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TERT-BUTYL-4-BROMOBENZOATE

TERT-BUTYL-4-BROMOBENZOATE structure

CAS No.: 59247-47-1

Chemical Name:: TERT-BUTYL-4-BROMOBENZOATE

Synonyms: tert-Butyl p-BroMobenzoate;TERT-BUTYL-4-BROMOBENZOATE;Tert-butyl 4-bromobenzoate?New;4-Bromobenzoic acid tert-butyl ester;4-BroMobenzoic Acid 1,1-DiMethylethyl Ester;Benzoic acid, 4-broMo-, 1,1-diMethylethyl ester

CBNumber:: CB6774796

Molecular Formula:: C11H13BrO2

Molecular Weight:: 257.12

MDL Number:: MFCD00093266

MOL File:: 59247-47-1.mol

MSDS File:: SDS

Last updated:2025-07-24 18:13:51

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TERT-BUTYL-4-BROMOBENZOATE Properties

Boiling point	91-92 °C(Press: 1.2 Torr)
Density	1.331±0.06 g/cm3(Predicted)
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
form	liquid
color	Colourless to light yellow
InChI	InChI=1S/C11H13BrO2/c1-11(2,3)14-10(13)8-4-6-9(12)7-5-8/h4-7H,1-3H3
InChIKey	BFJJYXUCGYOXDM-UHFFFAOYSA-N
SMILES	C(OC(C)(C)C)(=O)C1=CC=C(Br)C=C1

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H315-H319
Precautionary statements	P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
HS Code	2916399090

TERT-BUTYL-4-BROMOBENZOATE price More Price(29)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TRC	B690695	tert-Butyl4-Bromobenzoate	59247-47-1	25g	$1230	2021-12-16	Buy
American Custom Chemicals Corporation	HCH0027225	TERT-BUTYL 4-BROMOBENZOATE 95.00%	59247-47-1	25G	$2333.1	2021-12-16	Buy
Biosynth Carbosynth	FB19441	tert-Butyl 4-bromobenzoate	59247-47-1	25g	$600	2021-12-16	Buy
Apolloscientific	OR313102	tert-Butyl4-bromobenzoate	59247-47-1	25g	$675	2021-12-16	Buy
American Custom Chemicals Corporation	HCH0027225	TERT-BUTYL 4-BROMOBENZOATE 95.00%	59247-47-1	2.5G	$869	2021-12-16	Buy

Product number	Packaging	Price	Buy
B690695	25g	$1230	Buy
HCH0027225	25G	$2333.1	Buy
FB19441	25g	$600	Buy
OR313102	25g	$675	Buy
HCH0027225	2.5G	$869	Buy

TERT-BUTYL-4-BROMOBENZOATE Chemical Properties,Uses,Production

Uses

4-bromo substituted benzoic acid derivative, tert-Butyl-4-broMobenzoate can be used as a building block for the synthesis of various biologically active compounds.

Synthesis

865-47-4

586-75-4

59247-47-1

At -78 °C, 4-bromobenzoyl chloride (25.08 g, 114 mmol) was dissolved in THF (120 mL) and a THF solution of potassium tert-butanolate (1 M, 120 mL, 120 mmol) was slowly added. The reaction mixture was stirred at -78 °C and gradually warmed to room temperature for 2 hours. After completion of the reaction, the reaction mixture was diluted with ether. The organic phase was washed sequentially with saturated NaHCO3 solution (2×) and brine (1×) and then dried with anhydrous MgSO4. The desiccant was removed by filtration and the filtrate was concentrated under reduced pressure. The crude product was purified by fast column chromatography on silica gel, the eluent being a hexane solution of 5% ethyl acetate to give tert-butyl 4-bromobenzoate (27.96 g, 95% yield) as a colorless oil.1H NMR (600 MHz, CDCl3) δ 7.84 (d, J = 8.5 Hz, 2H), 7.54 (d, J = 8.5 Hz, 2H), 1.59 (s 9H); ESIMS calculated value 257.0 (M + + H), measured value 257.1 (M + + H).

References

[1] RSC Advances, 2016, vol. 6, # 22, p. 18165 - 18177
[2] Journal of Organic Chemistry, 2000, vol. 65, # 17, p. 5428 - 5430
[3] Patent: WO2007/2248, 2007, A2. Location in patent: Page/Page column 72-73
[4] Organic Process Research and Development, 2012, vol. 16, # 11, p. 1832 - 1845
[5] Journal of the American Chemical Society, 2016, vol. 138, # 32, p. 10293 - 10298

TERT-BUTYL-4-BROMOBENZOATE Preparation Products And Raw materials

Raw materials

Benzamide, 4-bromo-N-(1,1-dimethylethoxy)- 4-Bromobenzoyl chloride Potassium tert-butoxide 4-Bromobenzoic acid 4-Bromobenzyl alcohol

tert-Butanol Di-tert-butyl dicarbonate

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Preparation Products

tert-Butyl 4-aminobenzoate 4,4',4'',4'''-(1,4-phenylenebis(azanetriyl))tetrabenzoic acid

TERT-BUTYL-4-BROMOBENZOATE Suppliers

Global( 167)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20190	58
Capot Chemical Co.,Ltd.	+8613336195806	sales@capot.com	China	29734	60
Fluoropharm Co., Ltd.	+86-0571-85586753 +86-13336034509	sales@fluoropharm.com	China	1445	60
Zhejiang ZETian Fine Chemicals Co. LTD	+8618957127338	stella@zetchem.com	China	2161	58
Accela ChemBio Inc.	+1-858-6993322	info@accelachem.com	United States	21193	58
Changzhou Ditong Chemical Co.,Ltd	+86-0519-88299272	info@edengenechem.com	China	2176	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
career henan chemical co	+86-0371-86658258 +8613203830695	factory@coreychem.com	China	29800	58
Shaanxi Dideu Medichem Co. Ltd	+86-29-87569266 +86-17392581500	1015@dideu.com	China	3969	58
Jinan Liheng Biotechnology Co., Ltd.	15865262812	info@lihengpharm.com	CHINA	938	58

Supplier	Advantage
Henan Fengda Chemical Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Fluoropharm Co., Ltd.	60
Zhejiang ZETian Fine Chemicals Co. LTD	58
Accela ChemBio Inc.	58
Changzhou Ditong Chemical Co.,Ltd	58
Alchem Pharmtech,Inc.	58
career henan chemical co	58
Shaanxi Dideu Medichem Co. Ltd	58
Jinan Liheng Biotechnology Co., Ltd.	58

View Lastest Price from TERT-BUTYL-4-BROMOBENZOATE manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2025-07-25	TERT-BUTYL-4-BROMOBENZOATE 59247-47-1	US $0.00 / kg	1kg	99%	10000KGS	Shaanxi Dideu New Materials Co. Ltd
2024-04-23	TERT-BUTYL-4-BROMOBENZOATE 59247-47-1	US $8.00-6.00 / kg	1kg	99%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd
2020-01-03	TERT-BUTYL-4-BROMOBENZOATE 59247-47-1	US $1.00 / KG	1KG	99%	100KG	Career Henan Chemical Co

TERT-BUTYL-4-BROMOBENZOATE
59247-47-1
US $0.00 / kg
99%
Shaanxi Dideu New Materials Co. Ltd

TERT-BUTYL-4-BROMOBENZOATE
59247-47-1
US $8.00-6.00 / kg
99%
Henan Fengda Chemical Co., Ltd

TERT-BUTYL-4-BROMOBENZOATE
59247-47-1
US $1.00 / KG
99%
Career Henan Chemical Co

TERT-BUTYL-4-BROMOBENZOATE Spectrum

TERT-BUTYL-4-BROMOBENZOATE(59247-47-1)¹HNMR

59247-47-1(TERT-BUTYL-4-BROMOBENZOATE)Related Search:

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TERT-BUTYL 4-BROMO-3-METHYLBENZOATE TERT-BUTYL 4-BROMO-2-METHOXYBENZOATE TERT-BUTYL-2-BROMOBENZOATE

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TERT-BUTYL-4-BROMOBENZOATE 4-Bromobenzoic acid tert-butyl ester Benzoic acid, 4-broMo-, 1,1-diMethylethyl ester 4-BroMobenzoic Acid 1,1-DiMethylethyl Ester tert-Butyl p-BroMobenzoate Tert-butyl 4-bromobenzoate?New 59247-47-1 Aryl Ester Organohalides Aromatics Intermediates & Fine Chemicals Pharmaceuticals