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tert-Butyl-2-bromobenzoate

tert-Butyl-2-bromobenzoate Structure
tert-Butyl-2-bromobenzoate structure
CAS No.
55666-42-7
Chemical Name:
tert-Butyl-2-bromobenzoate
Synonyms
tert-Butyl-2-bromobenzoate;2-BROMO-BENZOIC ACID TERT-BUTYL ESTER;Benzoic acid, 2-bromo-, 1,1-dimethylethyl ester
CBNumber:
CB0401922
Molecular Formula:
C11H13BrO2
Molecular Weight:
257.12
MDL Number:
MFCD00027950
MOL File:
55666-42-7.mol
MSDS File:
SDS
Last updated:2026-09-12 18:48:19
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tert-Butyl-2-bromobenzoate Properties

Boiling point 280.3±13.0 °C(Predicted)
Density 1.331±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
Appearance Colorless to light yellow Liquid

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338

tert-Butyl-2-bromobenzoate price More Price(44)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Biosynth FCA66642 tert-Butyl 2-bromobenzoate 55666-42-7 50g $590 2026-06-04 Buy
Activate Scientific AS88308 tert-Butyl 2-bromobenzoate 97% 55666-42-7 1g $25 2026-06-04 Buy
Activate Scientific AS88308 tert-Butyl 2-bromobenzoate 97% 55666-42-7 5g $68 2026-06-04 Buy
Activate Scientific AS88308 tert-Butyl 2-bromobenzoate 97% 55666-42-7 25g $220 2026-06-04 Buy
Activate Scientific AS88308 tert-Butyl 2-bromobenzoate 97% 55666-42-7 100g $835 2026-06-04 Buy
Product number Packaging Price Buy
FCA66642 50g $590 Buy
AS88308 1g $25 Buy
AS88308 5g $68 Buy
AS88308 25g $220 Buy
AS88308 100g $835 Buy

tert-Butyl-2-bromobenzoate Chemical Properties, Uses, Production

Synthesis

2-Bromobenzoyl chloride

7154-66-7

tert-Butanol

75-65-0

TERT-BUTYL-2-BROMOBENZOATE

55666-42-7

Example 64: Synthesis of tert-butyl 2-bromobenzoate Step A. To a solution of 2-bromobenzoyl chloride (2.0 g, 9.11 mmol) in anhydrous ethyl ether (40 mL) was added sequentially tert-butanol (0.96 mL, 10.02 mmol) and 4-(dimethylamino)pyridine (111 mg, 0.91 mmol). The reaction mixture was stirred at room temperature for 48 hours under nitrogen protection. After completion of the reaction, the resulting white suspension was extracted by partitioning with ethyl acetate (100 mL) and 1 M hydrochloric acid (100 mL). The organic phase was separated and washed sequentially with 1 M hydrochloric acid (100 mL), 2 M sodium hydroxide (2 x 100 mL), water (100 mL) and saturated saline (100 mL). The organic phase was dried with anhydrous magnesium sulfate and concentrated under reduced pressure to give a yellow oil. Purification by fast column chromatography with ethyl acetate/hexane as eluent gave tert-butyl 2-bromobenzoate (1.22 g, 52% yield) as a colorless oil.

References

[1] Organic Letters, 2011, vol. 13, # 19, p. 5326 - 5329
[2] Patent: US2006/287522, 2006, A1. Location in patent: Page/Page column 41

tert-Butyl-2-bromobenzoate Preparation Products And Raw materials

Raw materials

2-Bromobenzoyl chloride tert-Butanol 2-Bromobenzoic acid Diethyl ether 4-Dimethylaminopyridine

Preparation Products

SR 2595

tert-Butyl-2-bromobenzoate Suppliers

Global Suppliers ( 78)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Wuhan TCASChem Technology Co., Ltd. 027-86697669 13986148687 sales@tcaschem.com China 3987 55
Shanghai Litong Chemical Technology Co.,Ltd. 13598610367 0373-7129549 2468833170@qq.com China 932 58
Shanghai Aladdin Bio-Chem Technology Co.,LTD 400-6206333 13167063860 anhua.mao@aladdin-e.com China 29985 65
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Mashilabs (Shanghai) Co.,Ltd. 19916721580 mafarm@126.com China 4534 58
Cool Pharm, Ltd 021-60455363 18019463053 sales@coolpharm.com China 8455 58
Chengdu Research Accelerators Technology Co., Ltd. 028-64353063 reacchemical@163.com China 5243 58
skychemical Co.Ltd 021-20960837,QQ1332204249 sales@skychemical.com China 3338 55
Shanghai YuanYe Biotechnology Co., Ltd. 15026964105 2881489226@qq.com China 89667 60
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Wuhan TCASChem Technology Co., Ltd. 55
Shanghai Litong Chemical Technology Co.,Ltd. 58
Shanghai Aladdin Bio-Chem Technology Co.,LTD 65
Bide Pharmatech Ltd. 60
Mashilabs (Shanghai) Co.,Ltd. 58
Cool Pharm, Ltd 58
Chengdu Research Accelerators Technology Co., Ltd. 58
skychemical Co.Ltd 55
Shanghai YuanYe Biotechnology Co., Ltd. 60

tert-Butyl-2-bromobenzoate Spectrum

TERT-BUTYL-2-BROMOBENZOATE(55666-42-7)1HNMR

55666-42-7 (tert-Butyl-2-bromobenzoate) Related Search:

tert-butyl 2-broMo-5-fluorobenzoate Tert-butyl 2-bromo-6-fluoro-3-methoxybenzoate tert-butyl 3,5-dibroMobenzoate tert-Butyl2-chloro-4-fluoroBenzoate tert-Butyl 2,6-difluoronicotinate
tert-Butyl 2-bromo-4-fluorobenzoate Tert-butyl 2-bromo-4,5-dimethylbenzoate Magnesium oxide Chlorine dioxide 2,2-Dimethoxy-2-phenylacetophenone
Tert-butyl 2-bromo-5-(trifluoromethyl)benzoate tert-Butyl3,5-difluorobenzoate Tert-butyl 3,5-dichloro-2-fluorobenzoate Tert-butyl 3,5-dichloro-4-methoxybenzoate Tert-butyl 2,6-difluoro-4-iodobenzoate
tert-Butyl-4-bromobenzoate tert-Butyl-2-bromonicotinate tert-Butyl-3-bromobenzoate

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2-BROMO-BENZOIC ACID TERT-BUTYL ESTER Benzoic acid, 2-bromo-, 1,1-dimethylethyl ester tert-Butyl-2-bromobenzoate 55666-42-7 Aryl Ester Organohalides