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2-Bromobenzoic acid

CAS No.
88-65-3
Chemical Name:
2-Bromobenzoic acid
Synonyms
2-bromobenzoate;2-Bromobenzoic aicd;2-Bromobenzoic;O-BROMOBENZOIC ACID;EINECS2;Pramipexol 61;bromobenzoicacid;2-Brombenzoesure;2-BROMO BENZOIC A;2-bromo-benzoicaci
CBNumber:
CB1739693
Molecular Formula:
C7H5BrO2
Molecular Weight:
201.02
MDL Number:
MFCD00002402
MOL File:
88-65-3.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-27 23:46:05
Product description Number Pack Size Price
2-Bromobenzoic acid 97% 137677 25g $42.5
2-Bromobenzoic acid 97% 137677 100g $73.8
2-Bromobenzoic Acid >98.0%(GC)(T) B0552 25g $18
2-Bromobenzoic Acid >98.0%(GC)(T) B0552 100g $42
2-Bromobenzoic acid, min. 98% min.98% 06-0134 25g $40
More product size

2-Bromobenzoic acid Properties

Melting point 147-150 °C (lit.)
Boiling point 86 °C(Press: 4-5 Torr)
Density 1,929 g/cm3
vapor pressure >1 mm Hg ( 20 °C)
refractive index 1.6080 (estimate)
Flash point >100°C
storage temp. Sealed in dry,Room Temperature
solubility 95% ethanol: soluble100mg/mL, clear, colorless to yellow
pka 2.84(at 25℃)
form Powder
color White to light yellow or beige
Water Solubility slightly soluble
BRN 971266
InChI 1S/C7H5BrO2/c8-6-4-2-1-3-5(6)7(9)10/h1-4H,(H,9,10)
InChIKey XRXMNWGCKISMOH-UHFFFAOYSA-N
SMILES OC(=O)c1ccccc1Br
CAS DataBase Reference 88-65-3(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII AZ789TZS4L
NIST Chemistry Reference Benzoic acid, 2-bromo-(88-65-3)
EPA Substance Registry System 2-Bromobenzoic acid (88-65-3)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H319
Precautionary statements  P264-P280-P305+P351+P338-P337+P313
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-36-37/38-22
Safety Statements  26-36-24/25-37/39
WGK Germany  3
RTECS  DG4448035
Hazard Note  Irritant
TSCA  TSCA listed
HS Code  29163900
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
NFPA 704
1
2 0

2-Bromobenzoic acid price More Price(69)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 137677 2-Bromobenzoic acid 97% 88-65-3 25g $42.5 2026-04-30 Buy
Sigma-Aldrich 137677 2-Bromobenzoic acid 97% 88-65-3 100g $73.8 2026-04-30 Buy
TCI Chemical B0552 2-Bromobenzoic Acid >98.0%(GC)(T) 88-65-3 25g $18 2026-04-30 Buy
TCI Chemical B0552 2-Bromobenzoic Acid >98.0%(GC)(T) 88-65-3 100g $42 2026-04-30 Buy
Strem Chemicals 06-0134 2-Bromobenzoic acid, min. 98% min.98% 88-65-3 25g $40 2026-04-30 Buy
Product number Packaging Price Buy
137677 25g $42.5 Buy
137677 100g $73.8 Buy
B0552 25g $18 Buy
B0552 100g $42 Buy
06-0134 25g $40 Buy

2-Bromobenzoic acid Chemical Properties,Uses,Production

Chemical Properties

White to light yellow crystal powder

Uses

2-Bromobenzoic acid was used in the synthesis of new zinc(II) 2-bromobenzoate complex compounds. It was used as the starting reagent in the synthesis of hemilabile benzimidazolyl phosphine ligands.

Synthesis Reference(s)

Canadian Journal of Chemistry, 43, p. 1306, 1965 DOI: 10.1139/v65-178
The Journal of Organic Chemistry, 59, p. 4042, 1994 DOI: 10.1021/jo00094a007

General Description

2-Bromobenzoic acid (2-BA) on condensation with aminoquinolines yields phenylquinolylamines. 2-BA is the common building block for synthesis of various nitrogen heterocycles.

Purification Methods

Crystallise the acid from *C6H6 or MeOH. The anilide has m 141o (from EtOH/H2O). [Beilstein 9 IV 1011.]

Toxics Screening Level

The ITSL for o-bromobenzoic acid has been changed from 0.04 μg/m3 to 0.1 μg/m3 based on an annual averaging time.

Global( 460)Suppliers
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Hebei Chuanghai Biotechnology Co., Ltd
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Hebei Chuanghai Biotechnology Co,.LTD
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View Lastest Price from 2-Bromobenzoic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Bromobenzoic acid pictures 2026-08-07 2-Bromobenzoic acid
88-65-3
$5.00 1kg ≥98% 300mt/year Jinan Finer Chemical Co., Ltd
2-Bromobenzoic acid pictures 2026-06-30 2-Bromobenzoic acid
88-65-3
1KG 99.0% 10000KGS Shaanxi Dideu New Materials Co. Ltd
2-Bromobenzoic acid pictures 2026-05-28 2-Bromobenzoic acid
88-65-3
$2.00-5.00 1KG 99% 10000kg Hebei Chuanghai Biotechnology Co,.LTD
o-bromo-benzoicaci 2-bromo-benzoicaci Benzoic acid, o-bromo- benzoicacid,2-bromo- bromobenzoicacid 2-BROMO BENZOIC A 2-Brom-benzoic acid Brombenzoicacid,95% o-Bromobenzoic Acid 2-Bromobenzoic Acid O-BROMOBENZOIC ACID CRYSTALLINE 2-BROMO BENZOIC ACID FOR SYNTHESIS EINECS2 2-Bromobenzoic acid,97% 2-Bromobenzene carboxylic acid 2-Brombenzoesure 2-Bromobenzoic acid ,99% 2-BroMobenzoic acid, 97% 100GR 2-BroMobenzoic acid, 97% 25GR Adjacent broMine benzoic acid 2-Bromobenzoic acid Vetec(TM) reagent grade, 97% RARECHEM AL BO 0014 2-BROMOBENZOIC ACID 2-Bromobenzoic Acid > Pramipexol 61 2-Bromobenzoic acid, 98% 2-Bromobenzoic aicd 2-bromobenzoate 2-Bromobenzoic O-BROMOBENZOIC ACID 88-65-3 135443-91-8 910463-68-3 BrC6H4COOH BrC6H4CO2H ARYL ACID Organic Building Blocks Carboxylic Acids Carbonyl Compounds C7 Building Blocks Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts Benzoic acid Organic acids Acids & Esters Bromine Compounds C7 Carbonyl Compounds Carboxylic Acids alkyl bromide| carboxylic acid Aromatic Compounds bc0001