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Boron dichloride-methyl sulfide complex

CAS No.
63462-42-0
Chemical Name:
Boron dichloride-methyl sulfide complex
Synonyms
Dichloroborane dimethyl sulfide;Dichloro(dimethyl sulfide)borane;DICHLOROBORANE-METHYL SULFIDE COMPLEX;Dichloro(dimethyl sulfide)(hydro)boron;Boron dichloride-methyl sulfide complex;Dichloroborane methyl sulfide complex in excess methyl sulfide
CBNumber:
CB0368298
Molecular Formula:
C2H7BCl2S
Molecular Weight:
144.86
MDL Number:
MFCD00013209
MOL File:
63462-42-0.mol
MSDS File:
SDS
Last updated:2026-09-12 18:48:19

Boron dichloride-methyl sulfide complex Properties

Density 1.255 g/mL at 25 °C(lit.)
Flash point 75 °F
solubility Sol benzene, carbon tetrachloride, dichloromethane, diethyl ether, THF
InChI 1S/C2H7BCl2S/c1-6(2)3(4)5/h3H,1-2H3
InChIKey UMDZKXAEAKAIPA-UHFFFAOYSA-N
SMILES C[S+](C)[BH-](Cl)Cl
UNSPSC Code 12352101
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Corrosion (GHS05)
GHS02,GHS05
Signal word  Danger
Hazard statements  H226-H314
Precautionary statements  P210-P233-P240-P280-P303+P361+P353-P305+P351+P338
PPE Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes  C
Risk Statements  10-14-34
Safety Statements  16-26-36/37/39-45
RIDADR  UN 2920 8/PG 2
WGK Germany  3
HazardClass  3.2
PackingGroup  III
Storage Class 3 - Flammable liquids
Hazard Classifications Flam. Liq. 3
Skin Corr. 1B

Boron dichloride-methyl sulfide complex price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 298433 Dichloroborane methyl sulfide complex in excess methyl sulfide 63462-42-0 50g $350 2026-04-30 Buy
aablocks AA00EGDA BORON DICHLORIDE-METHYL SULFIDE COMPLEX 63462-42-0 1g $31 2026-05-28 Buy
aablocks AA00EGDA BORON DICHLORIDE-METHYL SULFIDE COMPLEX 63462-42-0 5g $106 2026-05-28 Buy
AHH MT-08456 Dichloroborane-methyl sulfide complex 97% 250g $335 2026-05-26 Buy
TRC D432265 Dichloroborane methyl sulfide complex 63462-42-0 1g $45 2021-12-16 Buy
Product number Packaging Price Buy
298433 50g $350 Buy
AA00EGDA 1g $31 Buy
AA00EGDA 5g $106 Buy
MT-08456 250g $335 Buy
D432265 1g $45 Buy

Boron dichloride-methyl sulfide complex Chemical Properties, Uses, Production

Uses

Reactant for:

  • Hydroboration reactions
  • Pyrolysis reactions
  • Addition reactions
  • Preparation of unsymmetrical borafluorenes
  • Cyclization reactions
  • Dismutation followed by haloboration of azadiboriridine to give boron-nitrogen clusters
  • Markovnikov hydroboration

reaction suitability

reagent type: reductant

Synthesis

Dichloroborane methyl sulfide complex is synthesized by redistribution of Borane-Dimethyl Sulfide (BMS) and BCl3.SMe2. A mixture containing BHCl2.SMe2 (73%) and BMS, BH2Cl.SMe2, and BCl3.SMe2 is obtained by the reaction of BMS with Ph3CCl.

storage

Dichloroborane methyl sulfide complex is corrosive, air- and moisture-sensitive, flammable liquid; stench. Reacts violently with water. Handle and store under nitrogen or argon. Stable indefinitely when stored  under nitrogen at 25 °C. Destructive to upper respiratory tract, eyes, and skin. Handle in a fume hood.

Boron dichloride-methyl sulfide complex Preparation Products And Raw materials

Raw materials

Preparation Products

Boron dichloride-methyl sulfide complex Suppliers

Global Suppliers ( 20)
Supplier Tel Email Country ProdList Advantage
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
ShangHai Siyan Biological Technology Co., Ltd. 021-50908862,442785678,326799392 18721037013 siyansales@126.com China 9612 58
Shanghai YuanYe Biotechnology Co., Ltd. 15026964105 2881489226@qq.com China 89667 60
JinJin Le Chemical Co., Ltd 18001959627(微信同号) 18001959627 jjlchem2@163.com China 9890 58
Alfa Chemistry +1-5166625404; Info@alfa-chemistry.com United States 20000 58
Energy Chemical 021-58432009 400-005-6266 marketing@energy-chemical.com China 44871 58
Guangdong wengjiang Chemical Reagent Co., Ltd. 0751-2815987 13927875076 3007432263@qq.com China 9999 58
Shanghai Aladdin Biochemical Technology Co.,Ltd. 6206333 13167063860 anhua.mao@aladdin-e.com China 43601 58
Guangdong Yuanfeng Chemical Reagent Co., Ltd 0751-2829979 13318584237 3929169616@qq.com China 9991 58
Aladdin Scientific tp@aladdinsci.com United States 54733 58
DICHLOROBORANE-METHYL SULFIDE COMPLEX Dichloro(dimethyl sulfide)(hydro)boron Dichloro(dimethyl sulfide)borane Dichloroborane dimethyl sulfide Dichloroborane methyl sulfide complex in excess methyl sulfide Boron dichloride-methyl sulfide complex 63462-42-0 C2H7BCl2S CH32SBHCl2 Boranes Synthetic Reagents Reduction