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3-(Trifluoromethyl)benzyl bromide

CAS No.
402-23-3
Chemical Name:
3-(Trifluoromethyl)benzyl bromide
Synonyms
1-(Bromomethyl)-3-(trifluoromethyl)benzene;3-(TrifL;TIMTEC-BB SBB006697;3-(TrifluoroMethyl)broMide;M-TRIFLUOROMETHYLBENZYL BROMIDE;3-(BROMOMETHYL)BENZOTRIFLUORIDE;3-(TRIFLUOROMETHYL)BENZYL BROMIDE;A'-BROMO-A,A,A-TRIFLUORO-M-XYLENE;à'-bromo-à,à,à-trifluoro-m-xylene;α'-bromo-α,α,α-trifluoro-m-xylene
CBNumber:
CB0371287
Molecular Formula:
C8H6BrF3
Molecular Weight:
239.03
MDL Number:
MFCD00000395
MOL File:
402-23-3.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-27 17:40:34

3-(Trifluoromethyl)benzyl bromide Properties

Boiling point 69 °C/4 mmHg (lit.)
Density 1.565 g/mL at 25 °C (lit.)
refractive index n20/D 1.492(lit.)
Flash point 190 °F
storage temp. Keep in dark place,Inert atmosphere,Room temperature
form clear liquid
color Colorless to Almost colorless
Specific Gravity 1.565
Sensitive Lachrymatory
BRN 743243
InChI 1S/C8H6BrF3/c9-5-6-2-1-3-7(4-6)8(10,11)12/h1-4H,5H2
InChIKey MYYYZNVAUZVXBO-UHFFFAOYSA-N
SMILES FC(F)(F)c1cccc(CBr)c1
CAS DataBase Reference 402-23-3(CAS DataBase Reference)
FDA UNII AQW68T8KB6
NIST Chemistry Reference 3-Trifluoromethylbenzyl bromide(402-23-3)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405
PPE Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes  C,Xi
Risk Statements  34
Safety Statements  26-36/37/39-45-25
RIDADR  UN 3265 8/PG 2
WGK Germany  3
Hazard Note  Corrosive/Lachrymatory
HazardClass  8
PackingGroup  III
HS Code  29039990
Storage Class 8A - Combustible corrosive hazardous materials
Hazard Classifications Skin Corr. 1B
Limited Quantities 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
1
3 0

3-(Trifluoromethyl)benzyl bromide price More Price(41)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 290556 3-(Trifluoromethyl)benzyl bromide 98% 402-23-3 5g $39.6 2026-04-30 Buy
Sigma-Aldrich 290556 3-(Trifluoromethyl)benzyl bromide 98% 402-23-3 25g $89.4 2026-04-30 Buy
TCI Chemical T1782 3-(Trifluoromethyl)benzyl Bromide >98.0%(GC) 402-23-3 5g $44 2026-04-30 Buy
TCI Chemical T1782 3-(Trifluoromethyl)benzyl Bromide >98.0%(GC) 402-23-3 25g $137 2026-04-30 Buy
Apolloscientific PC7632 3-(Trifluoromethyl)benzyl bromide 97% 402-23-3 25g $29 2026-06-04 Buy
Product number Packaging Price Buy
290556 5g $39.6 Buy
290556 25g $89.4 Buy
T1782 5g $44 Buy
T1782 25g $137 Buy
PC7632 25g $29 Buy

3-(Trifluoromethyl)benzyl bromide Chemical Properties, Uses, Production

Chemical Properties

Colorless to light yellow liqui

Uses

Used in the preparation of 1-benzylazetidine-3-carboxylic acid derivatives as agonists and antagonists of the S1P5 receptor.

Uses

3-(Trifluoromethyl)benzyl bromide has been used in the preparation of flocoumafen.

349-75-7
402-23-3
Synthesis of 3-(Trifluoromethyl)benzyl bromide from 3-(Trifluoromethyl)benzyl alcohol
Global Suppliers ( 310)
Supplier Tel Email Country ProdList Advantage
Shanghai Boyle Chemical Co., Ltd. 021-50182298 021-50180596 sales@boylechem.com China 2202 55
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Beijing HwrkChemical Technology Co., Ltd 89508211 18501085097 sales.bj@hwrkchemical.com China 9407 55
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shijiazhuang Sdyano Fine Chemical Co., Ltd. 0311-89250318 13582355795 master@sjzsdyn.com China 2776 65
Wuhan Chemwish Technology Co., Ltd 86-027-67849912 sales@chemwish.com China 35884 56
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 China 18187 66

View Latest Price from 3-(Trifluoromethyl)benzyl bromide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
3-(Trifluoromethyl)benzyl bromide pictures 2026-09-02 3-(Trifluoromethyl)benzyl bromide
402-23-3
$1.00-100.00 1KG 99% Henan Fengda Chemical Co., Ltd
3-(Trifluoromethyl)benzyl bromide pictures 2026-03-20 3-(Trifluoromethyl)benzyl bromide
402-23-3
$10.00 1kg 99% 100 mt Hebei Chuanghai Biotechnology Co., Ltd
3-(Trifluoromethyl)benzyl bromide pictures 2024-08-20 3-(Trifluoromethyl)benzyl bromide
402-23-3
$8.00-10.00 1kg 99% 20ton Hebei Ganmiao New material Technology Co., LTD
3-(Bromomethyl)benzotrifluoride, 1-(Bromomethyl)-3-(trifluoromethyl)benzene ALPHA'-BROMO-ALPHA,ALPHA,ALPHA-TRIFLUORO-M-XYLENE ALPHA-BROMO-ALPHA',ALPHA',ALPHA'-TRIFLUORO-M-XYLENE A'-BROMO-A,A,A-TRIFLUORO-M-XYLENE 3-(TRIFLUOROMETHYL)BENZYL BROMIDE 3-(BROMOMETHYL)BENZOTRIFLUORIDE 3-(TrifluoroMethyl)broMide 3-(Bromomethyl)benzotrifluoride alpha-Bromo-alpha',alpha',alpha'-trifluoro-m-xylene M-TRIFLUOROMETHYLBENZYL BROMIDE TIMTEC-BB SBB006697 Benzene, 1-(bromomethyl)-3-(trifluoromethyl)- 3-(TrifL alpha'-Bromo-alpha,alpha,alpha-trifluoro-m-xylene,98% 3-(Trifluoromethyl)benzyl bromide,α′-Bromo-α,α,α-trifluoro-m-xylene à'-bromo-à,à,à-trifluoro-m-xylene α'-bromo-α,α,α-trifluoro-m-xylene 3-(Trifluoromethyl)benzyl bromide 98% 3-(Trifluoromethyl)benzylbromide98% 3-(BroMoMethyl)-1-(trifluoroMethyl)benzene 3-(Trifluoromethyl)benzyl bromide ISO 9001:2015 REACH 1-(bromomethyl)-3-(trifluoromethyl)benzen 1-(Bromomethyl)-3-(trifluoromethyl)benzene 402-23-3 414-62-6 C8H6BrF3 CF3C6H4CH2Br C8 Aryl Building Blocks BENZYL HALIDE Halogenated Hydrocarbons Organic Building Blocks Aromatic Halides (substituted) Miscellaneous Benzenes Fluoro-contained benzyl bromide series Benzyl Aromatics Miscellaneous Reagents Halogenated Heterocycles ,Pyrimidines