.com China 475 58
Supplier Advantage
Chengdu Forest Science and Technology Development Co., Ltd. 58
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Energy Chemical 61
Jia Xing Isenchem Co.,Ltd 66
Innochem(Beijing) Technology Co.,Ltd. 57
Tianjin Derchemist Science & Technology Co., Ltd. 50
Thermo Fisher Scientific 75
Shanghai T&W Pharmaceutical Co., Ltd. 58
Shanghai Incat Chemtech Co.,Ltd. 58

View Lastest Price from (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE pictures 2020-01-08 (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
135620-04-1
 $1.00 1KG 99.0% 100kg Career Henan Chemical Co

(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride Spectrum

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE(135620-04-1)FT-IR(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE(135620-04-1)IR

135620-04-1((S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride)Related Search:

(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine (1S,2S)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chromium(III)chloride (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride (1S,2S)-(+)-[1,2-Cyclohexanediamino-n N'-bis(3,5-di-t-butylsalicylidene)]chromium (III) chloride
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(+)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO- HEXANEDIAMINO-MN CL (S,S)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYL- IDENE)-1,2-CYCLOHEXANEDIAMINO-MN-CL (1S,2S)-(+)-(1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene))manganese(III)chloride (S,S)-Jacobsencat. (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III)chloride,98%(S,S)-JacobsenCat. (S,S)(+)N,N'-Bis(3,5-di-tbutylsalicylidene)1,2-chexanediaminomanganese(iii)chlorideco (S,S)-(+)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chlo (1S,2S)-(+)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]Manganese(III) chloride (S,S)-Jacobsen Cat. (1S,2S)-(+)-〔1,2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕manganese(Ⅲ) Chloride (1S,2S)-(+)-[1,2-Cyclohexanediammino-N,N'-bis(3,5-di-t-butylsalicylidene)] manganese (III)chloride,98% (S,S)-Jacobsen Cat (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride (S,S)-(+)-N,N′-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride (S,S)-Jacbosen -1,2-cyclohexanediamine]manganese(III) (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE JACOBSEN'S CATALYST (S,S)-JACOBSEN'S CATALYST MANGANESE(III) CHLORIDE COMPLEX (S,S)-JACOBSEN (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE ISO 9001：2015 REACH (III)(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) (S, S) - (+) - N, N '- bis (3,5-di-tert-butylsalicyl) -1,2-cyclohexanediamine manganese chloride (S,S)-(+)-Jacobsen manganese (III) catalyst (4S,9S)-14,16,22,24-tetra-tert-butyl-18,20-dioxa-3,10-diaza-19-manganatetracyclo[19.4.0.0?,?.012,1?]pentacosa-1(25),2,10,12,14,16,21,23-octaen-19-ylium chloride (1S,2S)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III) chloride (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride (1S,2S)-[1,2-Cyclohexanediamino-N,N’-bis(3,5-di-t-butylsalicylidene)]manganese?chloride (S,S)-(+)N,N'-bis(3,5-ditert-butyl)-1,2-cyclohexyldiaminechloromanganese (S,S)-JACOBSEN CATALYST (S,S)-JACOBSEN'S CATALYST (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride 135620-04-1 CH33C2C6H22OCHN2C6H10MnCl C36H54Cl3MnN2O2 Chiral Catalysts, Ligands, and Reagents Asymmetric Synthesis Epoxidation Chiral Reagents Jacobsen Metal Other Metal