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HALFENPROX

CAS No.
111872-58-3
Chemical Name:
HALFENPROX
Synonyms
SIRBON;ANNIVERSE;BROFENPROX;HALFENPROX;FUBFENPROX;Halfenprox [iso];HALFENPROX STANDARD;Halfenprox Solution;C14059000 Halfenprox;Halfenprox in Acetone
CBNumber:
CB0398565
Molecular Formula:
C24H23BrF2O3
Molecular Weight:
477.34
MDL Number:
MFCD01632339
MOL File:
111872-58-3.mol
MSDS File:
SDS
Last updated:2026-07-31 15:25:14

HALFENPROX Properties

Melting point <25 °C
Boiling point approximate 291℃
Density 1.331±0.06 g/cm3(Predicted)
storage temp. 0-6°C
BRN 11404200
Henry's Law Constant 1.9×101 mol/(m3Pa) at 25℃, Ebert et al. (2023)
Major Application agriculture
environmental
InChI 1S/C24H23BrF2O3/c1-23(2,19-11-13-21(14-12-19)30-24(25,26)27)17-28-16-18-7-6-10-22(15-18)29-20-8-4-3-5-9-20/h3-15H,16-17H2,1-2H3
InChIKey WIFXJBMOTMKRMM-UHFFFAOYSA-N
SMILES CC(C)(COCC1=CC(=CC=C1)OC2=CC=CC=C2)C3=CC=C(C=C3)OC(F)(F)Br
CAS DataBase Reference 111872-58-3
FDA UNII L5U3LY0FN8
UNSPSC Code 41116107
NACRES NA.24

SAFETY

Risk and Safety Statements

Symbol(GHS)  Skull and Crossbones (GHS06)Environment (GHS09)
GHS06,GHS09
Signal word  Danger
Hazard statements  H301-H410
Precautionary statements  P264-P270-P273-P301+P310-P391-P405
Hazard Codes  T,N
Risk Statements  25-50/53
Safety Statements  45-60-61
RIDADR  UN2810 - class 6.1 - PG 3 - EHS - Toxic, liquids, organic, n.o.s., HI: all
WGK Germany  3
Storage Class 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Acute Tox. 3 Oral
Aquatic Acute 1
Aquatic Chronic 1

HALFENPROX price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich CRM37054 Halfenprox certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland 111872-58-3 10 mg $175 2026-04-30 Buy
Sigma-Aldrich 37054 Halfenprox PESTANAL 111872-58-3 10mg $138 2026-04-30 Buy
Sigma-Aldrich CRM37054 Halfenprox certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland 111872-58-3 1 unit $164 2025-07-31 Buy
Biosynth LEA87258 Halfenprox 111872-58-3 5mg $1382.6 2026-06-04 Buy
Biosynth LEA87258 Halfenprox 111872-58-3 10mg $1923.6 2026-06-04 Buy
Product number Packaging Price Buy
CRM37054 10 mg $175 Buy
37054 10mg $138 Buy
CRM37054 1 unit $164 Buy
LEA87258 5mg $1382.6 Buy
LEA87258 10mg $1923.6 Buy

HALFENPROX Chemical Properties, Uses, Production

Uses

Halfenprox is a pesticide residue in crops.

Production Methods

Halfenprox is produced through a multi-step chemical synthesis that builds its complex ether-linked structure. The process typically begins with the reaction of 3-phenoxybenzaldehyde and a cyanoacetic acid ester in the presence of a base like triethylamine, forming a key intermediate via a Knoevenagel condensation. This intermediate then undergoes cyclisation with dibromoethane, introducing the ether bridge and forming the central propyl linkage. The final step involves attaching a bromodifluoromethoxy group to the aromatic ring through halogenation and etherification reactions, completing the molecule’s insecticidal functionality. The product is then purified, often by recrystallisation or chromatography, to yield the active halfenprox compound.

Definition

ChEBI: An aromatic ether the is the 3-phenoxybenzyl ether of 2-(4-difluorobromomethoxyphenyl)-2-methylpropanol.

Mechanism of action

Broad-spectrum with contact knock-down action and some residual effects. Sodium channel modulator.

Pesticide Type

Insecticide; Acaricide

HALFENPROX Preparation Products And Raw materials

Raw materials

Preparation Products

Global Suppliers ( 51)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Nanjing Sunlida Biological Technology Co., Ltd. 025-57798810 18652991625 sales@sunlidabio.com China 3223 55
TianJin Alta Scientific Co., Ltd. 022-65378550-8551 contact@altascientific.com China 2772 58
Alta Scientific Co., Ltd. 022-6537-8550 15522853686 sales@altasci.com.cn China 4508 55
Shandong Xiya Chemical Co., Ltd. 4009903999 13395398332 sales@xiyashiji.com China 20788 60
Raw material medicin reagent co.,Ltd sales@njromanme.com China 4511 58
Shandong Ono Chemical Co., Ltd. 0539-6362799 20) China 9998 58
Shenzhen Regent Biochemical Technology Co., Ltd. 0755-85201366 18938635012 sales@regentsciences.com China 9385 58
Shenzhen Polymeri Biochemical Technology Co., Ltd. +86-400-002-6226 sales@rrkchem.com China 57336 58
Chongqing Chemdad Co., Ltd +86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39866 58

View Latest Price from HALFENPROX manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Halfenprox pictures 2020-02-01 Halfenprox
111872-58-3
$1.00 1KG Min98% HPLC Career Henan Chemical Co
  • Halfenprox pictures
  • Halfenprox
    111872-58-3
  • $1.00
  • Min98% HPLC
  • Career Henan Chemical Co
SIRBON FUBFENPROX HALFENPROX BROFENPROX ANNIVERSE 2-(4-Bromodifluoromethoxyphenyl)-2-methylpropyl 3-phenoxybenzyl ether 1-[(2-{4-[Bromo(difluoro)methoxy]phenyl}-2-methylpropoxy)methyl]-3-phenoxybenzene Halfenprox Solution, 100ppm Halfenprox [iso] halfenprox (bsi,e-iso,f-iso) HALFENPROX STANDARD Halfenprox Solution Halfenprox@10 μg/mL in Methanol Halfenprox@1000 μg/mL in Acetone Benzene, 1-[[2-[4-(bromodifluoromethoxy)phenyl]-2-methylpropoxy]methyl]-3-phenoxy- C14059000 Halfenprox Halfenprox 10.0 μg/ml Acetonitrile Halfenprox 10.0 μg/ml Ethyl acetate L14059000CY HalfenproX10μg/mLin Cyclohexane Halfenprox in Acetone Halfenprox 10 μg/mL in Cyclohexane 111872-58-3 0111872-58- C24H23BrF2O3