1-N-Boc-cis-1,4-cyclohexyldiamine
- CAS No.
- 247570-24-7
- Chemical Name:
- 1-N-Boc-cis-1,4-cyclohexyldiamine
- Synonyms
- 1-N-Boc-cis-1,4-cycL;1-N-Boc-cis-1,4-Cyclohexyldiam;N-Boc-cis-1,4-cyclohexyldiaMine;N1-BOC-CIS-1,4-CYCLOHEXYLDIAMINE;cis-N-Boc-1,4-cyclohexanediaMine;N-Boc-cis-1,4-cyclohexanediamine;1-N-BOC-CIS-1,4-CYCLOHEXYLDIAMINE;Cis-N-Boc-cyclohexane-1,4-diamine;Cis-1N-Boc-cyclohexane-1,4-diaMine;cis-4-(Boc-amino)cyclohexylamine,97%
- CBNumber:
- CB1123856
- Molecular Formula:
- C11H22N2O2
- Molecular Weight:
- 214.31
- MDL Number:
- MFCD03844604
- MOL File:
- 247570-24-7.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Boiling point | 322.1±31.0 °C(Predicted) |
|---|---|
| Density | 1.02±0.1 g/cm3(Predicted) |
| storage temp. | under inert gas (nitrogen or Argon) at 2–8 °C |
| form | powder |
| pka | 12.44±0.40(Predicted) |
| color | Off-white |
| Water Solubility | Soluble in methanol, ethyl acetate and Slightly soluble in water. |
| InChI | InChI=1S/C11H22N2O2/c1-11(2,3)15-10(14)13-9-6-4-8(12)5-7-9/h8-9H,4-7,12H2,1-3H3,(H,13,14)/t8-,9+ |
| InChIKey | FEYLUKDSKVSMSZ-DTORHVGOSA-N |
| SMILES | C(OC(C)(C)C)(=O)N[C@@H]1CC[C@H](N)CC1 |
| CAS DataBase Reference | 247570-24-7 |
| UNSPSC Code | 12352116 |
| NACRES | NA.21 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| Hazard Codes | Xi | |||||||||
| WGK Germany | WGK 3 | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 2921309990 | |||||||||
| Storage Class | 10 - Combustible liquids | |||||||||
| Hazard Classifications | Aquatic Chronic 2 | |||||||||
| NFPA 704 |
|
1-N-Boc-cis-1,4-cyclohexyldiamine price More Price(71)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Usbiological | 266824 | 1-N-Boc-cis-1,4-cyclohexyldiamine Asreported | 247570-24-7 | 500mg | $340 | 2026-06-03 | Buy |
| Usbiological | 266824 | 1-N-Boc-cis-1,4-cyclohexyldiamine Asreported | 247570-24-7 | 1g | $582 | 2026-06-03 | Buy |
| Usbiological | 266824 | 1-N-Boc-cis-1,4-cyclohexyldiamine Asreported | 247570-24-7 | 2g | $811 | 2026-06-03 | Buy |
| Usbiological | 266824 | 1-N-Boc-cis-1,4-cyclohexyldiamine Asreported | 247570-24-7 | 5g | $1480 | 2026-06-03 | Buy |
| Usbiological | 266824 | 1-N-Boc-cis-1,4-cyclohexyldiamine Asreported | 247570-24-7 | 10g | $2164 | 2026-06-03 | Buy |
1-N-Boc-cis-1,4-cyclohexyldiamine Chemical Properties, Uses, Production
Uses
cis-4-(Boc-amino)cyclohexylamine can be used in agrochemical, pharmaceutical and dyestuff field.
Synthesis
247568-84-9
247570-24-7
Step 4: To a solution of tert-butyl (cis-4-azido-cyclohexyl)-carbamate (6.3 g, 26 mmol) in methanol (100 mL) was added 5% Pd/C (Degussa type, 0.63 g) under argon protection. The reaction flask was sealed, evacuated and backfilled with hydrogen, and the process was repeated three times. The reaction mixture was stirred for 2 h at room temperature under an atmosphere of hydrogen at 1 atm. Upon completion of the reaction, the catalyst was removed by filtration through a diatomaceous earth pad and the filtrate was concentrated under reduced pressure. The residue was partitioned between ether (Et2O) and 1N hydrochloric acid (HCl) solution. The aqueous phase was separated and alkalized with sodium hydroxide solution to pH > 10, followed by extraction with ethyl acetate (EtOAc, 2 × 100 mL). The organic phases were combined, washed with saturated sodium chloride solution (brine), dried over anhydrous sodium sulfate (Na2SO4), filtered and concentrated under reduced pressure to afford the white solid product (tert-butyl cis-4-amino-cyclohexyl)-carbamate (3.6 g, 64% yield). Mass spectrometry (MS) analysis showed (M+H)+ = 215.6.
References
[1] Patent: US2005/54626, 2005, A1. Location in patent: Page/Page column 48
[2] Patent: EP1683795, 2006, A1. Location in patent: Page/Page column 14; 15
[3] Patent: US2005/20639, 2005, A1. Location in patent: Page 14 - 15
1-N-Boc-cis-1,4-cyclohexyldiamine Preparation Products And Raw materials
Raw materials
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Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| PharmaBlock Sciences (Nanjing),Inc. | 025-86918202 4000255188 | sales@pharmablock.com | China | 5000 | 55 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| Wuhan Chemwish Technology Co., Ltd | 86-027-67849912 | sales@chemwish.com | China | 35884 | 56 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 | |
| Jia Xing Isenchem Co.,Ltd | 0573-85285100 18627885956 | isenchem@163.com | China | 9389 | 66 |
| Adamas Reagent, Ltd. | 400-6009262 15618770481 | yhx@titansci.com | China | 14098 | 59 |
| Accela ChemBio Co.,Ltd. | 021-50795510 4000665055 | marketing@accelachem.com | China | 10972 | 64 |
| ZEROSCHEM.CO.,LTD. | 10-61256048 13810278579; | sales@zeroschem.com | China | 1399 | 59 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
View Latest Price from 1-N-Boc-cis-1,4-cyclohexyldiamine manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-12-31 | 1-N-Boc-cis-1,4-cyclohexyldiamine
247570-24-7
|
$1.00 | 1KG | 99% | 100KG | Career Henan Chemical Co |
-
- 1-N-Boc-cis-1,4-cyclohexyldiamine
247570-24-7
- $1.00
- 99%
- Career Henan Chemical Co
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