ChemicalBook >> CAS DataBase List >>Borane-methyl sulfide complex
Borane-methyl sulfide complex
- CAS No.
- 13292-87-0
- Chemical Name:
- Borane-methyl sulfide complex
- Synonyms
- BMS;Dimethylsulfide borane complex;(Dimethyl sulfide)trihydroboron;DMSB;DIMETHYL SULFIDE BORANE;borane-methyl sulfide;BORANE-DIMETHYLSULFIDE;BORANE-DIMETHYLSULFIDE COMPLEX;BORANE DIMETHYL SULPHIDE COMPLEX;borane dimethyl sulfide complex solution
- CBNumber:
- CB3700534
- Molecular Formula:
- C2H10BS
- Molecular Weight:
- 76.97
- MDL Number:
- MFCD00013189
- MOL File:
- 13292-87-0.mol
- MSDS File:
- SDS
Last updated:2026-05-28 04:40:01
| Melting point | -40--37°C |
|---|---|
| Boiling point | ~34 °C |
| Density | 1.287 g/mL at 25 °C |
| refractive index | 1.4570 |
| Flash point | 65 °F |
| storage temp. | 2-8°C |
| solubility | Miscible with ethyl ether, tetrahydrofurane, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents. |
| form | Solution |
| Specific Gravity | 0.801 |
| color | Colorless to pale yellow |
| Water Solubility | reacts |
| Sensitive | Air & Moisture Sensitive |
| BRN | 3663489 |
| InChI | 1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3 |
| InChIKey | RMHDLBZYPISZOI-UHFFFAOYSA-N |
| SMILES | B.CSC |
| CAS DataBase Reference | 13292-87-0(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | 6AVE9SRR08 |
| NIST Chemistry Reference | Borane-methyl sulfide complex(13292-87-0) |
| EPA Substance Registry System | Boron, trihydro[thiobis[methane]]-, (T-4)- (13292-87-0) |
| UNSPSC Code | 12352112 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS02,GHS05,GHS06,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H225-H260-H301+H311-H318-H360FD-H412 | |||||||||
| Precautionary statements | P210-P231+P232-P273-P280-P301+P310-P305+P351+P338 | |||||||||
| Hazard Codes | F+,Xn,F,Xi | |||||||||
| Risk Statements | 12-14/15-19-20/22-37/38-41-67-65-63-48/20-38-11-22-14-40-36-21-36/37/38-37 | |||||||||
| Safety Statements | 36/37-62-36/39-33-26-23-16-36-24/25-7/8-43-39-36/37/39 | |||||||||
| RIDADR | UN 3399 4.3/PG 1 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | PV5080000 | |||||||||
| F | 10-13-23 | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 4.3 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29309090 | |||||||||
| Storage Class | 4.3 - Hazardous materials which set free flammable gases upon contact with water | |||||||||
| Hazard Classifications | Acute Tox. 4 Oral Eye Dam. 1 Flam. Liq. 2 Repr. 1B Skin Irrit. 2 Water-react 1 |
|||||||||
| REACH Registrations | Active | |||||||||
| Excepted Quantities | Not Permitted as Excepted Quantity | |||||||||
| NFPA 704 |
|
Borane-methyl sulfide complex price More Price(47)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 192120 | Borane dimethyl sulfide complex solution 2.0?M in THF | 13292-87-0 | 4X25ML | $88.1 | 2026-04-30 | Buy |
| Sigma-Aldrich | 179825 | Borane dimethyl sulfide complex | 13292-87-0 | 25ml | $88.5 | 2026-04-30 | Buy |
| Sigma-Aldrich | 179825 | Borane dimethyl sulfide complex | 13292-87-0 | 4x25ml | $168 | 2026-04-30 | Buy |
| TCI Chemical | D1843 | Dimethyl Sulfide Borane >90.0%(T) | 13292-87-0 | 25mL | $40 | 2026-04-30 | Buy |
| TCI Chemical | D1843 | Dimethyl Sulfide Borane >90.0%(T) | 13292-87-0 | 100mL | $116 | 2026-04-30 | Buy |
Borane-methyl sulfide complex Chemical Properties, Uses, Production
Chemical Properties
clear colorless to light yellow solution
Uses
Borane-dimethyl sulfide complex is used for hydroborations and reductions. Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides.
Uses
Borane-dimethyl sulfide (BH3 Me2S) can be used as a reagent:
- For the selective synthesis of 1,3,5-oxygenated compounds from dimethyl 3-oxoglutarate.
- For the conversion of ozonides to alcohols.
- In the CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols.
- For enantioselective reduction of ketones to chiral secondary alcohols in the presence of C3-symmetric tripodal hydroxyamide as a ligand.
- For the hydroboration reduction and other applications.
- With a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones.
General Description
Borane dimethyl sulfide complex (BMS) acts as a highly efficient and selective reducing agent in the presence of catalytic sodium tetrahydroborate for α-hydroxy esters. Asymmetric borane reduction of a variety of prochiral ketones with BMS using spiroborate esters as catalyst has been reported.
reaction suitability
reagent type: reductant
Borane-methyl sulfide complex Preparation Products And Raw materials
Raw materials
Preparation Products
4H-Amino-6-bromo-2,3-dihydrothiochromen-1,1-dioxide
Ethylferrocene
5'-Bromo-2'-chloroacetophenone
1,1'-Di-n-butylferrocene
4-Hydroxy-6-bromo-2,3-dihydrothiochromen-1,1-dioxide
Butylferrocene
3-Nitrobenzylammonium hydrochloride
(S)-5-Hydroxymethyldihydrofuran-2-one
1,1,2-Trimethylpropylborane
1,1'-Dimethylferrocene
1of4
Global Suppliers ( 297)
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Viwit Pharmaceutical Co., Ltd. | 0632-0632-2980981 15063270987 | service.china3@viwit.com | China | 121 | 55 |
| Shanghai Scientia Pharmaceutical Technology Co., Ltd. | 21-21-54301573 13917723525 | sales@scientiapharm.com | China | 260 | 62 |
| Shanghai Forxine Pharmaceutical Co., Ltd. | 21-21-64961388 18918697718 | service@forxine.com | China | 65 | 60 |
| Central China Special Gas (CCSG) Co., Ltd | 0734-8755555 15674722888 | lyq@ccsg.cn | China | 405 | 58 |
| Pingdingshan Longwei Biotechnology Co. , Ltd. | 15343756688 | 3079249712@qq.com | China | 300 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TAIYUAN RHF CO.,LTD. | +86 351 7031519 | sales@RHFChem.com | China | 2334 | 56 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
Related articles
- Borane-Methyl Sulfide Complex: Stable Borane Reductant for Organic Synthesis
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- Jun 14,2026
View Latest Price from Borane-methyl sulfide complex manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-08-25 | Di-methylsulfide borane
13292-87-0
|
$1.10-9.90 | 1kg | 99%min | 100kg | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | |
 |
2026-08-07 | Borane-Methyl Sulfide Complex
13292-87-0
|
$1.00-4.00 | 1KG | 99% | 200000KG | Shaanxi Dideu Medichem Co. Ltd | |
 |
2026-05-28 | Borane-Methyl Sulfide Complex
13292-87-0
|
$2.00-5.00 | 1KG | 99% | 10000kg | Hebei Chuanghai Biotechnology Co,.LTD |
-
- Di-methylsulfide borane
13292-87-0
- $1.10-9.90
- 99%min
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
-
- Borane-Methyl Sulfide Complex
13292-87-0
- $1.00-4.00
- 99%
- Shaanxi Dideu Medichem Co. Ltd
-
- Borane-Methyl Sulfide Complex
13292-87-0
- $2.00-5.00
- 99%
- Hebei Chuanghai Biotechnology Co,.LTD
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