ChemicalBook >> CAS DataBase List >>(R)-(+)-2,2'-Diamino-1,1'-binaphthalene
(R)-(+)-2,2'-Diamino-1,1'-binaphthalene
- CAS No.
- 18741-85-0
- Chemical Name:
- (R)-(+)-2,2'-Diamino-1,1'-binaphthalene
- Synonyms
- (R)-BINAM;(R)-[1,1'-Binaphthalene]-2,2'-diamine;R(+)-DABN;S(-)-DABN;2,2-DIAMINO-1,1'-BINAPHTHALENE;(R)-(+)-1,1'-BI(2-NAPHTHYLAMINE);(+)-1,1'-Binaphthyl-2,2'-diamine;(R)-(+)-2,2'-Diamino-1,1'-biphthyl;(aR)-2,2'-Diamino-1,1'-binaphthalene;(aR)-1,1'-Binaphthalene-2,2'-diamine
- CBNumber:
- CB0357339
- Molecular Formula:
- C20H16N2
- Molecular Weight:
- 284.35
- MDL Number:
- MFCD00145204
- MOL File:
- 18741-85-0.mol
- MSDS File:
- SDS
- TDS File:
- TDS
Last updated:2026-05-27 22:41:06
| Melting point | 242-244 °C(lit.) |
|---|---|
| alpha | 156 º (c=1, pyridine) |
| Boiling point | 416.85°C (rough estimate) |
| Density | 1.0447 (rough estimate) |
| refractive index | 1.6450 (estimate) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly) |
| pka | 3.79±0.10(Predicted) |
| form | Powder |
| color | slightly beige |
| optical activity | [α]20/D +157°, c = 1 in pyridine |
| Water Solubility | slightly soluble |
| BRN | 5279621 |
| InChI | 1S/C20H16N2/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12H,21-22H2 |
| InChIKey | DDAPSNKEOHDLKB-UHFFFAOYSA-N |
| SMILES | Nc1ccc2ccccc2c1-c3c(N)ccc4ccccc34 |
| CAS DataBase Reference | 18741-85-0(CAS DataBase Reference) |
| FDA UNII | XI03TW52AO |
| UNSPSC Code | 12352005 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xn,Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-39-37/39-36 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | DU3090000 | |||||||||
| F | 10 | |||||||||
| HS Code | 29215900 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
(R)-(+)-2,2'-Diamino-1,1'-binaphthalene price More Price(69)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 382426 | (R)-(+)-1,1′-Binaphthyl-2,2′-diamine 99% | 18741-85-0 | 1g | $245 | 2026-04-30 | Buy |
| TCI Chemical | D3207 | (R)-(+)-1,1'-Binaphthyl-2,2'-diamine >98.0%(HPLC)(T) | 18741-85-0 | 200mg | $41 | 2026-04-30 | Buy |
| Strem Chemicals | 07-0327 | (R)-(+)-2,2'-Diamino-1,1'-binaphthyl, 99% 99% | 18741-85-0 | 250mg | $78 | 2026-04-30 | Buy |
| Strem Chemicals | 07-0327 | (R)-(+)-2,2'-Diamino-1,1'-binaphthyl, 99% 99% | 18741-85-0 | 1g | $225 | 2026-04-30 | Buy |
| TRC | TRC-B387010-5G | (R)-(+)-[1,1'-Binaphthalene]-2,2'-diamine | 18741-85-0 | 5g | $651 | 2026-06-03 | Buy |
(R)-(+)-2,2'-Diamino-1,1'-binaphthalene Chemical Properties, Uses, Production
Synthesis
(R)-(+)-2,2'-Diamino-1,1'-binaphthalene can be 1a , 2b, potassium carbonate, potassium iodide, dimethyl sulfoxide as a reaction solvent, then react with adding potassium hydroxide, and finally extract with ethyl acetate And get.
Physical properties
(R)-(+)-2,2'-Diamino-1,1'-binaphthalene is a off-white to brown powder.
Uses
(R)-(+)-1,1'-Bi(2-naphthylamine) derivatives have been used for asymmetric hydrogenations, cyclopropanations and formation of chiral lactones. It can be used for the synthesis of sterically hindered binaphthalene-based monophosphane ligands.
General Description
(R)-(+)-1,1′-Binaphthyl-2,2′-diamine is an axially dissymmetric binaphthyl ligand mainly used in enantioselective catalysis.
References
[1] Patent: CN107814729, 2018, A. Location in patent: Paragraph 0170-0173; 0254-0257
[2] Organic and Biomolecular Chemistry, 2016, vol. 14, # 38, p. 9021 - 9032
(R)-(+)-2,2'-Diamino-1,1'-binaphthalene Preparation Products And Raw materials
Raw materials
Preparation Products
Global Suppliers ( 186)
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Daicel Chiral Technologies (China)CO.,LTD | 021-50460086-9 15921403865 | han_yajun@dctc.daicel.com | China | 7909 | 65 |
| Zhengzhou HQ Material Co., Ltd. | +86-0371-67759225 13526468238 | 3165471285@qq.com | China | 342 | 55 |
| Chengdu Forest Science and Technology Development Co., Ltd. | 18030648795 18030648795 | sales@cdforestchem.com | China | 1997 | 58 |
| Xinxiang Runyu Material Co., Ltd. | 166-166-37336996 15690792173 | chenxi.song@runvmat.com | China | 282 | 55 |
| Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51389 | 80 |
| Shanghai Boyle Chemical Co., Ltd. | sales@boylechem.com | China | 2915 | 55 | |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
View Latest Price from (R)-(+)-2,2'-Diamino-1,1'-binaphthalene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-09-17 | (R)-(+)-1,1'-Bi(2-naphthylamine)
18741-85-0
|
$86.00-296.00 | 5g | 0.97 | 25kg | Shanghai UCHEM Inc. | |
 |
2026-08-25 | (R)-(+)-2,2'-Diamino-1,1'-binaphthalene
18741-85-0
|
$2.00-5.00 | 1kg | 99% | 100kg | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | |
 |
2025-12-23 | (R)-(+)-1,1'-binaphthyl-2,2'-diamine
18741-85-0
|
1KG | 0.99 | 500kg | XINXIANG RUNYU MATERIAL CO., LTD. |
-
- (R)-(+)-1,1'-Bi(2-naphthylamine)
18741-85-0
- $86.00-296.00
- 0.97
- Shanghai UCHEM Inc.
-
- (R)-(+)-2,2'-Diamino-1,1'-binaphthalene
18741-85-0
- $2.00-5.00
- 99%
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
-
- (R)-(+)-1,1'-binaphthyl-2,2'-diamine
18741-85-0
- 0.99
- XINXIANG RUNYU MATERIAL CO., LTD.
18741-85-0 ((R)-(+)-2,2'-Diamino-1,1'-binaphthalene) Related Search:
(R)-(+)-1,1''-BINAPHTHALENE-2,2''-DIAMINE (R-BINAM) ((R)-(+) -2,2''-DIAMINO-1''1-BINAPHTHYL)
(R)-(+)-1,1μ-Binaphthalene-2,2μ-diamine, (R)-(+)-2,2μ-Diamino-1,1μ-binaphthalene, (R)-(+)-DABN
(R)-(+)-1,1μ-Bi(2-naphthylamine), (R)-(+)-1,1μ-Binaphthalene-2,2μ-diamine, (R)-(+)-2,2μ-Diamino-1,1μ-binaphthalene, (R)-(+)-DABN
(aR)-1,1'-Binaphthalene-2,2'-diamine
(aR)-2,2'-Diamino-1,1'-binaphthalene
[aR,(+)]-1,1'-Binaphthalene-2,2'-diamine
(R)-(+)-1,1'-BINAPHTHYL-2,2'-DIAMINE, 99 % (99% EE/GLC)
(R)-(+)-2,2'-Diamino-1,1'-binaphthyl,99%
(R)-(+)-2,2'-Diamino-1,1'-binaphthalene,99%
(R)-(+)-1,1'-Binaphthyl-2,2'-diamine
(R)-(+)-1,1'-Binaphthyl-2,2'-diamine 99%
(R)-(+)-1,1′-Binaphthyl-2,2′-diamine, >=98%
(R)-[1,1'-Binaphthalene]-2,2'-diamine,99%e.e.
(+/-)-2,2'-DIAMINO-1,1'-BINAPHTHALENE
2,2-DIAMINO-1,1'-BINAPHTHALENE
R(+)-DABN
(S)-(-)-2,2'-DIAMINO-1,1'-BINAPHTHYL
S(-)-1,1'-BINAPHTHALENE-2,2'-DIAMINE
S(-)-DABN
(R)-(+)-1,1'-BI(2-NAPHTHYLAMINE)
R(+)-1,1'-BINAPHTHALENE-2,2'-DIAMINE
RACEMIC-2,2'-DIAMINO-1,1'-BINAPHTHYL
(R)-(+)-2,2'-DIAMINO-1,1-BINAPHTHALENE
(R)-(+)-2,2-DIAMINO-1,1'-BINAPHTHALENE
R-(+)-2,2'-DIAMINO-1,1'-BINAPHTHALENE
(+/-)-1,1'-BINAPHTHALENE-2,2'-DIAMINE
[1,1'-Binaphthalene]-2,2'-diamine, (1R)-
1-(2-aminonaphthalen-1-yl)naphthalen-2-amine
(R)-(+)-2,2'-Diamino-1,1'-binaphthyl,99%,99%ee
(R)-[1,1'-Binaphthalene]-2,2'-diamine
[(R)-Binam]
(+)-1,1'-Binaphthyl-2,2'-diamine
(R)-(+)-2,2′-Diamino-1,1′-binaphthalene((R)-Binam)
(R)-(+)-2,2'-Diamino-1,1'-binaphthalene
(R)-(+)-1,1'-binaphthyl-2,2'-diamine
(R)-[1,1'-Binaphthalene]-2,2'-diamine
[(R)-Binam
(R)-(+)-2,2'-Diamino-1,1'-binaphthyl
(R)-(+)-1,1′-Bi(2-naphthylamine), CAS 18741-85-0
(R)-(+)-2,2'-DIAMINO-1,1'-BINAPHTHALENE 99%
(R)-(+)-2,2'-Diamino-1,1'-biphthyl
(R)-[1,1'-Binaphthalene]-2,2'-diamine
(R)-BINAM
18741-85-0
Asymmetric Synthesis
Polyamines
Other Chiral Ligands
Organic Building Blocks
Nitrogen Compounds
Chiral Catalysts, Ligands, and Reagents
Building Blocks
BINAM Series
Achiral Nitrogen
