1-(4-Amino-3-bromo-phenyl)-ethanone
- CAS No.
- 56759-32-1
- Chemical Name:
- 1-(4-Amino-3-bromo-phenyl)-ethanone
- Synonyms
- 1-(4-aMino-3-broMophenyl)ethan-1-one;1-(4-amino-3-bromophenyl)ethylone;1-(4-Amino-3-bromo-phenyl)-ethanone;Ethanone, 1-(4-amino-3-bromophenyl)-
- CBNumber:
- CB1101386
- Molecular Formula:
- C8H8BrNO
- Molecular Weight:
- 214.06
- MDL Number:
- MFCD00272386
- MOL File:
- 56759-32-1.mol
- MSDS File:
- SDS
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319 |
| Precautionary statements | P501-P270-P264-P280-P337+P313-P305+P351+P338-P302+P352-P332+P313-P362-P301+P310+P330-P405 |
| HS Code | 2922390090 |
1-(4-Amino-3-bromo-phenyl)-ethanone price
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Apolloscientific | OR480776 | 4-Amino-3-bromoacetophenone >97% | 56759-32-1 | 1g | $21 | 2026-06-04 | Buy |
| Apolloscientific | OR480776 | 4-Amino-3-bromoacetophenone >97% | 56759-32-1 | 5g | $30 | 2026-06-04 | Buy |
| Apolloscientific | OR480776 | 4-Amino-3-bromoacetophenone >97% | 56759-32-1 | 25g | $141 | 2026-06-04 | Buy |
| Apolloscientific | OR480776 | 4-Amino-3-bromoacetophenone >97% | 56759-32-1 | 100g | $549 | 2026-06-04 | Buy |
| Activate Scientific | AS120792 | 1-(4-Amino-3-bromophenyl)ethanone 96% | 56759-32-1 | 1g | $38 | 2026-06-04 | Buy |
1-(4-Amino-3-bromo-phenyl)-ethanone Chemical Properties, Uses, Production
Synthesis
99-92-3
56759-32-1
The general procedure for the synthesis of 4''-amino-3''-bromoacetophenone from 4-aminoacetophenone was as follows: 1-(4-aminophenyl)ethanone (10.0 g, 74.0 mmol) was dissolved in acetonitrile (50 mL), and an acetonitrile solution of N-bromosuccinimide (13.8 g, 77.7 mmol) was slowly added dropwise (30 mL) under ice-bath cooling conditions. After the dropwise addition, the reaction mixture was stirred at room temperature for 20 hours. After completion of the reaction, the solvent was removed by distillation under reduced pressure and the residue obtained was dissolved in ethyl acetate. The organic layer was washed sequentially with saturated aqueous sodium bicarbonate and saturated saline and dried with anhydrous sodium sulfate. Finally, the solvent was evaporated under reduced pressure to afford the target product 4''-amino-3''-bromoacetophenone as a yellow powder (15.8 g, 100% yield). The structure of the product was confirmed by 1H-NMR (CDCl3, 400 MHz): δ 2.49 (3H, s), 4.52-4.70 (2H, br), 6.73 (1H, d, J = 8.5 Hz), 7.73 (1H, dd, J = 8.5, 1.9 Hz), 8.05 (1H, d, J = 1.9 Hz).
References
[1] Patent: US2016/207883, 2016, A1. Location in patent: Paragraph 0644-0646
[2] Synthetic Communications, 2009, vol. 39, # 2, p. 215 - 219
[3] Chemistry - A European Journal, 2017, vol. 23, # 69, p. 17463 - 17468
[4] Journal of Labelled Compounds and Radiopharmaceuticals, 2016, vol. 59, # 13, p. 552 - 556
[5] Agricultural and Biological Chemistry, 1984, vol. 48, # 11, p. 2883 - 2888
1-(4-Amino-3-bromo-phenyl)-ethanone Preparation Products And Raw materials
Raw materials
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Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Wuhan Chemwish Technology Co., Ltd | 86-027-67849912 | sales@chemwish.com | China | 35884 | 56 |
| Shanghai Sinch Parmaceuticals Tech. Co. Ltd. | +86-21-54098501 | sales@sinch.com.cn | China | 11592 | 64 |
| Adamas Reagent, Ltd. | 400-6009262 15618770481 | yhx@titansci.com | China | 14098 | 59 |
| Shanghai Longsheng chemical Co.,Ltd. | 58099637 13585536065 | sales@shlschem.com | China | 9880 | 59 |
| Shanghai Synthfine Chemical Co.,Ltd | 15921303235 | sales@synthfine.com | China | 995 | 58 |
| Shanghai Topbiochem Technology Co., Ltd | +86-21-60341587 | sales@topbiochem.com | China | 6166 | 58 |
| Nanjing Norris-Pharm Technology Co., Ltd | 13901585132 | sales@norris-pharm.com | China | 8869 | 55 |
| SuZhou ShiYa Biopharmaceuticals, Inc. | 86(512)5235 8471 17715136450 | sales@shiyabiopharm.com | China | 4167 | 58 |
| Shanghai Aladdin Bio-Chem Technology Co.,LTD | 400-6206333 13167063860 | anhua.mao@aladdin-e.com | China | 29977 | 65 |
| SynAsst Chemical. | 021-60343070 | China | 12731 | 55 |
View Latest Price from 1-(4-Amino-3-bromo-phenyl)-ethanone manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2019-12-23 | 1-(4-AMINO-3-BROMO-PHENYL)-ETHANONE
56759-32-1
|
$1.00 | 1KG | 99% | 100KG | Career Henan Chemical Co |
-

- 1-(4-AMINO-3-BROMO-PHENYL)-ETHANONE
56759-32-1
- $1.00
- 99%
- Career Henan Chemical Co
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