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N-Benzylhydroxylamine hydrochloride

N-Benzylhydroxylamine hydrochloride Structure
N-Benzylhydroxylamine hydrochloride structure
CAS No.
29601-98-7
Chemical Name:
N-Benzylhydroxylamine hydrochloride
Synonyms
Benzyl(hydroxy)ammonium chloride;N-Benzylhydroxylammonium chloride;N-BENZYLHYDROXYLAMINE HYDROCHLORIDE;N-Benzylhydroxylamine Hydrochloride >N-Benzylhydroxylamine hydrochloride 97%;BenzeneMethanaMine,N-hydroxy-,hydrochlori;N-Benzylhydroxylamine hydrochloride;N-hydroxy-BenzeneMethanaMine hydrochloride;Benzenemethanamine, N-hydroxy-, hydrochloride;N-Benzylhydroxylamine hydrochloride≥ 98%(HPLC)
CBNumber:
CB0664646
Molecular Formula:
C7H10ClNO
Molecular Weight:
159.61
MDL Number:
MFCD00043377
MOL File:
29601-98-7.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-10-21 17:18:09
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N-Benzylhydroxylamine hydrochloride Properties

Melting point 108-110 °C(lit.)
storage temp. Inert atmosphere,Room Temperature
solubility DMSO (Slightly), Ethyl Acetate (Slightly, Heated), Methanol (Slightly)
form powder to crystal
color White to Light yellow
BRN 507948
InChI InChI=1S/C7H9NO.ClH/c9-8-6-7-4-2-1-3-5-7;/h1-5,8-9H,6H2;1H
InChIKey YSNXOQGDHGUKCZ-UHFFFAOYSA-N
SMILES N(CC1=CC=CC=C1)O.[H]Cl
CAS DataBase Reference 29601-98-7
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
F  3-10
HS Code  29280000
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

N-Benzylhydroxylamine hydrochloride price More Price(88)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 13454 N-Benzylhydroxylamine hydrochloride puriss., ≥99.0% (AT) 29601-98-7 1g $66.3 2026-04-30 Buy
Sigma-Aldrich 13454 N-Benzylhydroxylamine hydrochloride puriss., ≥99.0% (AT) 29601-98-7 5G $204 2026-04-30 Buy
TCI Chemical B4073 N-Benzylhydroxylamine Hydrochloride >98.0%(HPLC)(T) 29601-98-7 5g $151 2026-04-30 Buy
TCI Chemical B4073 N-Benzylhydroxylamine Hydrochloride >98.0%(HPLC)(T) 29601-98-7 25g $536 2026-04-30 Buy
TRC TRC-H809745-1G N-Hydroxybenzylamine Hydrochloride 29601-98-7 1g $117 2026-06-03 Buy
Product number Packaging Price Buy
13454 1g $66.3 Buy
13454 5G $204 Buy
B4073 5g $151 Buy
B4073 25g $536 Buy
TRC-H809745-1G 1g $117 Buy

N-Benzylhydroxylamine hydrochloride Chemical Properties, Uses, Production

Chemical Properties

White crystalline

Uses

N-Benzylhydroxylamine hydrochloride may be used in the preparation of a precursor to hitherto unknown aminocyclopentitol derivative, hydroxy functionalised 4-exo-ethoxycarbonyl-3-oxa-2-azabicyclo[3.3.0]octane system.

General Description

N-Benzylhydroxylamine hydrochloride is a N-substituted-hydroxylamine. It participates in the ring opening of (2S,3R)-1,2-epoxy-4-penten-3-ol. Two-step synthesis of N-benzylhydroxylamine starting from dibenzylamine is reported.

Biochem/physiol Actions

N-Benzylhydroxylamine is a potential pharmacological agent in the prevention and progression of acrolein-induced damage to the retinal pigment epithelium.

Synthesis

Benzenemethanamine,N-(phenylmethylene)-, N-oxide

3376-26-9

N-Benzylhydroxylamine hydrochloride

29601-98-7

The general procedure for the synthesis of N-benzylhydroxylamine hydrochloride from the compound (CAS:3376-26-9) was as follows: in a two-necked round-bottomed flask equipped with a stirrer, a mixture of dibenzylamine (1) (32.8 g, 0.17 mol), Na2WO4-2H2O (0.98 g, 3.33 mmol) and methanol (0.17 L) was cooled to -15 °C. A 30% aqueous solution of H2O2 (57 mL, 0.5 mol) was slowly added dropwise over about 1 h via a pressure equalizing dropping funnel. After the dropwise addition, the reaction mixture was stirred continuously at room temperature for 16 hours. Subsequently, the mixture was transferred to a 3 L beaker and crushed ice (1 kg) was added under vigorous stirring. The white precipitate formed was collected by filtration and washed several times with ice water (1 L) to completely remove the peroxide. The wet crude nitrone was dissolved in 20% aqueous HCl solution (0.33 L) and concentrated under reduced pressure at a water bath temperature of 70 °C. To remove trace water, the mixture was washed with toluene (3 x 33 mL) and subsequently concentrated under vacuum to dryness overnight. Finally, recrystallization was carried out using minimal amounts of hot methanol (30 mL) and ether (115 mL) to give a white crystalline pure product (19.3 g, 71% yield). The 1H and 13C NMR spectra of the product were in agreement with those reported in the literature; ESI-HRMS analysis resulted in a calculated value of 124.07 and a measured value of 124.0750 for C7H9NO(M + H)+.

References

[1] Synthetic Communications, 2005, vol. 35, # 18, p. 2445 - 2451
[2] Journal of Organic Chemistry, 1983, vol. 48, # 9, p. 1444 - 1448
[3] Synthesis, 2009, # 18, p. 3174 - 3176
[4] Bioorganic and Medicinal Chemistry Letters, 2011, vol. 21, # 17, p. 4969 - 4972

N-Benzylhydroxylamine hydrochloride synthesis

57079-14-8
29601-98-7
Synthesis of N-Benzylhydroxylamine hydrochloride from (Z)-6-(3-Carboxyacrylamido)hexanoic acid

N-Benzylhydroxylamine hydrochloride Preparation Products And Raw materials

Raw materials

Benzenemethanamine,N-(phenylmethylene)-, N-oxide Benzyl-(2,3-dimethoxy-benzyl)-amine Benzamide, N-hydroxy-N-(phenylmethyl)- Dibenzylamine p-Toluic acid
N-Benzylhydroxylamine hydrochloride Benzylamine Water Benzoic acid Benzaldoxime

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Preparation Products

4-Fluorobenzoic acid 2,3-Dimethoxybenzaldoxime

N-Benzylhydroxylamine hydrochloride Suppliers

Global Suppliers ( 353)
Supplier Tel Email Country ProdList Advantage
Dezhou Honghai Pharmaceutical Technology Co., Ltd 15552645780 17653416096 17658510842@163.com China 57 58
Hunan HuaTeng Pharmaceutical Co., Ltd., 400-8592883 15367835770 sales@huatengsci.com China 5869 58
Suzhou Lakestar Pharmatech Co., Ltd. 0512-63970158-603 18018108880 info@lakestarpharma.com China 399 59
SHANDONG XINGRUNDA CHEMICAL CO.,LTD 0534-18615348689 18615348689 hclt1978@163.com China 35 58
Shenyang Feikai Chemical Technology Co., Ltd. 13889276367 40825993@qq.com China 9 58
Chongqing Cotechx Technology co., LTD 13512396738 13452341540 13452341540@139.com China 23 58
Shanghai Boyle Chemical Co., Ltd. 021-50182298 021-50180596 sales@boylechem.com China 2202 55
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
ZHIWE CHEMTECH CO LTD 021-20221225 13917446399 zwchem@163.com China 518 61
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Supplier Advantage
Dezhou Honghai Pharmaceutical Technology Co., Ltd 58
Hunan HuaTeng Pharmaceutical Co., Ltd., 58
Suzhou Lakestar Pharmatech Co., Ltd. 59
SHANDONG XINGRUNDA CHEMICAL CO.,LTD 58
Shenyang Feikai Chemical Technology Co., Ltd. 58
Chongqing Cotechx Technology co., LTD 58
Shanghai Boyle Chemical Co., Ltd. 55
J & K SCIENTIFIC LTD. 76
ZHIWE CHEMTECH CO LTD 61
TCI (Shanghai) Development Co., Ltd. 81

View Latest Price from N-Benzylhydroxylamine hydrochloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
N-Benzylhydroxylamine hydrochloride pictures 2026-10-21 N-Benzylhydroxylamine hydrochloride
29601-98-7
 1KG 99% 100 KG Shanghai Massive Chemical Technology Co., Ltd
N-Benzylhydroxylamine hydrochloride pictures 2026-06-30 N-Benzylhydroxylamine hydrochloride
29601-98-7
 1kg 99% 10000KGS Shaanxi Dideu New Materials Co. Ltd
N-Benzylhydroxylamine hydrochloride pictures 2025-12-24 N-Benzylhydroxylamine hydrochloride
29601-98-7
 $49.00 1KG 99.0% 1000 tons Shaanxi Dideu Medichem Co. Ltd

N-Benzylhydroxylamine hydrochloride Spectrum

N-Benzylhydroxylamine hydrochloride(29601-98-7)1HNMRN-Benzylhydroxylamine hydrochloride(29601-98-7)RamanN-Benzylhydroxylamine hydrochloride(29601-98-7)IR

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